| 2007 | BUN, Leanne | John Monash Science School | Clayton | Biology | 44 |
| 2008 | BUNBURY SMITH, Indigo | Kew High School | Kew East | Further Mathematics | 40 |
| 2009 | BUNCE, Jarman | Mount Waverley Secondary College | Mount Waverley | Further Mathematics | 40 |
| 2010 | BUNDEY, Callum Edward Myles | Melbourne Grammar School | Melbourne | IT Applications | 45 |
| 2011 | BUNGAY, Nikita | Presbyterian Ladies College | Burwood | English | 44 |
| 2012 | BUNGE, Lucinda Rose | The Hamilton and Alexandra College | Hamilton | English | 44 |
| 2013 | BUNGIRIYA, Chathuni Ravinga | Victorian School of Languages | Thornbury | Languages: Sinhala | 40 |
| 2014 | BUNGLA, Sumit | John Monash Science School | Clayton | Mathematical Methods (CAS) | 41 |
| 2015 | BUNGLA, Sumit | John Monash Science School | Clayton | Physics | 41 |
| 2016 | BUNKER, Ronald Maximillion | The Geelong College | Newtown | Physics | 41 |
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| 2017 | BUNN, Cameron Daniel | Princes Hill Secondary College | Princes Hill | Further Mathematics | 41 |
| 2018 | BUNN, Cameron Daniel | Princes Hill Secondary College | Princes Hill | English | 40 |
| 2019 | BUNNAGE, Timothy Peter | Box Hill High School | Box Hill | Mathematical Methods (CAS) | 41 |
| 2020 | BUNNEY, Matthew | University High School | Parkville | Chemistry | 42 |
| 2021 | BUNNEY, Matthew | University High School | Parkville | Specialist Mathematics | 42 |
| 2022 | BUNNEY, Matthew | University High School | Parkville | English | 41 |
| 2023 | BUNNEY, Matthew | University High School | Parkville | Physics | 40 |
| 2024 | BUNSTON, Zachary Mark | Trinity Grammar School | Kew | Studio Arts | 42 |
| 2025 | BUNTINE, Charles John Ross | Scotch College | Hawthorn | English | 47 |
| 2026 | BUNTINE, Charles John Ross | Scotch College | Hawthorn | Psychology | 47 |
| 2027 | BUNTINE, Charles John Ross | Scotch College | Hawthorn | Literature | 41 |
| 2028 | BURCHETT, Hannah Jane | The Geelong College | Newtown | English | 40 |
| 2029 | BURCHETT, Linda Jane | Yarra Valley Grammar School | Ringwood | Music Performance | 42 |
| 2030 | BURCHILL, Zoe Alexandra | St Leonards College | Brighton East | Psychology | 45 |
| 2031 | BURCHILL, Zoe Alexandra | St Leonards College | Brighton East | English | 44 |
| 2032 | BURCHILL, Zoe Alexandra | St Leonards College | Brighton East | History: Revolutions | 42 |
| 2033 | BURFORD, Monika Barbara | Padua College | Mornington | Further Mathematics | 42 |
| 2034 | BURGE, Curtis Jack | St Bedes College | Mentone | Music Technical Production (VCE VET) | 40 |
| 2035 | BURGE, Mikayla Bree | St Mary MacKillop College | Swan Hill | Sport and Recreation (VCE VET) | 41 |
| 2036 | BURGEN, Paris | Lowther Hall Anglican Grammar School | Essendon | Psychology | 40 |
| 2037 | BURGER, Sarah Jacqueline | Fintona Girls School | Balwyn | Biology | 50 |
| 2038 | BURGESS, Aleisha Nicole | Yarra Valley Grammar School | Ringwood | Legal Studies | 43 |
| 2039 | BURGESS, Christopher George | St Leonards College | Brighton East | Music Investigation | 50 |
| 2040 | BURGESS, Christopher George | St Leonards College | Brighton East | Theatre Studies | 42 |
| 2041 | BURGESS, Christopher George | St Leonards College | Brighton East | English | 40 |
| 2042 | BURGESS, Jayden Edward | Ballarat Grammar School | Wendouree | Product Design and Technology | 44 |
| 2043 | BURGESS, Layla Jacqualyn | Ballarat High School | Ballarat | Community Services (VCE VET) | 40 |
| 2044 | BURGESS, Michael John | St Kevins College | Toorak | Mathematical Methods (CAS) | 47 |
| 2045 | BURGESS, Shanii Maree | Mildura Senior College | Mildura | Community Services (VCE VET) | 41 |
| 2046 | BURGIN, Amy Allegra | Caulfield Grammar School Caulfield | St Kilda East | Health and Human Development | 41 |
| 2047 | BURKE, Elizabeth Kathleen | Korowa Anglican Girls School | Glen Iris | History: Revolutions | 41 |
| 2048 | BURKE, Hannah | Loreto Mandeville Hall | Toorak | Chemistry | 43 |
| 2049 | BURKE, Hannah | Loreto Mandeville Hall | Toorak | English | 43 |
| 2050 | BURKE, Hannah | Loreto Mandeville Hall | Toorak | Physics | 42 |
| 2051 | BURKE, Hannah | Loreto Mandeville Hall | Toorak | Specialist Mathematics | 41 |
| 2052 | BURKE, Jack | Whitefriars College | Donvale | Religion and Society | 44 |
| 2053 | BURKE, Lily Josephine | Catholic College Bendigo | Bendigo | Physical Education | 41 |
| 2054 | BURKE, Thomas Alan | Euroa Secondary College | Euroa | Sport and Recreation (VCE VET) | 40 |
| 2055 | BURKHARDT, Emily Jayne | Westbourne Grammar School | Truganina | Media | 45 |
| 2056 | BURKHARDT, Emily Jayne | Westbourne Grammar School | Truganina | English | 44 |