| 1916 | Northcote High School | Northcote | Languages: Chinese Second Language | 3 |
| 1917 | Northcote High School | Northcote | Legal Studies | 3 |
| 1918 | Northcote High School | Northcote | Philosophy | 3 |
| 1919 | Northcote High School | Northcote | Product Design and Technology | 3 |
| 1920 | Northcote High School | Northcote | Studio Arts | 3 |
| 1921 | Nossal High School | Berwick | History: Revolutions | 3 |
| 1922 | Nossal High School | Berwick | Languages: French | 3 |
| 1923 | Notre Dame College | Shepparton | Sport and Recreation (VCE VET) | 3 |
| 1924 | Nunawading Christian College | Nunawading | Health and Human Development | 3 |
| 1925 | Nunawading Christian College | Nunawading | Texts and Traditions | 3 |
| 1926 | Orbost Secondary College | Orbost | Visual Communication Design | 3 |
| 1927 | Our Lady of Mercy College | Heidelberg | Biology | 3 |
| 1928 | Our Lady of Mercy College | Heidelberg | Food and Technology | 3 |
| 1929 | Our Lady of Mercy College | Heidelberg | History: Revolutions | 3 |
| 1930 | Our Lady of Mercy College | Heidelberg | Theatre Studies | 3 |
| 1931 | Our Lady of Sacred Heart College | Bentleigh | Psychology | 3 |
| 1932 | Our Lady of Sion College | Box Hill | Mathematical Methods (CAS) | 3 |
| 1933 | Overnewton Anglican College | Keilor | Dance | 3 |
| 1934 | Overnewton Anglican College | Keilor | Legal Studies | 3 |
| 1935 | Overnewton Anglican College | Keilor | Mathematical Methods (CAS) | 3 |
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| 1936 | Overnewton Anglican College | Keilor | Physical Education | 3 |
| 1937 | Overnewton Anglican College | Keilor | Physics | 3 |
| 1938 | Oxley Christian College | Chirnside Park | Biology | 3 |
| 1939 | Oxley Christian College | Chirnside Park | Texts and Traditions | 3 |
| 1940 | Padua College | Mornington | Philosophy | 3 |
| 1941 | Padua College | Mornington | Physical Education | 3 |
| 1942 | Padua College | Mornington | Visual Communication Design | 3 |
| 1943 | Parade College | Bundoora | Business Management | 3 |
| 1944 | Parade College | Bundoora | History: Revolutions | 3 |
| 1945 | Parade College | Bundoora | Sport and Recreation (VCE VET) | 3 |
| 1946 | Pascoe Vale Girls Secondary College | Pascoe Vale | Business Management | 3 |
| 1947 | Pascoe Vale Girls Secondary College | Pascoe Vale | Physical Education | 3 |
| 1948 | Patterson River Secondary College | Seaford | Health and Human Development | 3 |
| 1949 | Patterson River Secondary College | Seaford | Psychology | 3 |
| 1950 | Peninsula Grammar | Mount Eliza | Accounting | 3 |
| 1951 | Peninsula Grammar | Mount Eliza | Physical Education | 3 |
| 1952 | Plenty Valley Christian College | Doreen | Biology | 3 |
| 1953 | Presbyterian Ladies College | Burwood | Economics | 3 |
| 1954 | Presbyterian Ladies College | Burwood | Languages: Chinese Second Language Advanced | 3 |
| 1955 | Presbyterian Ladies College | Burwood | Languages: French | 3 |
| 1956 | Presbyterian Ladies College | Burwood | Languages: Indonesian Second Language | 3 |
| 1957 | Presbyterian Ladies College | Burwood | Music Performance | 3 |
| 1958 | Presbyterian Ladies College | Burwood | Theatre Studies | 3 |
| 1959 | Presentation College | Windsor | Product Design and Technology | 3 |
| 1960 | Presentation College | Windsor | Theatre Studies | 3 |
| 1961 | Princes Hill Secondary College | Princes Hill | Chemistry | 3 |
| 1962 | Princes Hill Secondary College | Princes Hill | Classical Studies | 3 |
| 1963 | Princes Hill Secondary College | Princes Hill | Further Mathematics | 3 |
| 1964 | Princes Hill Secondary College | Princes Hill | Psychology | 3 |
| 1965 | Reservoir High School | Reservoir | Further Mathematics | 3 |
| 1966 | Ringwood Secondary College | Ringwood | Biology | 3 |
| 1967 | Ringwood Secondary College | Ringwood | English Language | 3 |
| 1968 | Ringwood Secondary College | Ringwood | Legal Studies | 3 |
| 1969 | Ringwood Secondary College | Ringwood | Psychology | 3 |
| 1970 | RMIT TAFE | Melbourne | Further Mathematics | 3 |
| 1971 | Rochester Secondary College | Rochester | Physical Education | 3 |
| 1972 | Rosebud Secondary College | Rosebud | Australian History | 3 |
| 1973 | Rosebud Secondary College | Rosebud | Outdoor and Environmental Studies | 3 |
| 1974 | Rosehill Secondary College | Niddrie | Food and Technology | 3 |
| 1975 | Rowville Secondary College | Rowville | Media | 3 |
| 1976 | Rowville Secondary College | Rowville | Sport and Recreation (VCE VET) | 3 |
| 1977 | Roxburgh College | Roxburgh Park | Information Technology (VCE VET) | 3 |
| 1978 | Ruyton Girls School | Kew | Classical Studies | 3 |
| 1979 | Ruyton Girls School | Kew | Languages: French | 3 |
| 1980 | Ruyton Girls School | Kew | Specialist Mathematics | 3 |
| 1981 | Sacre Coeur | Glen Iris | Psychology | 3 |
| 1982 | Sacre Coeur | Glen Iris | Theatre Studies | 3 |
| 1983 | Sacred Heart College Geelong | Newtown | Geography | 3 |
| 1984 | Sacred Heart College Geelong | Newtown | History: Revolutions | 3 |
| 1985 | Sacred Heart College Geelong | Newtown | Visual Communication Design | 3 |
| 1986 | Sacred Heart College Kyneton | Kyneton | English | 3 |
| 1987 | Sacred Heart College Kyneton | Kyneton | Outdoor and Environmental Studies | 3 |
| 1988 | Sacred Heart Girls College | Hughesdale | Australian History | 3 |
| 1989 | Sacred Heart Girls College | Hughesdale | Media | 3 |
| 1990 | Sacred Heart Girls College | Hughesdale | Physical Education | 3 |
| 1991 | Sacred Heart Girls College | Hughesdale | Psychology | 3 |
| 1992 | Saint Ignatius College | Drysdale | Mathematical Methods (CAS) | 3 |
| 1993 | Salesian College Chadstone | Chadstone | Chemistry | 3 |
| 1994 | Salesian College Chadstone | Chadstone | Psychology | 3 |
| 1995 | Salesian College Sunbury | Sunbury | English | 3 |
| 1996 | Salesian College Sunbury | Sunbury | Food and Technology | 3 |
| 1997 | Salesian College Sunbury | Sunbury | Health and Human Development | 3 |
| 1998 | Sandringham College | Sandringham | Psychology | 3 |
| 1999 | Sandringham College | Sandringham | Theatre Studies | 3 |
| 2000 | Santa Maria College | Northcote | Chemistry | 3 |
| 2001 | Santa Maria College | Northcote | Physical Education | 3 |
| 2002 | Santa Maria College | Northcote | Texts and Traditions | 3 |
| 2003 | Scotch College | Hawthorn | Geography | 3 |
| 2004 | Scotch College | Hawthorn | Global Politics | 3 |
| 2005 | Scotch College | Hawthorn | IT Applications | 3 |
| 2006 | Shelford Girls Grammar | Caulfield | Drama | 3 |
| 2007 | Siena College | Camberwell | Chemistry | 3 |
| 2008 | Siena College | Camberwell | Studio Arts | 3 |
| 2009 | Simonds Catholic College | Fitzroy North | Biology | 3 |
| 2010 | Sirius College Broadmeadows Campus | Broadmeadows | Mathematical Methods (CAS) | 3 |
| 2011 | St Albans Secondary College | St Albans | English | 3 |
| 2012 | St Bedes College | Mentone | Business Management | 3 |
| 2013 | St Bernards College | Essendon | Biology | 3 |
| 2014 | St Bernards College | Essendon | English Language | 3 |
| 2015 | St Bernards College | Essendon | Languages: Italian | 3 |
Last Updated: 8 Feb 2021