| 1896 | Smiths Hill High School | Wollongong | Visual Arts | 5 |
| 1897 | Snowy Mountains Grammar School | Jindabyne | English Advanced | 5 |
| 1898 | Springwood High School | Springwood | Textiles and Design | 5 |
| 1899 | St Aloysius College | Milsons Point | Music 2 | 5 |
| 1900 | St Andrews Cathedral School | Sydney | Music 1 | 5 |
| 1901 | St Andrews College Senior Campus | Marayong | History Extension | 5 |
| 1902 | St Augustines College | Brookvale | Drama | 5 |
| 1903 | St Augustines College | Brookvale | Engineering Studies | 5 |
| 1904 | St Catherines School | Waverley | Biology | 5 |
| 1905 | St Catherines School | Waverley | Economics | 5 |
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| 1906 | St Catherines School | Waverley | Geography | 5 |
| 1907 | St Catherines School | Waverley | Music 2 | 5 |
| 1908 | St Catherines School | Waverley | Personal Development, Health and Physical Education | 5 |
| 1909 | St Catherines School | Waverley | Studies of Religion I | 5 |
| 1910 | St Catherines School | Waverley | Visual Arts | 5 |
| 1911 | St Charbels College | Punchbowl | English Advanced | 5 |
| 1912 | St Charbels College | Punchbowl | Mathematics Standard 2 | 5 |
| 1913 | St Clares College | Waverley | Mathematics Advanced | 5 |
| 1914 | St Clares High School | Taree | Drama | 5 |
| 1915 | St Columba Anglican School | Port Macquarie | Drama | 5 |
| 1916 | St Columbas Catholic College | Springwood | Legal Studies | 5 |
| 1917 | St Columbas Catholic College | Springwood | Music 1 | 5 |
| 1918 | St Columbas Catholic College | Springwood | Studies of Religion II | 5 |
| 1919 | St Edwards Christian Brothers College | East Gosford | Industrial Technology | 5 |
| 1920 | St Euphemia College | Bankstown | Modern Greek Continuers | 5 |
| 1921 | St Francis Xaviers College | Hamilton | English Advanced | 5 |
| 1922 | St Francis Xaviers College | Hamilton | Legal Studies | 5 |
| 1923 | St Francis Xaviers College | Hamilton | Mathematics Extension 1 | 5 |
| 1924 | St Francis Xaviers College | Hamilton | Studies of Religion I | 5 |
| 1925 | St George Christian School | Hurstville | Modern History | 5 |
| 1926 | St George Girls High School | Kogarah | English Extension 2 | 5 |
| 1927 | St George Girls High School | Kogarah | Personal Development, Health and Physical Education | 5 |
| 1928 | St Ignatius College | Lane Cove | Physics | 5 |
| 1929 | St John Bosco College | Engadine | Legal Studies | 5 |
| 1930 | St John Bosco College | Engadine | Mathematics Extension 1 | 5 |
| 1931 | St John Paul II Catholic College Nirimba | Quakers Hill | Visual Arts | 5 |
| 1932 | St Josephs College Banora Point | Banora Point | English Advanced | 5 |
| 1933 | St Josephs College Banora Point | Banora Point | Studies of Religion I | 5 |
| 1934 | St Josephs College Hunters Hill | Hunters Hill | Ancient History | 5 |
| 1935 | St Josephs College Hunters Hill | Hunters Hill | Personal Development, Health and Physical Education | 5 |
| 1936 | St Lukes Catholic College Secondary | Marsden Park | Studies of Religion I | 5 |
| 1937 | St Lukes Grammar School | Dee Why | Ancient History | 5 |
| 1938 | St Lukes Grammar School | Dee Why | Modern History | 5 |
| 1939 | St Marks Coptic Orthodox College | Wattle Grove | Chemistry | 5 |
| 1940 | St Mary Star of the Sea College | Wollongong | Biology | 5 |
| 1941 | St Mary Star of the Sea College | Wollongong | English Advanced | 5 |
| 1942 | St Marys Cathedral College | Sydney | Mathematics Standard 2 | 5 |
| 1943 | St Marys Senior High School | St Marys | English Extension 2 | 5 |
| 1944 | St Patricks College Strathfield | Strathfield | Economics | 5 |
| 1945 | St Patricks College Strathfield | Strathfield | Modern History | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 6 Sep 2023