| 1791 | Merewether High School | Broadmeadow | English Extension 2 | 5 |
| 1792 | Merewether High School | Broadmeadow | Modern History | 5 |
| 1793 | Meriden School | Strathfield | Drama | 5 |
| 1794 | Meriden School | Strathfield | Legal Studies | 5 |
| 1795 | MLC School | Burwood | Modern History | 5 |
| 1796 | MLC School | Burwood | Personal Development, Health and Physical Education | 5 |
| 1797 | MLC School | Burwood | Studies of Religion I | 5 |
| 1798 | Monte Sant Angelo Mercy College | North Sydney | General Mathematics | 5 |
| 1799 | Monte Sant Angelo Mercy College | North Sydney | Studies of Religion I | 5 |
| 1800 | Moriah College | Queens Park | Chemistry | 5 |
| 1801 | Moriah College | Queens Park | English (Standard) | 5 |
| 1802 | Moriah College | Queens Park | Music 1 | 5 |
| 1803 | Moriah College | Queens Park | Music Extension | 5 |
| 1804 | Moriah College | Queens Park | Society and Culture | 5 |
| 1805 | Mosman High School | Mosman | Music 1 | 5 |
| 1806 | Mount Carmel Catholic High School | Varroville | English (Advanced) | 5 |
| 1807 | Mount Carmel Catholic High School | Varroville | Mathematics | 5 |
| 1808 | Mount St Benedict College | Pennant Hills | Biology | 5 |
| 1809 | Mount St Benedict College | Pennant Hills | Business Studies | 5 |
| 1810 | Mount St Benedict College | Pennant Hills | Legal Studies | 5 |
| 1811 | Mount St Joseph Milperra | Milperra | Business Studies | 5 |
| 1812 | Mount St Joseph Milperra | Milperra | English (Advanced) | 5 |
| 1813 | Mount St Joseph Milperra | Milperra | General Mathematics | 5 |
| 1814 | Mount St Patrick College | Murwillumbah | General Mathematics | 5 |
| 1815 | Mount St Patrick College | Murwillumbah | Mathematics | 5 |
| 1816 | Muswellbrook High School | Muswellbrook | Personal Development, Health and Physical Education | 5 |
| 1817 | Newcastle Grammar School | Newcastle | Music 1 | 5 |
| 1818 | Newtown High School of Performing Arts | Newtown | Modern History | 5 |
| 1819 | Newtown High School of Performing Arts | Newtown | Music 2 | 5 |
| 1820 | Normanhurst Boys High School | Normanhurst | English Extension 1 | 5 |
| 1821 | Normanhurst Boys High School | Normanhurst | Music 2 | 5 |
| 1822 | North Sydney Boys High School | Crows Nest | English Extension 2 | 5 |
| 1823 | North Sydney Boys High School | Crows Nest | Music 2 | 5 |
| 1824 | North Sydney Boys High School | Crows Nest | Visual Arts | 5 |
| 1825 | North Sydney Girls High School | Crows Nest | Drama | 5 |
| 1826 | North Sydney Girls High School | Crows Nest | French Extension | 5 |
| 1827 | North Sydney Girls High School | Crows Nest | Italian Beginners | 5 |
| 1828 | North Sydney Girls High School | Crows Nest | Japanese Extension | 5 |
| 1829 | North Sydney Girls High School | Crows Nest | Music Extension | 5 |
| 1830 | Northern Beaches Christian School | Terrey Hills | Mathematics | 5 |
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| 1831 | Northern Beaches Secondary College Freshwater Campus | Freshwater | Ancient History | 5 |
| 1832 | Northern Beaches Secondary College Mackellar Girls Campus | Manly Vale | Business Studies | 5 |
| 1833 | Northern Beaches Secondary College Manly Campus | North Curl Curl | Italian Beginners | 5 |
| 1834 | Northern Beaches Secondary College Manly Campus | North Curl Curl | Music 2 | 5 |
| 1835 | Northern Beaches Secondary College Manly Campus | North Curl Curl | Textiles and Design | 5 |
| 1836 | Northholm Grammar School | Arcadia | Business Studies | 5 |
| 1837 | Nowra Anglican College | Bomaderry | English (Advanced) | 5 |
| 1838 | Nowra High School | Nowra | Personal Development, Health and Physical Education | 5 |
| 1839 | Oakhill College | Castle Hill | Geography | 5 |
| 1840 | Our Lady of Mercy College Parramatta | Parramatta | Business Studies | 5 |
| 1841 | Our Lady of the Sacred Heart College | Kensington | Business Studies | 5 |
| 1842 | Our Lady of the Sacred Heart College | Kensington | Legal Studies | 5 |
| 1843 | Our Lady of the Sacred Heart College | Kensington | Studies of Religion II | 5 |
| 1844 | Oxley College | Burradoo | Visual Arts | 5 |
| 1845 | Oxley High School | North Tamworth | Geography | 5 |
| 1846 | Oxley High School | North Tamworth | Personal Development, Health and Physical Education | 5 |
| 1847 | Pacific Hills Christian School | Dural | Physics | 5 |
| 1848 | Pennant Hills High School | Pennant Hills | Legal Studies | 5 |
| 1849 | Penrith High School | Penrith | Food Technology | 5 |
| 1850 | Penrith High School | Penrith | Software Design and Development | 5 |
| 1851 | Picton High School | Picton | General Mathematics | 5 |
| 1852 | Port Hacking High School | Miranda | Information Processes and Technology | 5 |
| 1853 | Port Hacking High School | Miranda | Mathematics | 5 |
| 1854 | Prairiewood High School | Prairiewood | Mathematics | 5 |
| 1855 | Presbyterian Ladies College Sydney | Croydon | Chemistry | 5 |
| 1856 | Presbyterian Ladies College Sydney | Croydon | Chinese Continuers | 5 |
| 1857 | Presbyterian Ladies College Sydney | Croydon | Chinese Extension | 5 |
| 1858 | Presbyterian Ladies College Sydney | Croydon | General Mathematics | 5 |
| 1859 | Pymble Ladies College | Pymble | Earth and Environmental Science | 5 |
| 1860 | Pymble Ladies College | Pymble | French Extension | 5 |
| 1861 | Queenwood School for Girls | Mosman | Ancient History | 5 |
| 1862 | Queenwood School for Girls | Mosman | French Continuers | 5 |
| 1863 | Queenwood School for Girls | Mosman | History Extension | 5 |
| 1864 | Queenwood School for Girls | Mosman | Visual Arts | 5 |
| 1865 | Randwick Boys High School | Randwick | Mathematics | 5 |
| 1866 | Ravenswood School for Girls | Gordon | Japanese Continuers | 5 |
| 1867 | Ravenswood School for Girls | Gordon | Mathematics Extension 2 | 5 |
| 1868 | Reddam House Bondi Campus | North Bondi | Biology | 5 |
| 1869 | Reddam House Bondi Campus | North Bondi | Economics | 5 |
| 1870 | Reddam House Bondi Campus | North Bondi | Mathematics Extension 2 | 5 |
| 1871 | Reddam House Bondi Campus | North Bondi | Visual Arts | 5 |
| 1872 | Redeemer Baptist School | North Parramatta | Mathematics Extension 1 | 5 |
| 1873 | Redfield College | Dural | English (Advanced) | 5 |
| 1874 | Riverside Girls High School | Gladesville | History Extension | 5 |
| 1875 | Riverside Girls High School | Gladesville | Visual Arts | 5 |
| 1876 | Rosebank College | Five Dock | Ancient History | 5 |
| 1877 | Roseville College | Roseville | Ancient History | 5 |
| 1878 | Roseville College | Roseville | Drama | 5 |
| 1879 | Roseville College | Roseville | Mathematics | 5 |
| 1880 | Santa Sabina College | Strathfield | Modern History | 5 |
| 1881 | Santa Sabina College | Strathfield | Visual Arts | 5 |
| 1882 | SCECGS Redlands | Cremorne | General Mathematics | 5 |
| 1883 | SCEGGS Darlinghurst | Darlinghurst | Music 1 | 5 |
| 1884 | Sefton High School | Sefton | English (Standard) | 5 |
| 1885 | Sefton High School | Sefton | Information Processes and Technology | 5 |
| 1886 | Sefton High School | Sefton | Studies of Religion I | 5 |
| 1887 | SHORE Sydney Church of England Grammar School | North Sydney | Economics | 5 |
| 1888 | SHORE Sydney Church of England Grammar School | North Sydney | History Extension | 5 |
| 1889 | Smiths Hill High School | Wollongong | English Extension 2 | 5 |
| 1890 | Springwood High School | Springwood | Music 1 | 5 |
| 1891 | St Aloysius College | Milsons Point | Biology | 5 |
| 1892 | St Aloysius College | Milsons Point | Drama | 5 |
| 1893 | St Andrews Cathedral School | Sydney | Drama | 5 |
| 1894 | St Andrews Cathedral School | Sydney | Legal Studies | 5 |
| 1895 | St Andrews Cathedral School | Sydney | Music Extension | 5 |
| 1896 | St Augustines College | Brookvale | English (Advanced) | 5 |
| 1897 | St Augustines College | Brookvale | General Mathematics | 5 |
| 1898 | St Catherines School | Waverley | Mathematics Extension 2 | 5 |
| 1899 | St Charbels College | Punchbowl | Legal Studies | 5 |
| 1900 | St Charbels College | Punchbowl | Mathematics Extension 1 | 5 |
| 1901 | St Clares College | Waverley | Studies of Religion II | 5 |
| 1902 | St Clares High School | Taree | English (Advanced) | 5 |
| 1903 | St Columbas Catholic College | Springwood | English Extension 1 | 5 |
| 1904 | St Euphemia College | Bankstown | Modern Greek Continuers | 5 |
| 1905 | St Euphemia College | Bankstown | Modern Greek Extension | 5 |
| 1906 | St Francis Xaviers College | Hamilton | Ancient History | 5 |
| 1907 | St George Girls High School | Kogarah | Legal Studies | 5 |
| 1908 | St George Girls High School | Kogarah | Music Extension | 5 |
| 1909 | St Gregorys College Campbelltown | Gregory Hills | English (Advanced) | 5 |
| 1910 | St Gregorys College Campbelltown | Gregory Hills | Senior Science | 5 |
| 1911 | St Ignatius College | Lane Cove | Chemistry | 5 |
| 1912 | St Ives High School | St Ives | Legal Studies | 5 |
| 1913 | St Ives High School | St Ives | Mathematics | 5 |
| 1914 | St Ives High School | St Ives | Mathematics Extension 2 | 5 |
| 1915 | St John Bosco College | Engadine | Mathematics | 5 |
| 1916 | St John Paul College | Coffs Harbour | Legal Studies | 5 |
| 1917 | St John Paul II Catholic College Nirimba | Quakers Hill | Music 1 | 5 |
| 1918 | St John The Evangelist Catholic High School | Nowra | Drama | 5 |
| 1919 | St Johns College | ? | Mathematics Extension 1 | 5 |
| 1920 | St Josephs Catholic College | East Gosford | Geography | 5 |
| 1921 | St Josephs College | ? | English Extension 1 | 5 |
| 1922 | St Marks Coptic Orthodox College | Wattle Grove | Physics | 5 |
| 1923 | St Mary and St Minas Coptic Orthodox College | Rockdale | Mathematics Extension 2 | 5 |
| 1924 | St Mary Star of the Sea College | Wollongong | Biology | 5 |
| 1925 | St Mary Star of the Sea College | Wollongong | Mathematics | 5 |
| 1926 | St Mary Star of the Sea College | Wollongong | Music 1 | 5 |
| 1927 | St Marys Cathedral College | Sydney | Industrial Technology | 5 |
| 1928 | St Marys Senior High School | St Marys | Economics | 5 |
| 1929 | St Marys Senior High School | St Marys | English Extension 1 | 5 |
| 1930 | St Marys Senior High School | St Marys | Information Processes and Technology | 5 |
| 1931 | St Patricks College Campbelltown | Campbelltown | Ancient History | 5 |
| 1932 | St Patricks College Campbelltown | Campbelltown | Legal Studies | 5 |
| 1933 | St Patricks College Campbelltown | Campbelltown | Studies of Religion I | 5 |
| 1934 | St Patricks College Campbelltown | Campbelltown | Studies of Religion II | 5 |
| 1935 | St Patricks College Strathfield | Strathfield | Chemistry | 5 |
| 1936 | St Patricks College Sutherland | Sutherland | Mathematics Extension 2 | 5 |
| 1937 | St Patricks College Sutherland | Sutherland | Personal Development, Health and Physical Education | 5 |
| 1938 | St Patricks College Sutherland | Sutherland | Physics | 5 |
| 1939 | St Patricks Marist College | Dundas | Food Technology | 5 |
| 1940 | St Pauls Catholic College | ? | General Mathematics | 5 |
| 1941 | St Pauls Catholic College | ? | Visual Arts | 5 |
| 1942 | St Pauls Grammar School | Cranebrook | General Mathematics | 5 |
| 1943 | St Philips Christian College Newcastle | Waratah | Mathematics | 5 |
| 1944 | St Philips Christian College Newcastle | Waratah | Mathematics Extension 1 | 5 |
| 1945 | St Ursulas College | Kingsgrove | Visual Arts | 5 |
| 1946 | St Vincents College | Potts Point | Biology | 5 |
| 1947 | St Vincents College | Potts Point | Personal Development, Health and Physical Education | 5 |
| 1948 | Stella Maris College | Manly | Chinese Background Speakers | 5 |
| 1949 | Strathfield Girls High School | Strathfield | Ancient History | 5 |
| 1950 | Strathfield Girls High School | Strathfield | Information Processes and Technology | 5 |
| 1951 | Strathfield Girls High School | Strathfield | Mathematics Extension 2 | 5 |
| 1952 | Strathfield Girls High School | Strathfield | Visual Arts | 5 |
| 1953 | Strathfield South High School | Enfield | Mathematics Extension 1 | 5 |
| 1954 | Sutherland Shire Christian School | Barden Ridge | English (Advanced) | 5 |
| 1955 | Sydney Boys High School | Moore Park | Engineering Studies | 5 |
| 1956 | Sydney Distance Education High School | Woolloomooloo | English (Advanced) | 5 |
| 1957 | Sydney Grammar School | Darlinghurst | Classical Greek Continuers | 5 |
| 1958 | Sydney Grammar School | Darlinghurst | Classical Greek Extension | 5 |
| 1959 | Sydney Grammar School | Darlinghurst | Italian Extension | 5 |
| 1960 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Biology | 5 |
| 1961 | Sydney Technical High School | Bexley | Modern History | 5 |
| 1962 | Sylvania High School | Sylvania | Food Technology | 5 |
| 1963 | Tangara School for Girls | Cherrybrook | Music 1 | 5 |
| 1964 | Tara Anglican School for Girls | North Parramatta | English Extension 1 | 5 |
| 1965 | Tara Anglican School for Girls | North Parramatta | Food Technology | 5 |
| 1966 | Tara Anglican School for Girls | North Parramatta | Mathematics | 5 |
| 1967 | Tempe High School | Tempe | Mathematics | 5 |
| 1968 | Tempe High School | Tempe | Mathematics Extension 2 | 5 |
| 1969 | The Armidale School | Armidale | Mathematics | 5 |
| 1970 | The Hills Grammar School | Kenthurst | Mathematics Extension 2 | 5 |
| 1971 | The Hills Grammar School | Kenthurst | Visual Arts | 5 |
| 1972 | The Illawarra Grammar School | Wollongong | Visual Arts | 5 |
| 1973 | The Kings School | North Parramatta | Senior Science | 5 |
| 1974 | The McDonald College | North Strathfield | Music Extension | 5 |
| 1975 | The Scots College | Bellevue Hill | Ancient History | 5 |
| 1976 | The Scots College | Bellevue Hill | Drama | 5 |
| 1977 | The Scots College | Bellevue Hill | Physics | 5 |
| 1978 | The Scots School Albury | Albury | Ancient History | 5 |
| 1979 | The Scots School Albury | Albury | Music 1 | 5 |
| 1980 | Trinity Catholic College Auburn Campus | Auburn | Industrial Technology | 5 |
| 1981 | Trinity Catholic College Auburn Campus | Auburn | Legal Studies | 5 |
| 1982 | Trinity Catholic College Goulburn | Goulburn | Senior Science | 5 |
| 1983 | Trinity Grammar School | Summer Hill | Chinese Continuers | 5 |
| 1984 | Trinity Grammar School | Summer Hill | Physics | 5 |
| 1985 | Tuggerah Lakes Secondary College The Entrance Campus | Shelly Beach | Visual Arts | 5 |
| 1986 | Turramurra High School | South Turramurra | English Extension 1 | 5 |
| 1987 | Turramurra High School | South Turramurra | Physics | 5 |
| 1988 | Ulladulla High School | Ulladulla | General Mathematics | 5 |
| 1989 | Warners Bay High School | Warners Bay | General Mathematics | 5 |
| 1990 | Wenona School | North Sydney | Modern History | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 17 Feb 2023