| 1996 | Ryde Secondary College | Ryde | Japanese Beginners | 5 |
| 1997 | Santa Sabina College | Strathfield | Business Studies | 5 |
| 1998 | Santa Sabina College | Strathfield | Chemistry | 5 |
| 1999 | Santa Sabina College | Strathfield | Japanese Continuers | 5 |
| 2000 | Santa Sabina College | Strathfield | Legal Studies | 5 |
| 2001 | SCEGGS Darlinghurst | Darlinghurst | Ancient History | 5 |
| 2002 | SCEGGS Darlinghurst | Darlinghurst | Economics | 5 |
| 2003 | SCEGGS Darlinghurst | Darlinghurst | French Continuers | 5 |
| 2004 | SCEGGS Darlinghurst | Darlinghurst | Personal Development, Health and Physical Education | 5 |
| 2005 | SCEGGS Darlinghurst | Darlinghurst | Spanish Beginners | 5 |
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| 2006 | SEDA College NSW | Glebe | Mathematics Standard 1 Examination | 5 |
| 2007 | Sefton High School | Sefton | Studies of Religion I | 5 |
| 2008 | SHORE Sydney Church of England Grammar School | North Sydney | Design and Technology | 5 |
| 2009 | SHORE Sydney Church of England Grammar School | North Sydney | English Extension 1 | 5 |
| 2010 | Smiths Hill High School | Wollongong | Japanese Continuers | 5 |
| 2011 | Smiths Hill High School | Wollongong | Mathematics Extension 2 | 5 |
| 2012 | St Augustines College | Brookvale | Drama | 5 |
| 2013 | St Augustines College | Brookvale | Japanese Beginners | 5 |
| 2014 | St Augustines College | Brookvale | Personal Development, Health and Physical Education | 5 |
| 2015 | St Benedicts Catholic College | Oran Park | Design and Technology | 5 |
| 2016 | St Benedicts Catholic College | Oran Park | English Advanced | 5 |
| 2017 | St Benedicts Catholic College | Oran Park | Industrial Technology | 5 |
| 2018 | St Benedicts Catholic College | Oran Park | Studies of Religion I | 5 |
| 2019 | St Catherines School | Waverley | History Extension | 5 |
| 2020 | St Charbels College | Punchbowl | English Advanced | 5 |
| 2021 | St Charbels College | Punchbowl | Mathematics Advanced | 5 |
| 2022 | St Clares College | Waverley | Legal Studies | 5 |
| 2023 | St Columba Anglican School | Port Macquarie | Personal Development, Health and Physical Education | 5 |
| 2024 | St Edwards Christian Brothers College | East Gosford | Industrial Technology | 5 |
| 2025 | St Francis De Sales Regional College | Leeton | Mathematics Standard 2 | 5 |
| 2026 | St Francis Xaviers College | Hamilton | Visual Arts | 5 |
| 2027 | St George Christian School | Hurstville | Mathematics Extension 1 | 5 |
| 2028 | St George Christian School | Hurstville | Visual Arts | 5 |
| 2029 | St George Girls High School | Kogarah | Chemistry | 5 |
| 2030 | St George Girls High School | Kogarah | Drama | 5 |
| 2031 | St George Girls High School | Kogarah | Modern History | 5 |
| 2032 | St Gregorys College Campbelltown | Gregory Hills | Industrial Technology | 5 |
| 2033 | St Gregorys College Campbelltown | Gregory Hills | Mathematics Extension 1 | 5 |
| 2034 | St Ignatius College | Lane Cove | Chinese Continuers | 5 |
| 2035 | St Ignatius College | Lane Cove | Chinese Extension | 5 |
| 2036 | St Ignatius College | Lane Cove | Music 1 | 5 |
| 2037 | St Ives High School | St Ives | Visual Arts | 5 |
| 2038 | St John Bosco College | Engadine | English Advanced | 5 |
| 2039 | St John Bosco College | Engadine | Mathematics Extension 1 | 5 |
| 2040 | St Josephs Catholic College | East Gosford | Visual Arts | 5 |
| 2041 | St Josephs College Hunters Hill | Hunters Hill | Chemistry | 5 |
| 2042 | St Josephs College Lochinvar | Lochinvar | Studies of Religion I | 5 |
| 2043 | St Josephs Regional College | Port Macquarie | Mathematics Standard 2 | 5 |
| 2044 | St Lukes Grammar School | Dee Why | Chemistry | 5 |
| 2045 | St Lukes Grammar School | Dee Why | Design and Technology | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 7 Sep 2023