| 1981 | Ringwood Secondary College | Ringwood | Studio Arts | 3 |
| 1982 | Rutherglen High School | Rutherglen | Agricultural and Horticultural Studies | 3 |
| 1983 | Ruyton Girls School | Kew | Mathematical Methods (CAS) | 3 |
| 1984 | Ruyton Girls School | Kew | Specialist Mathematics | 3 |
| 1985 | Sacre Coeur | Glen Iris | Physical Education | 3 |
| 1986 | Sacred Heart College Geelong | Newtown | Product Design and Technology | 3 |
| 1987 | Saint Ignatius College | Drysdale | Religion and Society | 3 |
| 1988 | Saint Ignatius College | Drysdale | Studio Arts | 3 |
| 1989 | Salesian College Chadstone | Chadstone | Mathematical Methods (CAS) | 3 |
| 1990 | Salesian College Chadstone | Chadstone | Software Development | 3 |
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| 1991 | Salesian College Sunbury | Sunbury | Media | 3 |
| 1992 | Salesian College Sunbury | Sunbury | Product Design and Technology | 3 |
| 1993 | Santa Maria College | Northcote | Biology | 3 |
| 1994 | Scotch College | Hawthorn | Drama | 3 |
| 1995 | Scotch College | Hawthorn | Environmental Science | 3 |
| 1996 | Scotch College | Hawthorn | Languages: Chinese Second Language | 3 |
| 1997 | Scotch College | Hawthorn | Product Design and Technology | 3 |
| 1998 | Shelford Girls Grammar | Caulfield | Food Studies | 3 |
| 1999 | Shelford Girls Grammar | Caulfield | Global Politics | 3 |
| 2000 | Shelford Girls Grammar | Caulfield | Legal Studies | 3 |
| 2001 | Shelford Girls Grammar | Caulfield | Studio Arts | 3 |
| 2002 | Siena College | Camberwell | Business Management | 3 |
| 2003 | Siena College | Camberwell | Further Mathematics | 3 |
| 2004 | Siena College | Camberwell | History: Revolutions | 3 |
| 2005 | Siena College | Camberwell | Physical Education | 3 |
| 2006 | Siena College | Camberwell | Religion and Society | 3 |
| 2007 | Sirius College Broadmeadows Campus | Broadmeadows | English as an Additional Language | 3 |
| 2008 | Sirius College Meadow Fair Campus | Broadmeadows | Informatics | 3 |
| 2009 | Sirius College Meadow Fair Campus | Broadmeadows | Psychology | 3 |
| 2010 | Springvale Indo-Chinese Ethnic School Inc. | Springvale South | Languages: Vietnamese Second Language | 3 |
| 2011 | St Aloysius College | North Melbourne | Mathematical Methods (CAS) | 3 |
| 2012 | St Andrews Christian College | Wantirna South | Biology | 3 |
| 2013 | St Augustines College | Kyabram | Outdoor and Environmental Studies | 3 |
| 2014 | St Bedes College | Mentone | Psychology | 3 |
| 2015 | St Bedes College | Mentone | Religion and Society | 3 |
| 2016 | St Bernards College | Essendon | Legal Studies | 3 |
| 2017 | St Bernards College | Essendon | Religion and Society | 3 |
| 2018 | St Catherines School | Toorak | Health and Human Development | 3 |
| 2019 | St Catherines School | Toorak | Studio Arts | 3 |
| 2020 | St Columbas College | Essendon | Biology | 3 |
| 2021 | St Francis Xavier College | Beaconsfield | Business Management | 3 |
| 2022 | St Francis Xavier College | Beaconsfield | Psychology | 3 |
| 2023 | St Helena Secondary College | Eltham North | Further Mathematics | 3 |
| 2024 | St Helena Secondary College | Eltham North | Health and Human Development | 3 |
| 2025 | St Helena Secondary College | Eltham North | Psychology | 3 |
| 2026 | St Josephs College Ferntree Gully | Ferntree Gully | Info, Digital Media and Tech (VCE VET) | 3 |
| 2027 | St Josephs College Ferntree Gully | Ferntree Gully | Sport and Recreation (VCE VET) | 3 |
| 2028 | St Josephs College Geelong | Newtown | Chemistry | 3 |
| 2029 | St Josephs College Geelong | Newtown | Food Studies | 3 |
| 2030 | St Josephs College Geelong | Newtown | Furnishing (VCE VET) | 3 |
Last Updated: 9 Aug 2024