| 1976 | Rowville Secondary College | Rowville | Sport and Recreation (VCE VET) | 3 |
| 1977 | Roxburgh College | Roxburgh Park | Information Technology (VCE VET) | 3 |
| 1978 | Ruyton Girls School | Kew | Classical Studies | 3 |
| 1979 | Ruyton Girls School | Kew | Languages: French | 3 |
| 1980 | Ruyton Girls School | Kew | Specialist Mathematics | 3 |
| 1981 | Sacre Coeur | Glen Iris | Psychology | 3 |
| 1982 | Sacre Coeur | Glen Iris | Theatre Studies | 3 |
| 1983 | Sacred Heart College Geelong | Newtown | Geography | 3 |
| 1984 | Sacred Heart College Geelong | Newtown | History: Revolutions | 3 |
| 1985 | Sacred Heart College Geelong | Newtown | Visual Communication Design | 3 |
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| 1986 | Sacred Heart College Kyneton | Kyneton | English | 3 |
| 1987 | Sacred Heart College Kyneton | Kyneton | Outdoor and Environmental Studies | 3 |
| 1988 | Sacred Heart Girls College | Hughesdale | Australian History | 3 |
| 1989 | Sacred Heart Girls College | Hughesdale | Media | 3 |
| 1990 | Sacred Heart Girls College | Hughesdale | Physical Education | 3 |
| 1991 | Sacred Heart Girls College | Hughesdale | Psychology | 3 |
| 1992 | Saint Ignatius College | Drysdale | Mathematical Methods (CAS) | 3 |
| 1993 | Salesian College Chadstone | Chadstone | Chemistry | 3 |
| 1994 | Salesian College Chadstone | Chadstone | Psychology | 3 |
| 1995 | Salesian College Sunbury | Sunbury | English | 3 |
| 1996 | Salesian College Sunbury | Sunbury | Food and Technology | 3 |
| 1997 | Salesian College Sunbury | Sunbury | Health and Human Development | 3 |
| 1998 | Sandringham College | Sandringham | Psychology | 3 |
| 1999 | Sandringham College | Sandringham | Theatre Studies | 3 |
| 2000 | Santa Maria College | Northcote | Chemistry | 3 |
| 2001 | Santa Maria College | Northcote | Physical Education | 3 |
| 2002 | Santa Maria College | Northcote | Texts and Traditions | 3 |
| 2003 | Scotch College | Hawthorn | Geography | 3 |
| 2004 | Scotch College | Hawthorn | Global Politics | 3 |
| 2005 | Scotch College | Hawthorn | IT Applications | 3 |
| 2006 | Shelford Girls Grammar | Caulfield | Drama | 3 |
| 2007 | Siena College | Camberwell | Chemistry | 3 |
| 2008 | Siena College | Camberwell | Studio Arts | 3 |
| 2009 | Simonds Catholic College | Fitzroy North | Biology | 3 |
| 2010 | Sirius College Broadmeadows Campus | Broadmeadows | Mathematical Methods (CAS) | 3 |
| 2011 | St Albans Secondary College | St Albans | English | 3 |
| 2012 | St Bedes College | Mentone | Business Management | 3 |
| 2013 | St Bernards College | Essendon | Biology | 3 |
| 2014 | St Bernards College | Essendon | English Language | 3 |
| 2015 | St Bernards College | Essendon | Languages: Italian | 3 |
| 2016 | St Bernards College | Essendon | Psychology | 3 |
| 2017 | St Catherines School | Toorak | Biology | 3 |
| 2018 | St Catherines School | Toorak | Global Politics | 3 |
| 2019 | St Catherines School | Toorak | Physical Education | 3 |
| 2020 | St Catherines School | Toorak | Studio Arts | 3 |
| 2021 | St Columbas College | Essendon | Biology | 3 |
| 2022 | St Columbas College | Essendon | History: Revolutions | 3 |
| 2023 | St Columbas College | Essendon | Psychology | 3 |
| 2024 | St Francis Xavier College | Beaconsfield | Further Mathematics | 3 |
| 2025 | St Francis Xavier College | Beaconsfield | Interactive Digital Media (VCE VET) | 3 |
Last Updated: 8 Feb 2021