| 1971 | Bull, Thomas | St Mary MacKillop College | Swan Hill | Sport and Recreation (VCE VET) | 45 |
| 1972 | Bullen, Joshua | Lavalla Catholic College | Traralgon | Visual Communication Design | 41 |
| 1973 | Bullock, Joel | Bendigo Senior Secondary College | Bendigo | Health and Human Development | 43 |
| 1974 | Bullock, Joy | Beaconhills College Berwick | Berwick | Literature | 41 |
| 1975 | Bulman, Adam | Eltham High School | Eltham | Further Mathematics | 47 |
| 1976 | Bulmer, Thomas | Melbourne High School | South Yarra | Further Mathematics | 43 |
| 1977 | Bulmer, Thomas | Melbourne High School | South Yarra | Business Management | 42 |
| 1978 | Bulmer, Thomas | Melbourne High School | South Yarra | English | 40 |
| 1979 | Bulpit, Aurelia | MacRobertson Girls High School | Melbourne | Biology | 41 |
| 1980 | Bumpstead, Stephanie | Sacre Coeur | Glen Iris | Mathematical Methods | 41 |
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| 1981 | Bun, Huy Ngim | Springvale Secondary College | Springvale | Further Mathematics | 41 |
| 1982 | Bunce, Rachel | Parkwood Secondary College | Ringwood North | Health and Human Development | 40 |
| 1983 | Buncle, Alicia | Bendigo Senior Secondary College | Bendigo | English Language | 41 |
| 1984 | Bunn, Cherie | Sunbury College | Sunbury | Hospitality: Food and Beverages (VCE VET) | 43 |
| 1985 | Bunter, Blaire | Sacred Heart Girls College | Hughesdale | Further Mathematics | 40 |
| 1986 | Bunter, Blaire | Sacred Heart Girls College | Hughesdale | Geography | 40 |
| 1987 | Bunting, Christopher | Trinity Grammar School | Kew | English | 43 |
| 1988 | Bunting, Laura | MacRobertson Girls High School | Melbourne | English | 40 |
| 1989 | Bunting, Laura | MacRobertson Girls High School | Melbourne | History: Revolutions | 40 |
| 1990 | Bunting, Sarah | Huntingtower School | Mount Waverley | English | 44 |
| 1991 | Buntz, Kyle | Brighton Grammar School | Brighton | Design and Technology | 42 |
| 1992 | Buntz, Rachel | Firbank Grammar School | Brighton | Health and Human Development | 41 |
| 1993 | Buono, Jamelle | Camberwell High School | Canterbury | English | 40 |
| 1994 | Burak, Steven | Xavier College | Kew | English | 41 |
| 1995 | Burak, Steven | Xavier College | Kew | Texts and Traditions | 40 |
| 1996 | Buras, Julia | Trafalgar High School | Trafalgar | Biology | 48 |
| 1997 | Burattin, Nicole | Mercy College | Coburg | Psychology | 40 |
| 1998 | Burchill, Tom | Beaconhills College Pakenham | Pakenham | Biology | 40 |
| 1999 | Burden, Sasha | Billanook College | Mooroolbark | Media | 45 |
| 2000 | Burden, Sasha | Billanook College | Mooroolbark | English | 44 |
| 2001 | Burden, Sasha | Billanook College | Mooroolbark | Literature | 41 |
| 2002 | Burdett, Jordan | Plenty Valley Christian College | Doreen | Chemistry | 41 |
| 2003 | Burdett, Jordan | Plenty Valley Christian College | Doreen | Mathematical Methods (CAS) | 41 |
| 2004 | Burdett, Jordan | Plenty Valley Christian College | Doreen | Specialist Mathematics | 40 |
| 2005 | Burge, Grace | St Leonards College | Brighton East | Psychology | 43 |
| 2006 | Burge, Jarrod | St Leonards College | Brighton East | Geography | 41 |
| 2007 | Burge, Lauren | Ivanhoe Grammar School Ridgeway | Ivanhoe | Further Mathematics | 44 |
| 2008 | Burge, Thomas | Caulfield Grammar School Caulfield | St Kilda East | English | 40 |
| 2009 | Burge, Thomas | Caulfield Grammar School Caulfield | St Kilda East | Further Mathematics | 40 |
| 2010 | Burger, Benjamin | Xavier College | Kew | English | 41 |
| 2011 | Burger, Benjamin | Xavier College | Kew | Physics | 40 |
| 2012 | Burger, Sarah | Ballarat Clarendon College | Ballarat | Business Management | 43 |
| 2013 | Burger, Sarah | Ballarat Clarendon College | Ballarat | Psychology | 42 |
| 2014 | Burgess, Alice | Tintern Girls Grammar School | Ringwood East | Literature | 42 |
| 2015 | Burgess, Alice | Tintern Girls Grammar School | Ringwood East | Legal Studies | 40 |
| 2016 | Burgess, Ashleigh | Parkwood Secondary College | Ringwood North | History: Revolutions | 43 |
| 2017 | Burgess, Delia | Methodist Ladies College | Kew | Further Mathematics | 49 |
| 2018 | Burgess, Kit | Methodist Ladies College | Kew | Health and Human Development | 40 |
| 2019 | Burgess, Laura | Glenvale School Vic | Epping | Business Administration (VCE VET) | 42 |
| 2020 | Burgess, Nicholas | Scotch College | Hawthorn | English | 42 |