| 1991 | The Scots College | Bellevue Hill | History Extension | 5 |
| 1992 | The Scots College | Bellevue Hill | Legal Studies | 5 |
| 1993 | Thomas Hassall Anglican College | Middleton Grange | Mathematics Advanced | 5 |
| 1994 | Trinity Catholic College Auburn Campus | Auburn | English Advanced | 5 |
| 1995 | Trinity Catholic College Auburn Campus | Auburn | English Extension 1 | 5 |
| 1996 | Trinity Catholic College Auburn Campus | Auburn | Mathematics Advanced | 5 |
| 1997 | Trinity Catholic College Auburn Campus | Auburn | Studies of Religion I | 5 |
| 1998 | Warners Bay High School | Warners Bay | English Advanced | 5 |
| 1999 | Wenona School | North Sydney | Mathematics Advanced | 5 |
| 2000 | William Carey Christian School | Prestons | Biology | 5 |
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| 2001 | William Clarke College | Kellyville | Biology | 5 |
| 2002 | William Clarke College | Kellyville | Visual Arts | 5 |
| 2003 | Willoughby Girls High School | Willoughby | Music 1 | 5 |
| 2004 | Wollongong High School of the Performing Arts | Fairy Meadow | Society and Culture | 5 |
| 2005 | Woolooware High School | Woolooware | Personal Development, Health and Physical Education | 5 |
| 2006 | Xavier High School | North Albury | Studies of Religion I | 5 |
| 2007 | Abbotsleigh | Wahroonga | Chinese Continuers | 4 |
| 2008 | Abbotsleigh | Wahroonga | Latin Extension | 4 |
| 2009 | Abbotsleigh | Wahroonga | Studies of Religion I | 4 |
| 2010 | Al Noori Muslim School Senior Campus | Greenacre | Personal Development, Health and Physical Education | 4 |
| 2011 | Al-Faisal College Campbelltown Campus | Minto | Mathematics Advanced | 4 |
| 2012 | Al-Faisal College Liverpool Campus | Austral | Mathematics Advanced | 4 |
| 2013 | Albury High School | Albury | Mathematics Advanced | 4 |
| 2014 | Albury High School | Albury | Mathematics Standard 2 | 4 |
| 2015 | Alexandria Park Community School | Alexandria | Mathematics Extension 1 | 4 |
| 2016 | All Saints Greek Orthodox Grammar School | Belmore | Mathematics Advanced | 4 |
| 2017 | All Saints Greek Orthodox Grammar School | Belmore | Modern Greek Continuers | 4 |
| 2018 | Alpha Omega Senior College | Auburn | Biology | 4 |
| 2019 | Amity College Prestons | Prestons | Modern History | 4 |
| 2020 | Amity College Prestons | Prestons | Visual Arts | 4 |
| 2021 | Aquinas College | Menai | Community and Family Studies | 4 |
| 2022 | Aquinas College | Menai | Food Technology | 4 |
| 2023 | Aquinas College | Menai | Mathematics Extension 1 | 4 |
| 2024 | Arden Anglican School Epping Campus | Epping | English Extension 1 | 4 |
| 2025 | Arndell Anglican College | Oakville | Mathematics Standard 2 | 4 |
| 2026 | Arthur Phillip High School | Parramatta | Mathematics Extension 1 | 4 |
| 2027 | Ascham School | Edgecliff | French Continuers | 4 |
| 2028 | Ascham School | Edgecliff | Mathematics Extension 2 | 4 |
| 2029 | Ashfield Boys High School | Ashfield | Business Studies | 4 |
| 2030 | Ashfield Boys High School | Ashfield | Mathematics Advanced | 4 |
| 2031 | Ashfield Boys High School | Ashfield | Visual Arts | 4 |
| 2032 | Asquith Girls High School | Asquith | Biology | 4 |
| 2033 | Auburn Girls High School | Auburn | Mathematics Advanced | 4 |
| 2034 | Auburn Girls High School | Auburn | Mathematics Extension 1 | 4 |
| 2035 | Australian International School Hong Kong | Kowloon Tong, Hong Kong | Legal Studies | 4 |
| 2036 | Avondale School | Cooranbong | Hospitality Examination | 4 |
| 2037 | Bankstown Senior College | Bankstown | Persian Continuers | 4 |
| 2038 | Barker College | Hornsby | Science Extension | 4 |
| 2039 | Barrenjoey High School | Avalon | Mathematics Standard 2 | 4 |
| 2040 | Baulkham Hills High School | Baulkham Hills | Tamil Continuers | 4 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 6 Sep 2023