Below is the list of the best HSC students in 2021 ranked in order of their total number of subjects awarded.
A subject award can be either a Distinguished Achiever award or a Subject Rank award (top place in subject).
Where students have equal numbers of subject awards, those with an All Rounder award are ranked higher. As additional tie-breakers, Subject Rank awards are ranked by their place value and they are also ranked higher than Distinguished Achiever awards. Where all of these measures are equal, entries are listed alphabetically.
Note that these rankings are calculated using only the published results for 2021. A student's awards from any earlier years, if any, are not not included here.
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| 1 | Woo, Aidan | Sydney Grammar School | Darlinghurst | 9 | Yes | |
| 2 | Carungay, Abigail Bennett | James Ruse Agricultural High School | Carlingford | 9 | Yes | |
| 3 | Bowes, Cian Buo-Jren | Sydney Grammar School | Darlinghurst | 8 | Yes | |
| 4 | Mesimeris, Isander | Sydney Grammar School | Darlinghurst | 8 | Yes | |
| 5 | Landfear, Riley | Sydney Grammar School | Darlinghurst | 8 | Yes | |
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| 6 | Coffey, Katherine | Shire Christian School | Barden Ridge | 8 | Yes | |
| 7 | McKenzie, Charlotte | Smiths Hill High School | Wollongong | 8 | Yes | |
| 8 | Stala-Smith, Joseph | North Sydney Boys High School | Crows Nest | 8 | Yes | |
| 9 | Desai, Anjalee | Kambala | Rose Bay | 8 | Yes | |
| 10 | Paton, Mayling Natalie Vera | Kambala | Rose Bay | 8 | Yes | |
| 11 | Levison, Luke | Sydney Grammar School | Darlinghurst | 8 | Yes | |
| 12 | Brindley, Oliver | Sydney Grammar School | Darlinghurst | 8 | Yes | |
| 13 | Broinowski, Ava Rocka | Sydney Girls High School | Surry Hills | 8 | Yes | |
| 14 | Halliday Shand, Rachel | Ravenswood School for Girls | Gordon | 7 | Yes | |
| 15 | Airey, Alysha | Northern Beaches Secondary College Manly Campus | North Curl Curl | 7 | Yes | |
| 16 | Choy, Ethan | Sydney Grammar School | Darlinghurst | 7 | Yes | |
| 17 | Di Bello, Serenna | Pymble Ladies College | Pymble | 7 | Yes | |
| 18 | Tang, Rena Lin | Meriden School | Strathfield | 7 | Yes | |
| 19 | Yehuda, Shanni | Sydney Girls High School | Surry Hills | 7 | Yes | |
| 20 | Lin, Daniel | Sydney Grammar School | Darlinghurst | 7 | Yes | |
| 21 | Wong, Marcus | Sydney Grammar School | Darlinghurst | 7 | Yes | |
| 22 | Van Es-Dickman, Liam | Sydney Grammar School | Darlinghurst | 7 | Yes | |
| 23 | Huynh, Justin | Sydney Grammar School | Darlinghurst | 7 | Yes | |
| 24 | Karantanis, Marie | SCEGGS Darlinghurst | Darlinghurst | 7 | Yes | |
| 25 | Sebastian, Elanah Sarita | Catherine McAuley Westmead | Westmead | 7 | Yes | |
Supplementary data from school publications.