| 2021 | Burgess, Nicholas | Scotch College | Hawthorn | Further Mathematics | 40 |
| 2022 | Burgess, Peter | Monivae College | Hamilton | Accounting | 40 |
| 2023 | Burgess, Peter | Monivae College | Hamilton | Further Mathematics | 40 |
| 2024 | Burgess-Norris, Alexandra | Distance Education Centre Victoria | Thornbury | International Studies | 40 |
| 2025 | Burggraf, Millicent | Melbourne Girls Grammar | South Yarra | Biology | 50 |
| 2026 | Burggraf, Millicent | Melbourne Girls Grammar | South Yarra | Mathematical Methods | 40 |
| 2027 | Burgi, Caitlyn | Loreto Mandeville Hall | Toorak | History: Revolutions | 43 |
| 2028 | Burgin, Christian | Melbourne High School | South Yarra | Psychology | 45 |
| 2029 | Burgin, Ellen | St Leonards College | Brighton East | Legal Studies | 42 |
| 2030 | Burke, Dylan | Cheltenham Secondary College | Cheltenham | English | 41 |
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| 2031 | Burke, Lucy | Sacred Heart College Geelong | Newtown | Studio Arts | 40 |
| 2032 | Burke, Michelle | Caulfield Grammar School Caulfield | St Kilda East | Health and Human Development | 45 |
| 2033 | Burke, Nathan | Gleneagles Secondary College | Endeavour Hills | Further Mathematics | 40 |
| 2034 | Burke, Patrick | Xavier College | Kew | Mathematical Methods (CAS) | 43 |
| 2035 | Burleigh, Thomas | Mazenod College | Mulgrave | Economics | 46 |
| 2036 | Burleigh, Thomas | Mazenod College | Mulgrave | Further Mathematics | 46 |
| 2037 | Burleigh, Thomas | Mazenod College | Mulgrave | Accounting | 45 |
| 2038 | Burleigh, Thomas | Mazenod College | Mulgrave | IT Applications | 41 |
| 2039 | Burling, Emily | Wesley College St Kilda Rd | Melbourne | Studio Arts | 40 |
| 2040 | Burnell, Stefan | Peninsula Grammar | Mount Eliza | English | 40 |
| 2041 | Burnett, Daniel | Maffra Secondary College | Maffra | Outdoor and Environmental Studies | 40 |
| 2042 | Burnham, Alessi | Northcote High School | Northcote | Further Mathematics | 44 |
| 2043 | Burns, Jess | McKinnon Secondary College | McKinnon | Business Management | 49 |
| 2044 | Burns, Jess | McKinnon Secondary College | McKinnon | IT Applications | 42 |
| 2045 | Burns, Jess | McKinnon Secondary College | McKinnon | Economics | 40 |
| 2046 | Burns, Laura | Emmaus College | Vermont South | Further Mathematics | 40 |
| 2047 | Burns, Lore | Yarra Valley Grammar School | Ringwood | English | 44 |
| 2048 | Burns, Lore | Yarra Valley Grammar School | Ringwood | Drama | 43 |
| 2049 | Burns, Lore | Yarra Valley Grammar School | Ringwood | Philosophy | 42 |
| 2050 | Burns, Lore | Yarra Valley Grammar School | Ringwood | Music Solo Performance | 40 |
| 2051 | Burns, Phoebe | Maranatha Christian School | Endeavour Hills | Biology | 45 |
| 2052 | Burns, Phoebe | Maranatha Christian School | Endeavour Hills | History: Revolutions | 45 |
| 2053 | Burns, Phoebe | Maranatha Christian School | Endeavour Hills | English | 41 |
| 2054 | Burns, Phoebe | Maranatha Christian School | Endeavour Hills | Chemistry | 40 |
| 2055 | Burns, Rachel | Distance Education Centre Victoria | Thornbury | English | 40 |
| 2056 | Burns-Fabb, Findlay | Apollo Bay P-12 College | Apollo Bay | Outdoor and Environmental Studies | 45 |
| 2057 | Burns-Williamson, Shelley | Northcote High School | Northcote | English | 43 |
| 2058 | Burns-Williamson, Shelley | Northcote High School | Northcote | International Studies | 41 |
| 2059 | Burr, John | Wesley College St Kilda Rd | Melbourne | Mathematical Methods (CAS) | 42 |
| 2060 | Burr, John | Wesley College St Kilda Rd | Melbourne | Physics | 42 |
| 2061 | Burr, John | Wesley College St Kilda Rd | Melbourne | Chemistry | 41 |
| 2062 | Burr, John | Wesley College St Kilda Rd | Melbourne | Specialist Mathematics | 41 |
| 2063 | Burrage, Hannah | Mount Waverley Secondary College | Mount Waverley | Literature | 40 |
| 2064 | Burridge, Jennifer | Carey Baptist Grammar School | Kew | Visual Communication Design | 46 |
| 2065 | Burrows, Larissa | Mount Waverley Secondary College | Mount Waverley | Business Management | 43 |
| 2066 | Burrows, Rachel | Canterbury Girls Secondary College | Canterbury | Psychology | 44 |
| 2067 | Burrows, Robyn | Loreto College | Ballarat | Further Mathematics | 42 |
| 2068 | Burrows, Robyn | Loreto College | Ballarat | English | 40 |
| 2069 | Burrows, Robyn | Loreto College | Ballarat | Languages: Japanese Second Language | 40 |
| 2070 | Burrows, Thomas | Ruyton Girls School | Kew | Business Management | 43 |