| 1986 | Rose Bay Secondary College | Dover Heights | Biology | 5 |
| 1987 | Rose Bay Secondary College | Dover Heights | Business Studies | 5 |
| 1988 | Rose Bay Secondary College | Dover Heights | Society and Culture | 5 |
| 1989 | Rosebank College | Five Dock | Business Studies | 5 |
| 1990 | Rosebank College | Five Dock | English Advanced | 5 |
| 1991 | Roseville College | Roseville | Biology | 5 |
| 1992 | Roseville College | Roseville | Design and Technology | 5 |
| 1993 | Roseville College | Roseville | History Extension | 5 |
| 1994 | Roseville College | Roseville | Mathematics Extension 1 | 5 |
| 1995 | Ryde Secondary College | Ryde | Business Studies | 5 |
| 1996 | Ryde Secondary College | Ryde | Japanese Beginners | 5 |
| 1997 | Santa Sabina College | Strathfield | Business Studies | 5 |
| 1998 | Santa Sabina College | Strathfield | Chemistry | 5 |
| 1999 | Santa Sabina College | Strathfield | Japanese Continuers | 5 |
| 2000 | Santa Sabina College | Strathfield | Legal Studies | 5 |
| 2001 | SCEGGS Darlinghurst | Darlinghurst | Ancient History | 5 |
| 2002 | SCEGGS Darlinghurst | Darlinghurst | Economics | 5 |
| 2003 | SCEGGS Darlinghurst | Darlinghurst | French Continuers | 5 |
| 2004 | SCEGGS Darlinghurst | Darlinghurst | Personal Development, Health and Physical Education | 5 |
| 2005 | SCEGGS Darlinghurst | Darlinghurst | Spanish Beginners | 5 |
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| 2006 | SEDA College NSW | Glebe | Mathematics Standard 1 Examination | 5 |
| 2007 | Sefton High School | Sefton | Studies of Religion I | 5 |
| 2008 | SHORE Sydney Church of England Grammar School | North Sydney | Design and Technology | 5 |
| 2009 | SHORE Sydney Church of England Grammar School | North Sydney | English Extension 1 | 5 |
| 2010 | Smiths Hill High School | Wollongong | Japanese Continuers | 5 |
| 2011 | Smiths Hill High School | Wollongong | Mathematics Extension 2 | 5 |
| 2012 | St Augustines College | Brookvale | Drama | 5 |
| 2013 | St Augustines College | Brookvale | Japanese Beginners | 5 |
| 2014 | St Augustines College | Brookvale | Personal Development, Health and Physical Education | 5 |
| 2015 | St Benedicts Catholic College | Oran Park | Design and Technology | 5 |
| 2016 | St Benedicts Catholic College | Oran Park | English Advanced | 5 |
| 2017 | St Benedicts Catholic College | Oran Park | Industrial Technology | 5 |
| 2018 | St Benedicts Catholic College | Oran Park | Studies of Religion I | 5 |
| 2019 | St Catherines School | Waverley | History Extension | 5 |
| 2020 | St Charbels College | Punchbowl | English Advanced | 5 |
| 2021 | St Charbels College | Punchbowl | Mathematics Advanced | 5 |
| 2022 | St Clares College | Waverley | Legal Studies | 5 |
| 2023 | St Columba Anglican School | Port Macquarie | Personal Development, Health and Physical Education | 5 |
| 2024 | St Edwards Christian Brothers College | East Gosford | Industrial Technology | 5 |
| 2025 | St Francis De Sales Regional College | Leeton | Mathematics Standard 2 | 5 |
| 2026 | St Francis Xaviers College | Hamilton | Visual Arts | 5 |
| 2027 | St George Christian School | Hurstville | Mathematics Extension 1 | 5 |
| 2028 | St George Christian School | Hurstville | Visual Arts | 5 |
| 2029 | St George Girls High School | Kogarah | Chemistry | 5 |
| 2030 | St George Girls High School | Kogarah | Drama | 5 |
| 2031 | St George Girls High School | Kogarah | Modern History | 5 |
| 2032 | St Gregorys College Campbelltown | Gregory Hills | Industrial Technology | 5 |
| 2033 | St Gregorys College Campbelltown | Gregory Hills | Mathematics Extension 1 | 5 |
| 2034 | St Ignatius College | Lane Cove | Chinese Continuers | 5 |
| 2035 | St Ignatius College | Lane Cove | Chinese Extension | 5 |
| 2036 | St Ignatius College | Lane Cove | Music 1 | 5 |
| 2037 | St Ives High School | St Ives | Visual Arts | 5 |
| 2038 | St John Bosco College | Engadine | English Advanced | 5 |
| 2039 | St John Bosco College | Engadine | Mathematics Extension 1 | 5 |
| 2040 | St Josephs Catholic College | East Gosford | Visual Arts | 5 |
| 2041 | St Josephs College Hunters Hill | Hunters Hill | Chemistry | 5 |
| 2042 | St Josephs College Lochinvar | Lochinvar | Studies of Religion I | 5 |
| 2043 | St Josephs Regional College | Port Macquarie | Mathematics Standard 2 | 5 |
| 2044 | St Lukes Grammar School | Dee Why | Chemistry | 5 |
| 2045 | St Lukes Grammar School | Dee Why | Design and Technology | 5 |
| 2046 | St Marks Catholic College | Stanhope Gardens | Business Services Examination | 5 |
| 2047 | St Marks Catholic College | Stanhope Gardens | Mathematics Extension 1 | 5 |
| 2048 | St Marks Catholic College | Stanhope Gardens | Visual Arts | 5 |
| 2049 | St Marks Coptic Orthodox College | Wattle Grove | English Extension 1 | 5 |
| 2050 | St Mary and St Minas Coptic Orthodox College | Rockdale | English Advanced | 5 |
| 2051 | St Mary Star of the Sea College | Wollongong | Business Studies | 5 |
| 2052 | St Marys Cathedral College | Sydney | English Extension 1 | 5 |
| 2053 | St Marys Cathedral College | Sydney | Mathematics Extension 1 | 5 |
| 2054 | St Marys Catholic College Casino | Casino | Mathematics Standard 2 | 5 |
| 2055 | St Marys Senior High School | St Marys | Music 1 | 5 |
| 2056 | St Marys Senior High School | St Marys | Society and Culture | 5 |
| 2057 | St Patricks College Strathfield | Strathfield | English Extension 1 | 5 |
| 2058 | St Patricks College Sutherland | Sutherland | Visual Arts | 5 |
| 2059 | St Pauls Catholic College Manly | Manly | Mathematics Advanced | 5 |
| 2060 | St Philips Christian College Newcastle | Waratah | Design and Technology | 5 |
| 2061 | St Pius X College | Chatswood | Mathematics Extension 2 | 5 |
| 2062 | St Pius X College | Chatswood | Mathematics Standard 2 | 5 |
| 2063 | St Scholasticas College Glebe Point | Glebe Point | Studies of Religion I | 5 |
| 2064 | St Spyridon College Senior School | Maroubra | Chemistry | 5 |
| 2065 | St Stanislaus College | Bathurst | English Advanced | 5 |
| 2066 | St Ursulas College | Kingsgrove | Ancient History | 5 |
| 2067 | St Ursulas College | Kingsgrove | Hospitality Examination | 5 |
| 2068 | St Ursulas College | Kingsgrove | Music 1 | 5 |
| 2069 | St Ursulas College | Kingsgrove | Personal Development, Health and Physical Education | 5 |
| 2070 | St Ursulas College | Kingsgrove | Visual Arts | 5 |
| 2071 | St Vincents College | Potts Point | Design and Technology | 5 |
| 2072 | St Vincents College | Potts Point | English Extension 1 | 5 |
| 2073 | St Vincents College | Potts Point | Legal Studies | 5 |
| 2074 | St Vincents College | Potts Point | Mathematics Extension 1 | 5 |
| 2075 | St Vincents College | Potts Point | Studies of Religion I | 5 |
| 2076 | Stella Maris College | Manly | Business Studies | 5 |
| 2077 | Stella Maris College | Manly | Mathematics Extension 1 | 5 |
| 2078 | Strathfield Girls High School | Strathfield | English Extension 1 | 5 |
| 2079 | Sydney Boys High School | Moore Park | History Extension | 5 |
| 2080 | Sydney Girls High School | Surry Hills | English Extension 2 | 5 |
| 2081 | Sydney Girls High School | Surry Hills | Information Processes and Technology | 5 |
| 2082 | Sydney Girls High School | Surry Hills | Japanese Extension | 5 |
| 2083 | Sydney Girls High School | Surry Hills | Visual Arts | 5 |
| 2084 | Sydney Grammar School | Darlinghurst | Design and Technology | 5 |
| 2085 | Sydney Grammar School | Darlinghurst | Drama | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 7 Sep 2023