| 1993 | Buchholz, Elizabeth | Mercy Regional College | Camperdown | Further Mathematics | 47 |
| 1994 | Buchholz, Vanessa | Derrinallum P-12 College | Derrinallum | Health and Human Development | 48 |
| 1995 | Buchholz, Vanessa | Derrinallum P-12 College | Derrinallum | English | 40 |
| 1996 | Buckland, Dale | Beaconhills College Pakenham | Pakenham | Physics | 42 |
| 1997 | Buckland, Dale | Beaconhills College Pakenham | Pakenham | Mathematical Methods | 40 |
| 1998 | Buckland, Rachel | Beaconhills College Pakenham | Pakenham | Chemistry | 40 |
| 1999 | Buckle, Gabrielle | Ivanhoe Girls Grammar School | Ivanhoe | Music Solo Performance | 40 |
| 2000 | Buckley, Ellen | University High School | Parkville | Physical Education | 50 |
| 2001 | Buckley, Gemma | Sandringham College | Sandringham | Media | 49 |
| 2002 | Buckley, Gemma | Sandringham College | Sandringham | Psychology | 45 |
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| 2003 | Buckley, Joseph | Trinity Grammar School | Kew | English | 43 |
| 2004 | Buckley, Joseph | Trinity Grammar School | Kew | Mathematical Methods | 42 |
| 2005 | Buckley, Ryan | Ivanhoe Grammar School Ridgeway | Ivanhoe | English | 44 |
| 2006 | Buckley, Ryan | Ivanhoe Grammar School Ridgeway | Ivanhoe | Further Mathematics | 43 |
| 2007 | Bucknall, Joshua | Brighton Grammar School | Brighton | English | 41 |
| 2008 | Bucknall, Joshua | Brighton Grammar School | Brighton | History: Revolutions | 40 |
| 2009 | Bucknall, Joshua | Brighton Grammar School | Brighton | Literature | 40 |
| 2010 | Buczek, Radoslaw | Mazenod College | Mulgrave | Religion and Society | 41 |
| 2011 | Budge, Sarah | Mentone Girls Secondary College | Mentone | Psychology | 40 |
| 2012 | Budge, Timothy | Haileybury College | Keysborough | Business Management | 45 |
| 2013 | Budge, Timothy | Haileybury College | Keysborough | Physical Education | 41 |
| 2014 | Budiman, Jeff | Christian Brothers College | St Kilda East | Further Mathematics | 42 |
| 2015 | Buerfeind, Eleanor | Luther College | Croydon Hills | Business Management | 49 |
| 2016 | Buffett, Elizabeth | Catholic College Bendigo | Bendigo | English | 40 |
| 2017 | Bugden, Sarah | Damascus College | Mount Clear | Languages: French | 46 |
| 2018 | Bugden, Sarah | Damascus College | Mount Clear | History: Renaissance Italy | 44 |
| 2019 | Bugden, Sarah | Damascus College | Mount Clear | Further Mathematics | 42 |
| 2020 | Bugden, Sarah | Damascus College | Mount Clear | English | 41 |
| 2021 | Bugeja, Andrew | Penola Catholic College | Broadmeadows | Information Processing and Management | 42 |
| 2022 | Buhagiar, Michela | Our Lady of Sacred Heart College | Bentleigh | Languages: Italian | 47 |
| 2023 | Bui Tran, Kieu | Mount Alexander 7-12 College | Flemington | Multimedia (VCE VET) | 41 |
| 2024 | Bui, Long | Buckley Park College | Essendon | Media | 41 |
| 2025 | Bui, Viet-My | Macrobertson Girls High School | Melbourne | English | 48 |
| 2026 | Bui, Viet-My | Macrobertson Girls High School | Melbourne | Visual Communication Design | 46 |
| 2027 | Bui, Viet-My | Macrobertson Girls High School | Melbourne | Literature | 45 |
| 2028 | Bulafkin, Joshua | Mount Scopus Memorial College | Burwood | Health and Human Development | 45 |
| 2029 | Bulafkin, Joshua | Mount Scopus Memorial College | Burwood | English | 40 |
| 2030 | Bull, Emily | The Geelong College | Newtown | Further Mathematics | 45 |
| 2031 | Bull, Jacqueline | Sacre Coeur | Glen Iris | Physical Education | 48 |
| 2032 | Bull, Joanne | Padua College | Mornington | English | 43 |
| 2033 | Bull, Joanne | Padua College | Mornington | Mathematical Methods | 41 |
| 2034 | Bull, Lauren | Essendon Keilor College Essendon Campus | Essendon | English | 41 |
| 2035 | Bull, Matthew | Strathmore Secondary College | Strathmore | Business Management | 40 |
| 2036 | Bullard, Andrew | Padua College | Mornington | Further Mathematics | 43 |
| 2037 | Bulmer, Amy | Canterbury Girls Secondary College | Canterbury | Psychology | 42 |
| 2038 | Bulzomi, Louie | Robinvale College | Robinvale | Accounting | 41 |
| 2039 | Bulzomi, Louie | Robinvale College | Robinvale | Business Management | 41 |
| 2040 | Bulzomi, Louie | Distance Education Centre Victoria | Thornbury | Legal Studies | 40 |
| 2041 | Bumpstead, Nicole | Glenvale School Vic | Epping | Business Administration (VCE VET) | 46 |
| 2042 | Bunn, Amanda | Maranatha Christian School | Endeavour Hills | Visual Communication Design | 42 |
Last Updated: 5 Oct 2023