Below is the list of the best HSC students in 2022 ranked in order of their total number of subjects awarded.
A subject award can be either a Distinguished Achiever award or a Subject Rank award (top place in subject).
Where students have equal numbers of subject awards, those with an All Rounder award are ranked higher. As additional tie-breakers, Subject Rank awards are ranked by their place value and they are also ranked higher than Distinguished Achiever awards. Where all of these measures are equal, entries are listed alphabetically.
Note that these rankings are calculated using only the published results for 2022. A student's awards from any earlier years, if any, are not not included here.
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| 1 | Makarewicz, Logan Jade | Mercy Catholic College | Chatswood | 5 | Yes | |
| 2 | Tachjian, Kiara | Mercy Catholic College | Chatswood | 5 | Yes | |
| 3 | Woo, Charlotte Mae | Mercy Catholic College | Chatswood | 5 | Yes | |
| 4 | Mikhael, Lauren Sarah | Mercy Catholic College | Chatswood | 5 | ||
| 5 | McNally, Caitlyn Taylor | Mercy Catholic College | Chatswood | 4 | ||
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| 6 | Starr, Kate Judith | Mercy Catholic College | Chatswood | 4 | ||
| 7 | Aler, Deanna Joyce Hernandez | Mercy Catholic College | Chatswood | 3 | ||
| 8 | Au, Sonia | Mercy Catholic College | Chatswood | 3 | ||
| 9 | Li, Ching Man | Mercy Catholic College | Chatswood | 3 | ||
| 10 | Rana, Diyashree | Mercy Catholic College | Chatswood | 3 | ||
| 11 | Ambler, Charlotte Elise | Mercy Catholic College | Chatswood | 2 | ||
| 12 | Hester, Olivia Suzanne | Mercy Catholic College | Chatswood | 2 | ||
| 13 | Korkian, Bianca Rose | Mercy Catholic College | Chatswood | 2 | ||
| 14 | Krishna, Michella Ayusta | Mercy Catholic College | Chatswood | 2 | ||
| 15 | Morcom, Brianna Aoife Rosaleen | Mercy Catholic College | Chatswood | 2 | ||
| 16 | Saroukos, Sofia | Mercy Catholic College | Chatswood | 2 | ||
| 17 | Toms, Olivia Heather | Mercy Catholic College | Chatswood | 2 | ||
| 18 | Badger-Rahme, Bethany Faith | Mercy Catholic College | Chatswood | 1 | ||
| 19 | Baker, Jenna Louise | Mercy Catholic College | Chatswood | 1 | ||
| 20 | Barbara, Gabrielle Teresa | Mercy Catholic College | Chatswood | 1 | ||
| 21 | Bowden, Annabelle Rose | Mercy Catholic College | Chatswood | 1 | ||
| 22 | Curtin, Camryn Jeanette | Mercy Catholic College | Chatswood | 1 | ||
| 23 | Dearness, Yanhong GabrielleMargaret | Mercy Catholic College | Chatswood | 1 | ||
| 24 | Dikranian, Chanel Naira | Mercy Catholic College | Chatswood | 1 | ||
| 25 | Ho, Isabella Juliette | Mercy Catholic College | Chatswood | 1 | ||
| 26 | Sweeney, Scarlett Elizabeth | Mercy Catholic College | Chatswood | 1 | ||
| 27 | Walker, Mackenzie Elizabeth | Mercy Catholic College | Chatswood | 1 | ||
| 28 | Yabut, Jewel Grace | Mercy Catholic College | Chatswood | 1 | ||
Supplementary data from school publications.