| 1876 | Brodrick, Olivia | Sacred Heart College Geelong | Newtown | Further Mathematics | 44 |
| 1877 | Brodrick, Olivia | Sacred Heart College Geelong | Newtown | Physical Education | 43 |
| 1878 | Brodrick, Olivia | Sacred Heart College Geelong | Newtown | English | 40 |
| 1879 | Broeckx, Jacqueline | Braemar College | Woodend | Health and Human Development | 40 |
| 1880 | Broekman, Elena | Emmanuel College Warrnambool | Warrnambool | Outdoor and Environmental Studies | 42 |
| 1881 | Brokenshire, Anna | Donvale Christian College | Donvale | Further Mathematics | 43 |
| 1882 | Bromley, Luke | Xavier College | Kew | English | 43 |
| 1883 | Bromley, Luke | Xavier College | Kew | Languages: French | 43 |
| 1884 | Bromley, Luke | Xavier College | Kew | Chemistry | 41 |
| 1885 | Broner, Rebecca | Beth Rivkah Ladies College | St Kilda East | Further Mathematics | 47 |
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| 1886 | Broner, Rebecca | Beth Rivkah Ladies College | St Kilda East | Mathematical Methods (CAS) | 41 |
| 1887 | Brook, Henri | Luther College | Croydon Hills | Business Management | 44 |
| 1888 | Brooke, Kit | Yarra Valley Grammar School | Ringwood | Further Mathematics | 41 |
| 1889 | Brooke, Nicholas | Koonung Secondary College | Mont Albert North | Media | 44 |
| 1890 | Brooke, Nicholas | Koonung Secondary College | Mont Albert North | Biology | 42 |
| 1891 | Brooker, Alyce | Beaconhills College Berwick | Berwick | Media | 40 |
| 1892 | Brooks, Caitlin | Victorian School of Languages | Thornbury | Languages: German | 41 |
| 1893 | Brooks, Rebecca | Loreto College | Ballarat | Physical Education | 40 |
| 1894 | Brooks, Rhiannon | Overnewton Anglican College | Keilor | Drama | 45 |
| 1895 | Broom, Courtney | Essendon Keilor College Essendon Campus | Essendon | Health and Human Development | 41 |
| 1896 | Broome, Sebastian | Melbourne Grammar School | Melbourne | English | 50 |
| 1897 | Broome, Sebastian | Melbourne Grammar School | Melbourne | Literature | 49 |
| 1898 | Broome, Sebastian | Melbourne Grammar School | Melbourne | Languages: French | 41 |
| 1899 | Broome, Sebastian | Melbourne Grammar School | Melbourne | Mathematical Methods (CAS) | 41 |
| 1900 | Broomfield, Grace | Kilvington Grammar School | Ormond | Legal Studies | 40 |
| 1901 | Broomfield, Grace | Kilvington Grammar School | Ormond | Physical Education | 40 |
| 1902 | Brougham, Aaron | Salesian College Chadstone | Chadstone | English | 41 |
| 1903 | Broughton, Lochlan | Belmont High School | Belmont | IT Applications | 41 |
| 1904 | Broughton, Lochlan | Belmont High School | Belmont | Further Mathematics | 40 |
| 1905 | Brouwer, Haydn | Peninsula Grammar | Mount Eliza | Further Mathematics | 43 |
| 1906 | Brown, Amelia | St Peters College | Cranbourne | Psychology | 42 |
| 1907 | Brown, Brigid | Genazzano F.C.J. College | Kew | English | 42 |
| 1908 | Brown, Brigitte | Koo Wee Rup Secondary College | Koo Wee Rup | Psychology | 41 |
| 1909 | Brown, Brigitte | Koo Wee Rup Secondary College | Koo Wee Rup | Further Mathematics | 40 |
| 1910 | Brown, Chloe | Marist Sion College | Warragul | Studio Arts | 40 |
| 1911 | Brown, David | Luther College | Croydon Hills | Outdoor and Environmental Studies | 44 |
| 1912 | Brown, David | Luther College | Croydon Hills | IT Applications | 40 |
| 1913 | Brown, Douglas | Camberwell Grammar School | Canterbury | Engineering Studies (Certificate II) | 44 |
| 1914 | Brown, Emily | Beaconhills College Pakenham | Pakenham | English | 43 |
| 1915 | Brown, Gabriella | Forest Hill College | Burwood East | Media | 40 |
| 1916 | Brown, Georgia | Melbourne Girls Grammar | South Yarra | Business Management | 40 |
| 1917 | Brown, Hannah | Dandenong High School Dandenong | Dandenong | Dance | 40 |
| 1918 | Brown, Hayden | University High School | Parkville | Music Performance | 44 |
| 1919 | Brown, Jasper | Melbourne Rudolf Steiner School | Warranwood | English | 42 |
| 1920 | Brown, Jeremy | Camberwell Grammar School | Canterbury | Literature | 49 |
| 1921 | Brown, Jeremy | Camberwell Grammar School | Canterbury | Legal Studies | 43 |
| 1922 | Brown, Justin | Goulburn Valley Grammar School | Shepparton | Physical Education | 41 |
| 1923 | Brown, Lachlan | Scotch College | Hawthorn | Geography | 42 |
| 1924 | Brown, Lachlan | Oberon High School | Armstrong Creek | Physical Education | 42 |
| 1925 | Brown, Lachlan | Oberon High School | Armstrong Creek | Physics | 42 |