| 1866 | Pymble Ladies College | Pymble | Agriculture | 5 |
| 1867 | Pymble Ladies College | Pymble | Latin Extension | 5 |
| 1868 | Pymble Ladies College | Pymble | Textiles and Design | 5 |
| 1869 | Queenwood School for Girls | Mosman | Personal Development, Health and Physical Education | 5 |
| 1870 | Randwick Girls High School | Randwick | Chinese and Literature | 5 |
| 1871 | Randwick Girls High School | Randwick | Japanese Beginners | 5 |
| 1872 | Randwick Girls High School | Randwick | Mathematics General 2 | 5 |
| 1873 | Randwick Girls High School | Randwick | Visual Arts | 5 |
| 1874 | Ravenswood School for Girls | Gordon | English Extension 2 | 5 |
| 1875 | Red Bend Catholic College | Forbes | Studies of Religion I | 5 |
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| 1876 | Reddam House Bondi Campus | North Bondi | Chemistry | 5 |
| 1877 | Reddam House Bondi Campus | North Bondi | Economics | 5 |
| 1878 | Richard Johnson Anglican College | Oakhurst | Music 1 | 5 |
| 1879 | Riverside Girls High School | Gladesville | Drama | 5 |
| 1880 | Rose Bay Secondary College | Dover Heights | Legal Studies | 5 |
| 1881 | Rosebank College | Five Dock | English Extension 1 | 5 |
| 1882 | Ryde Secondary College | Ryde | Mathematics Extension 1 | 5 |
| 1883 | Ryde Secondary College | Ryde | Mathematics Extension 2 | 5 |
| 1884 | Santa Sabina College | Strathfield | Biology | 5 |
| 1885 | Santa Sabina College | Strathfield | Music 1 | 5 |
| 1886 | Santa Sabina College | Strathfield | Music Extension | 5 |
| 1887 | Santa Sabina College | Strathfield | Textiles and Design | 5 |
| 1888 | SCECGS Redlands | Cremorne | Economics | 5 |
| 1889 | SCECGS Redlands | Cremorne | Visual Arts | 5 |
| 1890 | SCEGGS Darlinghurst | Darlinghurst | Personal Development, Health and Physical Education | 5 |
| 1891 | Sefton High School | Sefton | Chemistry | 5 |
| 1892 | Sefton High School | Sefton | Mathematics General 2 | 5 |
| 1893 | Shearwater The Mullumbimby Steiner School | Mullumbimby | Music 1 | 5 |
| 1894 | SHORE Sydney Church of England Grammar School | North Sydney | History Extension | 5 |
| 1895 | Smiths Hill High School | Wollongong | Modern History | 5 |
| 1896 | St Aloysius College | Milsons Point | Biology | 5 |
| 1897 | St Andrews Cathedral School | Sydney | English Extension 1 | 5 |
| 1898 | St Andrews Cathedral School | Sydney | Mathematics | 5 |
| 1899 | St Andrews Cathedral School | Sydney | Music Extension | 5 |
| 1900 | St Augustines College | Brookvale | Personal Development, Health and Physical Education | 5 |
| 1901 | St Catherines School | Waverley | Ancient History | 5 |
| 1902 | St Catherines School | Waverley | Economics | 5 |
| 1903 | St Charbels College | Punchbowl | Business Studies | 5 |
| 1904 | St Charbels College | Punchbowl | Mathematics | 5 |
| 1905 | St Clares College | Waverley | Biology | 5 |
| 1906 | St Clares College | Waverley | Mathematics | 5 |
| 1907 | St Clares College | Waverley | Society and Culture | 5 |
| 1908 | St Clares College | Waverley | Visual Arts | 5 |
| 1909 | St Columba Anglican School | Port Macquarie | Dance | 5 |
| 1910 | St Francis De Sales Regional College | Leeton | Hospitality Examination | 5 |
| 1911 | St Francis De Sales Regional College | Leeton | Personal Development, Health and Physical Education | 5 |
| 1912 | St Francis Xaviers College | Hamilton | Ancient History | 5 |
| 1913 | St Francis Xaviers College | Hamilton | Studies of Religion II | 5 |
| 1914 | St George Girls High School | Kogarah | Business Studies | 5 |
| 1915 | St George Girls High School | Kogarah | English Extension 2 | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 23 Oct 2024