| 1991 | Toorak College | Mount Eliza | Languages: German | 3 |
| 1992 | Toorak College | Mount Eliza | Mathematical Methods | 3 |
| 1993 | Trafalgar High School | Trafalgar | English | 3 |
| 1994 | University High School | Parkville | Extended Investigation | 3 |
| 1995 | University High School | Parkville | Global Politics | 3 |
| 1996 | University High School | Parkville | Health and Human Development | 3 |
| 1997 | University High School | Parkville | Languages: French | 3 |
| 1998 | University High School | Parkville | Specialist Mathematics | 3 |
| 1999 | Vermont Secondary College | Vermont | English Language | 3 |
| 2000 | Vermont Secondary College | Vermont | Physics | 3 |
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| 2001 | Victorian College for the Deaf | Melbourne | Languages: Auslan | 3 |
| 2002 | Victorian College of the Arts Secondary School | Southbank | Further Mathematics | 3 |
| 2003 | Victorian School of Languages | Thornbury | Languages: Russian | 3 |
| 2004 | Victorian School of Languages | Thornbury | Languages: Sinhala | 3 |
| 2005 | Victory Christian College | Strathdale | Studio Arts | 3 |
| 2006 | Viewbank College | Viewbank | Art | 3 |
| 2007 | Viewbank College | Viewbank | Psychology | 3 |
| 2008 | Virtual School Victoria | Thornbury | Informatics | 3 |
| 2009 | Virtual School Victoria | Thornbury | Legal Studies | 3 |
| 2010 | Virtual School Victoria | Thornbury | Visual Communication Design | 3 |
| 2011 | Wangaratta High School | Wangaratta | English | 3 |
| 2012 | Wangaratta High School | Wangaratta | Further Mathematics | 3 |
| 2013 | Wantirna College | Wantirna | Psychology | 3 |
| 2014 | Warrandyte High School | Warrandyte | Physics | 3 |
| 2015 | Warrnambool College | Warrnambool | Health and Human Development | 3 |
| 2016 | Waverley Christian College Wantirna South | Wantirna South | English as an Additional Language | 3 |
| 2017 | Waverley Christian College Wantirna South | Wantirna South | History: Revolutions | 3 |
| 2018 | Waverley Christian College Wantirna South | Wantirna South | Legal Studies | 3 |
| 2019 | Waverley Christian College Wantirna South | Wantirna South | Visual Communication Design | 3 |
| 2020 | Wellington Secondary College | Mulgrave | Accounting | 3 |
| 2021 | Wellington Secondary College | Mulgrave | Food Studies | 3 |
| 2022 | Wellington Secondary College | Mulgrave | Physics | 3 |
| 2023 | Werribee Secondary College | Werribee | English | 3 |
| 2024 | Werribee Secondary College | Werribee | Psychology | 3 |
| 2025 | Wesley College St Kilda Rd | Melbourne | Mathematical Methods | 3 |
| 2026 | Wesley College St Kilda Rd | Melbourne | Theatre Studies | 3 |
| 2027 | Westbourne Grammar School | Truganina | English as an Additional Language | 3 |
| 2028 | Westbourne Grammar School | Truganina | Physics | 3 |
| 2029 | Westbourne Grammar School | Truganina | Studio Arts | 3 |
| 2030 | Wheelers Hill Secondary College | Wheelers Hill | Mathematical Methods | 3 |
| 2031 | Whitefriars College | Donvale | English Language | 3 |
| 2032 | Whitefriars College | Donvale | Further Mathematics | 3 |
| 2033 | Whitefriars College | Donvale | Mathematical Methods | 3 |
| 2034 | Williamstown High School | Williamstown | Chemistry | 3 |
| 2035 | Williamstown High School | Williamstown | Food Studies | 3 |
| 2036 | Williamstown High School | Williamstown | Studio Arts | 3 |
| 2037 | Wonthaggi Secondary College | Wonthaggi | Physical Education | 3 |
| 2038 | Woodleigh School | Langwarrin South | Outdoor and Environmental Studies | 3 |
| 2039 | Woodleigh School | Langwarrin South | Physics | 3 |
| 2040 | Xavier College | Kew | Economics | 3 |
Last Updated: 18 Dec 2019