| 1919 | BROWNING, Hailey | Frankston High School | Frankston | Art | 44 |
| 1920 | BROWNING, Sasha Jay | Luther College | Croydon Hills | English | 42 |
| 1921 | BROWNING, Sasha Jay | Luther College | Croydon Hills | Health and Human Development | 41 |
| 1922 | BROWNING, Sasha Jay | Luther College | Croydon Hills | Biology | 40 |
| 1923 | BROWNING, Zaki | Trinity Grammar School | Kew | Psychology | 47 |
| 1924 | BROWNING, Zaki | Trinity Grammar School | Kew | English | 41 |
| 1925 | BROWNING, Zaki | Trinity Grammar School | Kew | Economics | 40 |
| 1926 | BROWNLEE, Charlotte | St Michaels Grammar School | St Kilda | Food Studies | 42 |
| 1927 | BROZEK, Harry Jacob | Kardinia International College | Bell Post Hill | Further Mathematics | 45 |
| 1928 | BROZEK, Harry Jacob | Kardinia International College | Bell Post Hill | Physical Education | 45 |
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| 1929 | BRUCE, Jordyn Alexandra | Mentone Girls Secondary College | Mentone | Health and Human Development | 43 |
| 1930 | BRUCE, Livinia Alice | Kilvington Grammar School | Ormond | Biology | 43 |
| 1931 | BRUGLIERA, Isabelle Aurora Rose | Genazzano F.C.J. College | Kew | Biology | 50 |
| 1932 | BRUMBAUGH, Grace Linsey | Frankston High School | Frankston | Food Studies | 45 |
| 1933 | BRUNI, Odette Tara | Monivae College | Hamilton | Hospitality: Kitchen Operations (VCE VET) | 41 |
| 1934 | BRUNNING-HALSALL, Lucas Shelton | Northcote High School | Northcote | Legal Studies | 40 |
| 1935 | BRUNO, Antonia Isabelle | Haileybury Girls College | Keysborough | English | 44 |
| 1936 | BRUNO, Antonia Isabelle | Haileybury Girls College | Keysborough | Sociology | 43 |
| 1937 | BRUNO, Antonia Isabelle | Haileybury Girls College | Keysborough | Psychology | 40 |
| 1938 | BRUSCH, Ibby Inaya | St Michaels Grammar School | St Kilda | Literature | 48 |
| 1939 | BRUSCH, Ibby Inaya | St Michaels Grammar School | St Kilda | Media | 42 |
| 1940 | BRUSCH, Ibby Inaya | St Michaels Grammar School | St Kilda | Philosophy | 41 |
| 1941 | BRYAN, Caitlin Victoria | Methodist Ladies College | Kew | Studio Arts | 42 |
| 1942 | BRYAN, Callum George | Haileybury College | Keysborough | English | 45 |
| 1943 | BRYAN, Callum George | Haileybury College | Keysborough | Global Politics | 41 |
| 1944 | BRYANT, Ethan | Kew High School | Kew East | English | 41 |
| 1945 | BRYCE, Logan Bain | Belmont High School | Belmont | Software Development | 41 |
| 1946 | BRYCE, William Christopher | Xavier College | Kew | Further Mathematics | 41 |
| 1947 | BRYDSON, Amelia Rose | Sunbury Downs Secondary College | Sunbury | Legal Studies | 41 |
| 1948 | BRYDSON, Amelia Rose | Sunbury Downs Secondary College | Sunbury | English | 40 |
| 1949 | BSM, Vishiwaharen | McKinnon Secondary College | McKinnon | Further Mathematics | 48 |
| 1950 | BSM, Vishiwaharen | McKinnon Secondary College | McKinnon | Physics | 41 |
| 1951 | BSM, Vishiwaharen | McKinnon Secondary College | McKinnon | Chemistry | 40 |
| 1952 | BU, Xuhan | Caulfield Grammar School Wheelers Hill | Wheelers Hill | Studio Arts | 45 |
| 1953 | BU, Xuhan | Caulfield Grammar School Wheelers Hill | Wheelers Hill | Visual Communication Design | 44 |
| 1954 | BU, Xuhan | Caulfield Grammar School Wheelers Hill | Wheelers Hill | English | 42 |
| 1955 | BUBB, Cameron Claude | McKinnon Secondary College | McKinnon | Business Management | 42 |
| 1956 | BUBB, Grace Elizabeth | Rochester Secondary College | Rochester | Health and Human Development | 40 |
| 1957 | BUCCELLA, Lorena Giulia | Sacre Coeur | Glen Iris | Psychology | 44 |
| 1958 | BUCCELLA, Lorena Giulia | Sacre Coeur | Glen Iris | Geography | 42 |
| 1959 | BUCHANAN, Lucy | Camberwell Girls Grammar School | Canterbury | Theatre Studies | 40 |
| 1960 | BUCHANAN, Thomas Harry | Scotch College | Hawthorn | Australian History | 43 |
| 1961 | BUCHHOLZ, Max | Victorian School of Languages | Thornbury | Languages: German | 48 |
| 1962 | BUCK, James Charles | St Josephs College Ferntree Gully | Ferntree Gully | Sport and Recreation (VCE VET) | 41 |
| 1963 | BUCK, Maxwell Frank | Emmanuel College Melbourne | Altona North | Physical Education | 40 |
| 1964 | BUCKERIDGE, Sophie Grace | Star of the Sea College | Brighton | English | 47 |
| 1965 | BUCKERIDGE, Sophie Grace | Star of the Sea College | Brighton | Chemistry | 46 |
| 1966 | BUCKERIDGE, Sophie Grace | Star of the Sea College | Brighton | Mathematical Methods | 46 |
| 1967 | BUCKERIDGE, Sophie Grace | Star of the Sea College | Brighton | Specialist Mathematics | 45 |
| 1968 | BUCKI-SMITH, Thomas James | St Josephs College Geelong | Newtown | Visual Communication Design | 45 |