| 1956 | Parramatta High School | Parramatta | Business Studies | 5 |
| 1957 | Parramatta Marist High School | Westmead | English Standard | 5 |
| 1958 | Parramatta Marist High School | Westmead | Legal Studies | 5 |
| 1959 | Parramatta Marist High School | Westmead | Physics | 5 |
| 1960 | Patrician Brothers College Blacktown | Blacktown | Society and Culture | 5 |
| 1961 | Pennant Hills High School | Pennant Hills | Mathematics Extension 2 | 5 |
| 1962 | Pennant Hills High School | Pennant Hills | Physics | 5 |
| 1963 | Penrith High School | Penrith | Engineering Studies | 5 |
| 1964 | Pittwater High School | Mona Vale | Industrial Technology | 5 |
| 1965 | Pittwater High School | Mona Vale | Society and Culture | 5 |
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| 1966 | Pittwater House Schools | Collaroy | English Advanced | 5 |
| 1967 | Pittwater House Schools | Collaroy | Legal Studies | 5 |
| 1968 | Port Hacking High School | Miranda | Personal Development, Health and Physical Education | 5 |
| 1969 | Prairiewood High School | Prairiewood | Business Studies | 5 |
| 1970 | Prairiewood High School | Prairiewood | Chemistry | 5 |
| 1971 | Presbyterian Ladies College Sydney | Croydon | Business Studies | 5 |
| 1972 | Presbyterian Ladies College Sydney | Croydon | English EAL/D | 5 |
| 1973 | Presbyterian Ladies College Sydney | Croydon | Japanese Continuers | 5 |
| 1974 | Presbyterian Ladies College Sydney | Croydon | Legal Studies | 5 |
| 1975 | Presbyterian Ladies College Sydney | Croydon | Mathematics Extension 2 | 5 |
| 1976 | Presbyterian Ladies College Sydney | Croydon | Music Extension | 5 |
| 1977 | Pymble Ladies College | Pymble | Economics | 5 |
| 1978 | Pymble Ladies College | Pymble | Music Extension | 5 |
| 1979 | Queenwood School for Girls | Mosman | Design and Technology | 5 |
| 1980 | Queenwood School for Girls | Mosman | English Extension 1 | 5 |
| 1981 | Queenwood School for Girls | Mosman | Geography | 5 |
| 1982 | Reddam House Bondi Campus | North Bondi | Chinese and Literature | 5 |
| 1983 | Reddam House Bondi Campus | North Bondi | Personal Development, Health and Physical Education | 5 |
| 1984 | Redfield College | Dural | Modern History | 5 |
| 1985 | Riverside Girls High School | Gladesville | Mathematics Standard 2 | 5 |
| 1986 | Rose Bay Secondary College | Dover Heights | Biology | 5 |
| 1987 | Rose Bay Secondary College | Dover Heights | Business Studies | 5 |
| 1988 | Rose Bay Secondary College | Dover Heights | Society and Culture | 5 |
| 1989 | Rosebank College | Five Dock | Business Studies | 5 |
| 1990 | Rosebank College | Five Dock | English Advanced | 5 |
| 1991 | Roseville College | Roseville | Biology | 5 |
| 1992 | Roseville College | Roseville | Design and Technology | 5 |
| 1993 | Roseville College | Roseville | History Extension | 5 |
| 1994 | Roseville College | Roseville | Mathematics Extension 1 | 5 |
| 1995 | Ryde Secondary College | Ryde | Business Studies | 5 |
| 1996 | Ryde Secondary College | Ryde | Japanese Beginners | 5 |
| 1997 | Santa Sabina College | Strathfield | Business Studies | 5 |
| 1998 | Santa Sabina College | Strathfield | Chemistry | 5 |
| 1999 | Santa Sabina College | Strathfield | Japanese Continuers | 5 |
| 2000 | Santa Sabina College | Strathfield | Legal Studies | 5 |
| 2001 | SCEGGS Darlinghurst | Darlinghurst | Ancient History | 5 |
| 2002 | SCEGGS Darlinghurst | Darlinghurst | Economics | 5 |
| 2003 | SCEGGS Darlinghurst | Darlinghurst | French Continuers | 5 |
| 2004 | SCEGGS Darlinghurst | Darlinghurst | Personal Development, Health and Physical Education | 5 |
| 2005 | SCEGGS Darlinghurst | Darlinghurst | Spanish Beginners | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 7 Sep 2023