| 1966 | Strathfield Girls High School | Strathfield | Mathematics Extension 1 | 5 |
| 1967 | Sydney Boys High School | Moore Park | Geography | 5 |
| 1968 | Sydney Girls High School | Surry Hills | Economics | 5 |
| 1969 | Sydney Grammar School | Darlinghurst | Chinese Continuers | 5 |
| 1970 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Business Studies | 5 |
| 1971 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Earth and Environmental Science | 5 |
| 1972 | Sydney Secondary College Blackwattle Bay Campus | Glebe | English Extension 1 | 5 |
| 1973 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Mathematics Extension 2 | 5 |
| 1974 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Personal Development, Health and Physical Education | 5 |
| 1975 | Sydney Technical High School | Bexley | Biology | 5 |
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| 1976 | Sydney Technical High School | Bexley | English Standard | 5 |
| 1977 | Sydney Technical High School | Bexley | Music 1 | 5 |
| 1978 | Sydney Technical High School | Bexley | Software Design and Development | 5 |
| 1979 | Tangara School for Girls | Cherrybrook | English Advanced | 5 |
| 1980 | Tara Anglican School for Girls | North Parramatta | Mathematics Extension 1 | 5 |
| 1981 | Tempe High School | Tempe | Mathematics Extension 2 | 5 |
| 1982 | Tempe High School | Tempe | Visual Arts | 5 |
| 1983 | The Hills Grammar School | Kenthurst | Mathematics Standard 2 | 5 |
| 1984 | The Hills Grammar School | Kenthurst | Physics | 5 |
| 1985 | The Illawarra Grammar School | Wollongong | Mathematics Advanced | 5 |
| 1986 | The Kings School | North Parramatta | Chinese Continuers | 5 |
| 1987 | The Kings School | North Parramatta | Chinese Extension | 5 |
| 1988 | The Kings School | North Parramatta | Geography | 5 |
| 1989 | The Kings School | North Parramatta | Music 1 | 5 |
| 1990 | The Kings School | North Parramatta | Personal Development, Health and Physical Education | 5 |
| 1991 | The Scots College | Bellevue Hill | History Extension | 5 |
| 1992 | The Scots College | Bellevue Hill | Legal Studies | 5 |
| 1993 | Thomas Hassall Anglican College | Middleton Grange | Mathematics Advanced | 5 |
| 1994 | Trinity Catholic College Auburn Campus | Auburn | English Advanced | 5 |
| 1995 | Trinity Catholic College Auburn Campus | Auburn | English Extension 1 | 5 |
| 1996 | Trinity Catholic College Auburn Campus | Auburn | Mathematics Advanced | 5 |
| 1997 | Trinity Catholic College Auburn Campus | Auburn | Studies of Religion I | 5 |
| 1998 | Warners Bay High School | Warners Bay | English Advanced | 5 |
| 1999 | Wenona School | North Sydney | Mathematics Advanced | 5 |
| 2000 | William Carey Christian School | Prestons | Biology | 5 |
| 2001 | William Clarke College | Kellyville | Biology | 5 |
| 2002 | William Clarke College | Kellyville | Visual Arts | 5 |
| 2003 | Willoughby Girls High School | Willoughby | Music 1 | 5 |
| 2004 | Wollongong High School of the Performing Arts | Fairy Meadow | Society and Culture | 5 |
| 2005 | Woolooware High School | Woolooware | Personal Development, Health and Physical Education | 5 |
| 2006 | Xavier High School | North Albury | Studies of Religion I | 5 |
| 2007 | Abbotsleigh | Wahroonga | Chinese Continuers | 4 |
| 2008 | Abbotsleigh | Wahroonga | Latin Extension | 4 |
| 2009 | Abbotsleigh | Wahroonga | Studies of Religion I | 4 |
| 2010 | Al Noori Muslim School Senior Campus | Greenacre | Personal Development, Health and Physical Education | 4 |
| 2011 | Al-Faisal College Campbelltown Campus | Minto | Mathematics Advanced | 4 |
| 2012 | Al-Faisal College Liverpool Campus | Austral | Mathematics Advanced | 4 |
| 2013 | Albury High School | Albury | Mathematics Advanced | 4 |
| 2014 | Albury High School | Albury | Mathematics Standard 2 | 4 |
| 2015 | Alexandria Park Community School | Alexandria | Mathematics Extension 1 | 4 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 6 Sep 2023