| 1875 | BUIJS, Declan Rohan | Plenty Valley Christian College | Doreen | Mathematical Methods | 40 |
| 1876 | BUIST, Georgina Darcy | Wesley College Glen Waverley | Glen Waverley | Health and Human Development | 40 |
| 1877 | BUIST, Georgina Darcy | Wesley College Glen Waverley | Glen Waverley | Psychology | 40 |
| 1878 | BUIST, Megan Joan | St Helena Secondary College | Eltham North | Further Mathematics | 42 |
| 1879 | BUIST, Megan Joan | St Helena Secondary College | Eltham North | Psychology | 42 |
| 1880 | BULA, Olivia Amelie | Academy of Mary Immaculate | Fitzroy | Languages: French | 42 |
| 1881 | BULA, Olivia Amelie | Academy of Mary Immaculate | Fitzroy | Languages: Italian | 41 |
| 1882 | BULFORD, Iona Clare | The Geelong College | Newtown | English | 48 |
| 1883 | BULFORD, Iona Clare | The Geelong College | Newtown | Psychology | 48 |
| 1884 | BULFORD, Iona Clare | The Geelong College | Newtown | Languages: French | 41 |
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| 1885 | BULJAT, Martin Stipe | St Bedes College | Mentone | Mathematical Methods | 41 |
| 1886 | BULL, James Roy | Mentone Grammar School | Mentone | Physical Education | 44 |
| 1887 | BULLEN, Grace Marie | Northcote High School | Northcote | Psychology | 42 |
| 1888 | BULLOCK, Erin | Our Lady of Mercy College | Heidelberg | Business Management | 45 |
| 1889 | BULMAN, Amy Eleanor Rose | McKinnon Secondary College | McKinnon | Accounting | 47 |
| 1890 | BULMAN, Amy Eleanor Rose | McKinnon Secondary College | McKinnon | Economics | 44 |
| 1891 | BULMAN, Amy Eleanor Rose | McKinnon Secondary College | McKinnon | English | 40 |
| 1892 | BULMAN, Dillon | St Bedes College | Mentone | History: Revolutions | 45 |
| 1893 | BULT, Katelin Louise | Melbourne Girls Grammar | South Yarra | Biology | 42 |
| 1894 | BUMPSTEAD, Amy Joan | Luther College | Croydon Hills | Health and Human Development | 40 |
| 1895 | BUNAWAN, Rafael Rafka-Sulistio | Victorian School of Languages | Thornbury | Languages: Indonesian Second Language | 42 |
| 1896 | BUNGIRIYA, Isura Umayanga | Nossal High School | Berwick | Accounting | 45 |
| 1897 | BUNN, William Jack | St Bedes College | Mentone | Biology | 41 |
| 1898 | BUNNAGE, Samuel Benjamin | Haileybury College | Keysborough | Further Mathematics | 44 |
| 1899 | BUNNAGE, Samuel Benjamin | Haileybury College | Keysborough | Physical Education | 43 |
| 1900 | BUNNEY, Patrick | Donvale Christian College | Donvale | History: Revolutions | 44 |
| 1901 | BUNNING, Claudia May | Clonard College | Herne Hill | English | 43 |
| 1902 | BUNNING, Claudia May | Clonard College | Herne Hill | Psychology | 42 |
| 1903 | BUNTINE, Hugh Reilly | Peninsula Grammar | Mount Eliza | Mathematical Methods | 44 |
| 1904 | BUNTINE, Hugh Reilly | Peninsula Grammar | Mount Eliza | Physics | 42 |
| 1905 | BUNTING, Grace | Mentone Grammar School | Mentone | Health and Human Development | 45 |
| 1906 | BUNYAMIN, Glenn Jonathan | Melbourne High School | South Yarra | Accounting | 44 |
| 1907 | BURALLI, Matilda | Victorian School of Languages | Thornbury | Languages: Italian | 44 |
| 1908 | BURATTO, Keren Tirzah Indrani | Methodist Ladies College | Kew | English | 41 |
| 1909 | BURGE, Lachlan James | Mazenod College | Mulgrave | English | 40 |
| 1910 | BURGER, Caitlin Rose | Marian College Ararat | Ararat | Physical Education | 41 |
| 1911 | BURGER, Caitlin Rose | Marian College Ararat | Ararat | Sport and Recreation (VCE VET) | 41 |
| 1912 | BURGER, Stephanie Anne | Blackburn High School | Blackburn | Media | 43 |
| 1913 | BURGESS, Chloe Prestonia | Heatherton Christian College | Clarinda | English | 40 |
| 1914 | BURGESS, Emmi Louise | Matthew Flinders Girls Secondary College | Geelong | English | 43 |
| 1915 | BURGESS, Emmi Louise | Matthew Flinders Girls Secondary College | Geelong | Further Mathematics | 40 |
| 1916 | BURGESS, Liam Allan | Brauer College | Warrnambool | Physical Education | 43 |
| 1917 | BURGESS, Max Ray | Mazenod College | Mulgrave | Further Mathematics | 42 |
| 1918 | BURGESS-HOAR, Ruby Blanche | Geelong Grammar School | Corio | Geography | 41 |
| 1919 | BURKE, Alice Grace | Haileybury Girls College | Keysborough | Systems Engineering | 43 |
| 1920 | BURKE, Buddy Lulu | Caulfield Grammar School Caulfield | St Kilda East | Legal Studies | 41 |
| 1921 | BURKE, Ella Grace | Star of the Sea College | Brighton | Health and Human Development | 44 |
| 1922 | BURKE, Liam Michael | Parkdale Secondary College | Mordialloc | Legal Studies | 40 |
| 1923 | BURKE, Liam Shannon | St Kevins College | Toorak | Business Management | 40 |
| 1924 | BURKE, Nicholas Kevin | Haileybury College | Keysborough | English | 50 |