| 1901 | Burke, Cleo | Brunswick Secondary College | Brunswick | Legal Studies | 42 |
| 1902 | Burke, Hannah Paige | Sacred Heart College Geelong | Newtown | Sport and Recreation (VCE VET) | 41 |
| 1903 | Burke, Mia | MacKillop Catholic Regional College | Werribee | Health and Human Development | 45 |
| 1904 | Burke, Mia | MacKillop Catholic Regional College | Werribee | Business Management | 40 |
| 1905 | Burke, Stella Joy | Saint Ignatius College | Drysdale | General Mathematics | 43 |
| 1906 | Burleigh, Maeve Lillian | Belmont High School | Belmont | English | 43 |
| 1907 | Burley, Chloe Elizabeth | Wheelers Hill Secondary College | Wheelers Hill | General Mathematics | 47 |
| 1908 | Burley, Chloe Elizabeth | Wheelers Hill Secondary College | Wheelers Hill | Visual Communication Design | 42 |
| 1909 | Burley, Chloe Elizabeth | Wheelers Hill Secondary College | Wheelers Hill | Theatre Studies | 40 |
| 1910 | Burmas, Caitlin | Emmaus College | Vermont South | Physical Education | 45 |
| |
|||||
| 1911 | Burmas, Caitlin | Emmaus College | Vermont South | English | 44 |
| 1912 | Burmas, Caitlin | Emmaus College | Vermont South | Health and Human Development | 42 |
| 1913 | Burmas, Caitlin | Emmaus College | Vermont South | Biology | 41 |
| 1914 | Burnet, Madeleine Louise | Virtual School Victoria | Thornbury | Ancient History | 43 |
| 1915 | Burnett, Grace Elizabeth | Goulburn Valley Grammar School | Shepparton | Health and Human Development | 41 |
| 1916 | Burns, Archie Edward | Surf Coast Secondary College | Torquay | Food Studies | 42 |
| 1917 | Burns, Caitlin Emily | Ivanhoe Girls Grammar School | Ivanhoe | Psychology | 42 |
| 1918 | Burns, Ella Ashley | Loreto Mandeville Hall | Toorak | English | 50 |
| 1919 | Burns, Ella Ashley | Loreto Mandeville Hall | Toorak | Languages: French | 40 |
| 1920 | Burns, Emily Louise | St Francis Xavier College | Beaconsfield | Sport and Recreation (VCE VET) | 44 |
| 1921 | Burns, Emily Louise | St Francis Xavier College | Beaconsfield | Health and Human Development | 41 |
| 1922 | Burns, Emily Louise | St Francis Xavier College | Beaconsfield | English | 40 |
| 1923 | Burns, Emily Rose | Brighton Secondary College | Brighton East | General Mathematics | 44 |
| 1924 | Burns, Emily Rose | Brighton Secondary College | Brighton East | Visual Communication Design | 40 |
| 1925 | Burrage, Poppy Mae | Glen Eira College | Caulfield East | Physical Education | 41 |
| 1926 | Burrage, Poppy Mae | Glen Eira College | Caulfield East | Art Creative Practice | 40 |
| 1927 | Burridge, Mya Adele | Aquinas College | Ringwood | Health and Human Development | 42 |
| 1928 | Burrows, Benjamin Bob | St Pauls Anglican Grammar School | Warragul | Health and Human Development | 41 |
| 1929 | Burrows, Benjamin Bob | St Pauls Anglican Grammar School | Warragul | Physical Education | 41 |
| 1930 | Burrows, Sienna Carla | Taylors Lakes Secondary College | Taylors Lakes | Legal Studies | 50 |
| 1931 | Burrows, Sienna Carla | Taylors Lakes Secondary College | Taylors Lakes | Physical Education | 40 |
| 1932 | Burrows, Zoe Madison | Padua College | Mornington | Visual Communication Design | 41 |
| 1933 | Burston, Brigid Veronica | Genazzano F.C.J. College | Kew | Media | 42 |
| 1934 | Burston, Zack Matthew | Bacchus Marsh Grammar | Bacchus Marsh | Physical Education | 43 |
| 1935 | Burston, Zack Matthew | Bacchus Marsh Grammar | Bacchus Marsh | English | 42 |
| 1936 | Burt, Declan John | Copperfield College | Delahey | Chemistry | 49 |
| 1937 | Burt, Declan John | Copperfield College | Delahey | Physics | 49 |
| 1938 | Burt, Declan John | Copperfield College | Delahey | Mathematical Methods | 43 |
| 1939 | Burt, Jasmine Alexandra | Sandringham College | Sandringham | Psychology | 40 |
| 1940 | Burton, Jack Anthony Robert | St Francis Xavier College | Beaconsfield | General Mathematics | 40 |
| 1941 | Burton, Josie Barbara | Aquinas College | Ringwood | Food Studies | 42 |
| 1942 | Burton, Madeleine Rose | Westbourne Grammar School | Truganina | General Mathematics | 44 |
| 1943 | Burton, Madeleine Rose | Westbourne Grammar School | Truganina | Physical Education | 42 |
| 1944 | Burton, Thomas | Mentone Grammar School | Mentone | Business Management | 40 |
| 1945 | Bury, Oscar Chadwell | Gippsland Grammar | Sale | English | 40 |
| 1946 | Bushby, Alexander Harry Erich | Melbourne Grammar School | Melbourne | Environmental Science | 41 |
| 1947 | Busse, Kayla Jade | Huntingtower School | Mount Waverley | Food Studies | 46 |
| 1948 | Busse, Kayla Jade | Huntingtower School | Mount Waverley | Chemistry | 45 |
| 1949 | Busse, Kayla Jade | Huntingtower School | Mount Waverley | Biology | 44 |
| 1950 | Busse, Kayla Jade | Huntingtower School | Mount Waverley | Mathematical Methods | 44 |