| 1853 | Brighthope, Sarah-Jane | Melbourne Girls Grammar | South Yarra | Business Management | 43 |
| 1854 | Brindle, Sarah | Wesley College Glen Waverley | Glen Waverley | Psychology | 42 |
| 1855 | Brindle, Sarah | Wesley College Glen Waverley | Glen Waverley | Studio Arts | 41 |
| 1856 | Brindle, Sarah | Wesley College Glen Waverley | Glen Waverley | English | 40 |
| 1857 | Brinkworth, Kirsten | Wesley College St Kilda Rd | Melbourne | Physical Education | 42 |
| 1858 | Brisbane, Samuel | Eltham High School | Eltham | Further Mathematics | 47 |
| 1859 | Briscomb, Bede | Box Hill Senior Secondary College | Mont Albert North | Business Management | 41 |
| 1860 | Briscomb, Bede | Box Hill Senior Secondary College | Mont Albert North | Accounting | 40 |
| 1861 | Brittain, Zoe | Mount Erin College | Frankston South | Drama | 46 |
| 1862 | Britto, Geoffrey | The Knox School | Wantirna South | Further Mathematics | 41 |
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| 1863 | Brkic, Claudia | St Catherines School | Toorak | English | 46 |
| 1864 | Brkic, Claudia | St Catherines School | Toorak | Literature | 41 |
| 1865 | Broadbent, Edward | McKinnon Secondary College | McKinnon | Media | 42 |
| 1866 | Broadbent, Edward | McKinnon Secondary College | McKinnon | Health and Human Development | 41 |
| 1867 | Broadbent, Hayden | Brighton Secondary College | Brighton East | Food and Technology | 48 |
| 1868 | Broadbent-Hogan, Moriah | Wesley College St Kilda Rd | Melbourne | Further Mathematics | 41 |
| 1869 | Broadfoot, William | The Hamilton and Alexandra College | Hamilton | Further Mathematics | 41 |
| 1870 | Broadway, Jordan | Christian Brothers College | St Kilda East | Drama | 43 |
| 1871 | Brock, Emily | Penleigh and Essendon Grammar School | Keilor East | Accounting | 49 |
| 1872 | Brock, Emily | Penleigh and Essendon Grammar School | Keilor East | Economics | 42 |
| 1873 | Brodie, Rachael | Warrnambool College | Warrnambool | Outdoor and Environmental Studies | 44 |
| 1874 | Brodie, Rachael | Warrnambool College | Warrnambool | English | 41 |
| 1875 | Brodrick, Caleb | Aquinas College | Ringwood | IT Applications | 44 |
| 1876 | Brodrick, Olivia | Sacred Heart College Geelong | Newtown | Further Mathematics | 44 |
| 1877 | Brodrick, Olivia | Sacred Heart College Geelong | Newtown | Physical Education | 43 |
| 1878 | Brodrick, Olivia | Sacred Heart College Geelong | Newtown | English | 40 |
| 1879 | Broeckx, Jacqueline | Braemar College | Woodend | Health and Human Development | 40 |
| 1880 | Broekman, Elena | Emmanuel College Warrnambool | Warrnambool | Outdoor and Environmental Studies | 42 |
| 1881 | Brokenshire, Anna | Donvale Christian College | Donvale | Further Mathematics | 43 |
| 1882 | Bromley, Luke | Xavier College | Kew | English | 43 |
| 1883 | Bromley, Luke | Xavier College | Kew | Languages: French | 43 |
| 1884 | Bromley, Luke | Xavier College | Kew | Chemistry | 41 |
| 1885 | Broner, Rebecca | Beth Rivkah Ladies College | St Kilda East | Further Mathematics | 47 |
| 1886 | Broner, Rebecca | Beth Rivkah Ladies College | St Kilda East | Mathematical Methods (CAS) | 41 |
| 1887 | Brook, Henri | Luther College | Croydon Hills | Business Management | 44 |
| 1888 | Brooke, Kit | Yarra Valley Grammar School | Ringwood | Further Mathematics | 41 |
| 1889 | Brooke, Nicholas | Koonung Secondary College | Mont Albert North | Media | 44 |
| 1890 | Brooke, Nicholas | Koonung Secondary College | Mont Albert North | Biology | 42 |
| 1891 | Brooker, Alyce | Beaconhills College Berwick | Berwick | Media | 40 |
| 1892 | Brooks, Caitlin | Victorian School of Languages | Thornbury | Languages: German | 41 |
| 1893 | Brooks, Rebecca | Loreto College | Ballarat | Physical Education | 40 |
| 1894 | Brooks, Rhiannon | Overnewton Anglican College | Keilor | Drama | 45 |
| 1895 | Broom, Courtney | Essendon Keilor College Essendon Campus | Essendon | Health and Human Development | 41 |
| 1896 | Broome, Sebastian | Melbourne Grammar School | Melbourne | English | 50 |
| 1897 | Broome, Sebastian | Melbourne Grammar School | Melbourne | Literature | 49 |
| 1898 | Broome, Sebastian | Melbourne Grammar School | Melbourne | Languages: French | 41 |
| 1899 | Broome, Sebastian | Melbourne Grammar School | Melbourne | Mathematical Methods (CAS) | 41 |
| 1900 | Broomfield, Grace | Kilvington Grammar School | Ormond | Legal Studies | 40 |
| 1901 | Broomfield, Grace | Kilvington Grammar School | Ormond | Physical Education | 40 |
| 1902 | Brougham, Aaron | Salesian College Chadstone | Chadstone | English | 41 |