| 1931 | St John Paul II Catholic College Nirimba | Quakers Hill | Visual Arts | 5 |
| 1932 | St Josephs College Banora Point | Banora Point | English Advanced | 5 |
| 1933 | St Josephs College Banora Point | Banora Point | Studies of Religion I | 5 |
| 1934 | St Josephs College Hunters Hill | Hunters Hill | Ancient History | 5 |
| 1935 | St Josephs College Hunters Hill | Hunters Hill | Personal Development, Health and Physical Education | 5 |
| 1936 | St Lukes Catholic College Secondary | Marsden Park | Studies of Religion I | 5 |
| 1937 | St Lukes Grammar School | Dee Why | Ancient History | 5 |
| 1938 | St Lukes Grammar School | Dee Why | Modern History | 5 |
| 1939 | St Marks Coptic Orthodox College | Wattle Grove | Chemistry | 5 |
| 1940 | St Mary Star of the Sea College | Wollongong | Biology | 5 |
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| 1941 | St Mary Star of the Sea College | Wollongong | English Advanced | 5 |
| 1942 | St Marys Cathedral College | Sydney | Mathematics Standard 2 | 5 |
| 1943 | St Marys Senior High School | St Marys | English Extension 2 | 5 |
| 1944 | St Patricks College Strathfield | Strathfield | Economics | 5 |
| 1945 | St Patricks College Strathfield | Strathfield | Modern History | 5 |
| 1946 | St Patricks Marist College | Dundas | Mathematics Extension 1 | 5 |
| 1947 | St Patricks Marist College | Dundas | Studies of Religion II | 5 |
| 1948 | St Pauls Catholic College Booragul | Booragul | Community and Family Studies | 5 |
| 1949 | St Philips Christian College Newcastle | Waratah | Mathematics Advanced | 5 |
| 1950 | St Philips Christian College Newcastle | Waratah | Music 1 | 5 |
| 1951 | St Pius X College | Chatswood | Modern History | 5 |
| 1952 | St Scholasticas College Glebe Point | Glebe Point | Textiles and Design | 5 |
| 1953 | St Scholasticas College Glebe Point | Glebe Point | Visual Arts | 5 |
| 1954 | St Spyridon College Senior School | Maroubra | Legal Studies | 5 |
| 1955 | St Spyridon College Senior School | Maroubra | Mathematics Advanced | 5 |
| 1956 | St Spyridon College Senior School | Maroubra | Music 1 | 5 |
| 1957 | St Stanislaus College | Bathurst | Legal Studies | 5 |
| 1958 | St Ursulas College | Kingsgrove | Ancient History | 5 |
| 1959 | St Ursulas College | Kingsgrove | Hospitality Examination | 5 |
| 1960 | St Vincents College | Potts Point | Ancient History | 5 |
| 1961 | St Vincents College | Potts Point | English Extension 2 | 5 |
| 1962 | St Vincents College | Potts Point | Music 1 | 5 |
| 1963 | Stella Maris College | Manly | English Advanced | 5 |
| 1964 | Stella Maris College | Manly | Studies of Religion II | 5 |
| 1965 | Strathfield Girls High School | Strathfield | Food Technology | 5 |
| 1966 | Strathfield Girls High School | Strathfield | Mathematics Extension 1 | 5 |
| 1967 | Sydney Boys High School | Moore Park | Geography | 5 |
| 1968 | Sydney Girls High School | Surry Hills | Economics | 5 |
| 1969 | Sydney Grammar School | Darlinghurst | Chinese Continuers | 5 |
| 1970 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Business Studies | 5 |
| 1971 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Earth and Environmental Science | 5 |
| 1972 | Sydney Secondary College Blackwattle Bay Campus | Glebe | English Extension 1 | 5 |
| 1973 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Mathematics Extension 2 | 5 |
| 1974 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Personal Development, Health and Physical Education | 5 |
| 1975 | Sydney Technical High School | Bexley | Biology | 5 |
| 1976 | Sydney Technical High School | Bexley | English Standard | 5 |
| 1977 | Sydney Technical High School | Bexley | Music 1 | 5 |
| 1978 | Sydney Technical High School | Bexley | Software Design and Development | 5 |
| 1979 | Tangara School for Girls | Cherrybrook | English Advanced | 5 |
| 1980 | Tara Anglican School for Girls | North Parramatta | Mathematics Extension 1 | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 6 Sep 2023