| 1976 | St Ignatius College | Lane Cove | English Extension 2 | 5 |
| 1977 | St Ignatius College | Lane Cove | Personal Development, Health and Physical Education | 5 |
| 1978 | St Ives High School | St Ives | Business Studies | 5 |
| 1979 | St Ives High School | St Ives | Visual Arts | 5 |
| 1980 | St Johns College Dubbo | Dubbo East | English Advanced | 5 |
| 1981 | St Johns Park High School | St Johns Park | Mathematics Extension 1 | 5 |
| 1982 | St Josephs College Banora Point | Banora Point | Studies of Religion I | 5 |
| 1983 | St Josephs College Hunters Hill | Hunters Hill | Modern History | 5 |
| 1984 | St Lukes Grammar School | Dee Why | Geography | 5 |
| 1985 | St Lukes Grammar School | Dee Why | Physics | 5 |
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| 1986 | St Marks Coptic Orthodox College | Wattle Grove | Business Studies | 5 |
| 1987 | St Mary Star of the Sea College | Wollongong | Legal Studies | 5 |
| 1988 | St Marys Cathedral College | Sydney | Mathematics Extension 1 | 5 |
| 1989 | St Marys Cathedral College | Sydney | Visual Arts | 5 |
| 1990 | St Marys Senior High School | St Marys | English Extension 1 | 5 |
| 1991 | St Patricks College Strathfield | Strathfield | Italian Continuers | 5 |
| 1992 | St Patricks College Strathfield | Strathfield | Personal Development, Health and Physical Education | 5 |
| 1993 | St Patricks College Sutherland | Sutherland | Biology | 5 |
| 1994 | St Patricks College Sutherland | Sutherland | Chemistry | 5 |
| 1995 | St Patricks Marist College | Dundas | English Extension 1 | 5 |
| 1996 | St Patricks Marist College | Dundas | Mathematics | 5 |
| 1997 | St Peters Catholic College | Tuggerah | Business Studies | 5 |
| 1998 | St Philips Christian College Newcastle | Waratah | Personal Development, Health and Physical Education | 5 |
| 1999 | St Pius X College | Chatswood | English Advanced | 5 |
| 2000 | St Pius X College | Chatswood | Legal Studies | 5 |
| 2001 | St Pius X College | Chatswood | Mathematics Extension 2 | 5 |
| 2002 | St Pius X College | Chatswood | Physics | 5 |
| 2003 | St Spyridon College Senior School | Maroubra | Music 1 | 5 |
| 2004 | St Ursulas College | Kingsgrove | Economics | 5 |
| 2005 | St Vincents College | Potts Point | Business Studies | 5 |
| 2006 | St Vincents College | Potts Point | Society and Culture | 5 |
| 2007 | St Vincents College | Potts Point | Textiles and Design | 5 |
| 2008 | Stella Maris College | Manly | English Extension 1 | 5 |
| 2009 | Stella Maris College | Manly | Legal Studies | 5 |
| 2010 | Stella Maris College | Manly | Mathematics Extension 1 | 5 |
| 2011 | Stella Maris College | Manly | Studies of Religion II | 5 |
| 2012 | Strathfield Girls High School | Strathfield | History Extension | 5 |
| 2013 | Sydney Girls High School | Surry Hills | Music 2 | 5 |
| 2014 | Sydney Girls High School | Surry Hills | Textiles and Design | 5 |
| 2015 | Sydney Grammar School | Darlinghurst | Italian Continuers | 5 |
| 2016 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Chemistry | 5 |
| 2017 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Music 1 | 5 |
| 2018 | Sydney Technical High School | Bexley | Personal Development, Health and Physical Education | 5 |
| 2019 | Tangara School for Girls | Cherrybrook | Music 1 | 5 |
| 2020 | Tara Anglican School for Girls | North Parramatta | Mathematics | 5 |
| 2021 | Tempe High School | Tempe | English Extension 1 | 5 |
| 2022 | Tempe High School | Tempe | Visual Arts | 5 |
| 2023 | The Armidale School | Armidale | Drama | 5 |
| 2024 | The Armidale School | Armidale | English Advanced | 5 |
| 2025 | The Hills Grammar School | Kenthurst | English Extension 1 | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 10 Oct 2024