| 1872 | Brooks, James | Whitefriars College | Donvale | National Politics | 44 |
| 1873 | Brooks, Melanie | Sacred Heart College Geelong | Newtown | Health and Human Development | 41 |
| 1874 | Broome, Eliza | Loreto Mandeville Hall | Toorak | English | 48 |
| 1875 | Broome, Eliza | Loreto Mandeville Hall | Toorak | Economics | 46 |
| 1876 | Broome, Eliza | Loreto Mandeville Hall | Toorak | National Politics | 44 |
| 1877 | Broome, Eliza | Loreto Mandeville Hall | Toorak | Literature | 41 |
| 1878 | Broomhall, Sarah | Upwey High School | Upwey | Further Mathematics | 41 |
| 1879 | Broomhall, Sarah | Upwey High School | Upwey | English | 40 |
| 1880 | Brotchie, James | The Geelong College | Newtown | Further Mathematics | 40 |
| 1881 | Brott, Chantelle | The King David School | Armadale | Religion and Society | 46 |
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| 1882 | Brouwer, Jessica | Toorak College | Mount Eliza | Studio Arts | 47 |
| 1883 | Brouwer, Jessica | Toorak College | Mount Eliza | English | 44 |
| 1884 | Brouwer, Jessica | Toorak College | Mount Eliza | Further Mathematics | 42 |
| 1885 | Brouwer, Jessica | Toorak College | Mount Eliza | Psychology | 40 |
| 1886 | Brown, Alexandra | Siena College | Camberwell | Mathematical Methods | 42 |
| 1887 | Brown, Alexandra | Siena College | Camberwell | English | 41 |
| 1888 | Brown, Alexandra | Siena College | Camberwell | Drama | 40 |
| 1889 | Brown, Amy | St Columbas College | Essendon | Physical Education | 40 |
| 1890 | Brown, Andrew | Mount Eliza Secondary College | Mount Eliza | Further Mathematics | 46 |
| 1891 | Brown, Candice | MacKillop Catholic Regional College | Werribee | Australian History | 41 |
| 1892 | Brown, Connie | Eltham High School | Eltham | Business Management | 41 |
| 1893 | Brown, Derek | Yarra Hills Secondary College Mooroolbark | Mooroolbark | Software Development | 44 |
| 1894 | Brown, Durham | St Leonards College | Brighton East | Further Mathematics | 47 |
| 1895 | Brown, Eleanor | Methodist Ladies College | Kew | Languages: French | 44 |
| 1896 | Brown, Ellen | Padua College | Mornington | Design and Technology | 40 |
| 1897 | Brown, Hannah | Melbourne Girls College | Richmond | Health and Human Development | 50 |
| 1898 | Brown, Harriet | The Geelong College | Newtown | Further Mathematics | 46 |
| 1899 | Brown, James | Melbourne High School | South Yarra | English | 43 |
| 1900 | Brown, James | Melbourne High School | South Yarra | Further Mathematics | 41 |
| 1901 | Brown, Jessie-Lee | Healesville High School | Healesville | Further Mathematics | 41 |
| 1902 | Brown, Lauren | Mount Lilydale Mercy College | Lilydale | Business Management | 41 |
| 1903 | Brown, Liam | Scotch College | Hawthorn | Design and Technology | 43 |
| 1904 | Brown, Lisa | Sacre Coeur | Glen Iris | Biology | 40 |
| 1905 | Brown, Lucy | Assumption College | Kilmore | Further Mathematics | 40 |
| 1906 | Brown, Nicolas | Victorian School of Languages | Thornbury | Languages: Spanish | 50 |
| 1907 | Brown, Nicolas | University High School | Parkville | History: Revolutions | 41 |
| 1908 | Brown, Rachel | University High School | Parkville | Mathematical Methods | 41 |
| 1909 | Brown, Sally | St Pauls Anglican Grammar School | Warragul | Drama | 46 |
| 1910 | Brown, Sara | Box Hill High School | Box Hill | Psychology | 43 |
| 1911 | Brown, Sara | Sacre Coeur | Glen Iris | IT Applications | 40 |
| 1912 | Brown, Sara | Box Hill High School | Box Hill | Literature | 40 |
| 1913 | Brown, Shane | Mazenod College | Mulgrave | English | 50 |
| 1914 | Brown, Simon | Goulburn Valley Grammar School | Shepparton | Further Mathematics | 48 |
| 1915 | Brown, Simon | Scotch College | Hawthorn | Physical Education | 44 |
| 1916 | Brown, Simon | Goulburn Valley Grammar School | Shepparton | Mathematical Methods | 41 |
| 1917 | Brown, Sonja | Oxley Christian College | Chirnside Park | Further Mathematics | 46 |
| 1918 | Brown, Sonja | Oxley Christian College | Chirnside Park | Visual Communication Design | 43 |
| 1919 | Brown, Tegan | Berwick Secondary College | Berwick | Physical Education | 46 |
| 1920 | Brown, Timothy | St Josephs College Ferntree Gully | Ferntree Gully | Further Mathematics | 44 |
| 1921 | Brown-Greaves, Caroline | Melbourne Girls Grammar | South Yarra | Further Mathematics | 42 |