Below is the list of the best HSC students in 2016 ranked in order of their total number of subjects awarded.
A subject award can be either a Distinguished Achiever award or a Subject Rank award (top place in subject).
Where students have equal numbers of subject awards, those with an All Rounder award are ranked higher. As additional tie-breakers, Subject Rank awards are ranked by their place value and they are also ranked higher than Distinguished Achiever awards. Where all of these measures are equal, entries are listed alphabetically.
Note that these rankings are calculated using only the published results for 2016. A student's awards from any earlier years, if any, are not not included here.
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| 1 | Silvanian, Karina | Mercy Catholic College | Chatswood | 6 | Yes | |
| 2 | Mesiti, Kaitlin Theresa | Mercy Catholic College | Chatswood | 6 | Yes | |
| 3 | Thirugnanaraj, Esther Christina | Mercy Catholic College | Chatswood | 6 | Yes | |
| 4 | Brown, Karina Erin | Mercy Catholic College | Chatswood | 5 | Yes | |
| 5 | Power, Rosemonde Isabella | Mercy Catholic College | Chatswood | 5 | Yes | |
| 6 | Metham, Momoko | Mercy Catholic College | Chatswood | 5 | ||
| 7 | Muresan, Diane Leah | Mercy Catholic College | Chatswood | 5 | ||
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| 8 | Desa, Shannon Kathleen | Mercy Catholic College | Chatswood | 4 | ||
| 9 | Gandhi, Esther Verghese | Mercy Catholic College | Chatswood | 4 | ||
| 10 | Johnston, Madeleine Rose | Mercy Catholic College | Chatswood | 4 | ||
| 11 | Lambert, Jennifer | Mercy Catholic College | Chatswood | 4 | ||
| 12 | Raso, Chantelle | Mercy Catholic College | Chatswood | 4 | ||
| 13 | Chang, Isabelle | Mercy Catholic College | Chatswood | 3 | ||
| 14 | Farahani, Rouhy Diana | Mercy Catholic College | Chatswood | 3 | ||
| 15 | Ohtaras, Dimitra | Mercy Catholic College | Chatswood | 3 | ||
| 16 | Pelagio, Isabella Anne | Mercy Catholic College | Chatswood | 3 | ||
| 17 | Smith, Rebekah | Mercy Catholic College | Chatswood | 3 | ||
| 18 | Arruzza, Elizabeth Katherine | Mercy Catholic College | Chatswood | 2 | ||
| 19 | Dunn, Sasha Naomi | Mercy Catholic College | Chatswood | 2 | ||
| 20 | Kollias, Simone | Mercy Catholic College | Chatswood | 2 | ||
| 21 | Perry, Emma Gabrielle | Mercy Catholic College | Chatswood | 2 | ||
| 22 | Sharpe, Isabella Jane | Mercy Catholic College | Chatswood | 2 | ||
| 23 | Wong, Kelly | Mercy Catholic College | Chatswood | 2 | ||
| 24 | Woo, Stephanie Renee | Mercy Catholic College | Chatswood | 2 | ||
| 25 | Xu, Yinuo | Mercy Catholic College | Chatswood | 2 | ||
| 26 | Athos, Valerie | Mercy Catholic College | Chatswood | 1 | ||
| 27 | Briggs, Arabella Anne | Mercy Catholic College | Chatswood | 1 | ||
| 28 | Fahey, Siobhan | Mercy Catholic College | Chatswood | 1 | ||
| 29 | Fandialan, Janelle | Mercy Catholic College | Chatswood | 1 | ||
| 30 | Ghanem, Jessica | Mercy Catholic College | Chatswood | 1 | ||
| 31 | Nicola, Kristen | Mercy Catholic College | Chatswood | 1 | ||
| 32 | Partridge, Olivia Marie | Mercy Catholic College | Chatswood | 1 | ||
| 33 | Smith, Madeline | Mercy Catholic College | Chatswood | 1 | ||
| 34 | Stepanian, Deana | Mercy Catholic College | Chatswood | 1 | ||
| 35 | Sussanna, Victoria Elizabeth | Mercy Catholic College | Chatswood | 1 | ||
Supplementary data from school publications.