| 2001 | Moorebank High School | Moorebank | English Extension 1 | 5 |
| 2002 | Moorebank High School | Moorebank | Legal Studies | 5 |
| 2003 | Moriah College | Queens Park | Biology | 5 |
| 2004 | Moriah College | Queens Park | Modern History | 5 |
| 2005 | Moriah College | Queens Park | Music 1 | 5 |
| 2006 | Moriah College | Queens Park | Physics | 5 |
| 2007 | Mosman High School | Mosman | Design and Technology | 5 |
| 2008 | Mount St Benedict College | Pennant Hills | Personal Development, Health and Physical Education | 5 |
| 2009 | Mount St Joseph Milperra | Milperra | Biology | 5 |
| 2010 | Mount St Patrick College | Murwillumbah | Biology | 5 |
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| 2011 | Mount St Patrick College | Murwillumbah | Legal Studies | 5 |
| 2012 | Mount St Patrick College | Murwillumbah | Music 1 | 5 |
| 2013 | Muirfield High School | North Rocks | English (Advanced) | 5 |
| 2014 | Muirfield High School | North Rocks | Personal Development, Health and Physical Education | 5 |
| 2015 | Nepean Creative and Performing Arts High School | Emu Plains | Music 1 | 5 |
| 2016 | Newcastle Grammar School | Newcastle | English Extension 1 | 5 |
| 2017 | Newington College | Stanmore | Business Studies | 5 |
| 2018 | Newington College | Stanmore | Design and Technology | 5 |
| 2019 | Newington College | Stanmore | English Extension 1 | 5 |
| 2020 | Newington College | Stanmore | Mathematics Extension 2 | 5 |
| 2021 | Newington College | Stanmore | Software Design and Development | 5 |
| 2022 | Newtown High School of Performing Arts | Newtown | Music 1 | 5 |
| 2023 | Normanhurst Boys High School | Normanhurst | Software Design and Development | 5 |
| 2024 | North Sydney Boys High School | Crows Nest | Music Extension | 5 |
| 2025 | North Sydney Girls High School | Crows Nest | Design and Technology | 5 |
| 2026 | North Sydney Girls High School | Crows Nest | Visual Arts | 5 |
| 2027 | Northern Beaches Secondary College Freshwater Campus | Freshwater | Business Studies | 5 |
| 2028 | Northern Beaches Secondary College Freshwater Campus | Freshwater | Mathematics Extension 1 | 5 |
| 2029 | Northern Beaches Secondary College Freshwater Campus | Freshwater | Music 1 | 5 |
| 2030 | Northern Beaches Secondary College Mackellar Girls Campus | Manly Vale | Business Studies | 5 |
| 2031 | Northern Beaches Secondary College Mackellar Girls Campus | Manly Vale | Chinese and Literature | 5 |
| 2032 | Nowra High School | Nowra | English (Advanced) | 5 |
| 2033 | Oakhill College | Castle Hill | Community and Family Studies | 5 |
| 2034 | Oakhill College | Castle Hill | Drama | 5 |
| 2035 | Oakhill College | Castle Hill | Food Technology | 5 |
| 2036 | Our Lady of Mercy College Parramatta | Parramatta | Modern History | 5 |
| 2037 | Our Lady of Mercy College Parramatta | Parramatta | Personal Development, Health and Physical Education | 5 |
| 2038 | Our Lady of the Sacred Heart College | Kensington | Mathematics General 2 | 5 |
| 2039 | Oxford Falls Grammar School | Oxford Falls | Biology | 5 |
| 2040 | Oxley College | Burradoo | Biology | 5 |
| 2041 | Parramatta High School | Parramatta | Legal Studies | 5 |
| 2042 | Parramatta High School | Parramatta | Mathematics Extension 2 | 5 |
| 2043 | Parramatta High School | Parramatta | Physics | 5 |
| 2044 | Parramatta Marist High School | Westmead | English (Standard) | 5 |
| 2045 | Parramatta Marist High School | Westmead | English Extension 1 | 5 |
| 2046 | Patrician Brothers College Blacktown | Blacktown | Studies of Religion I | 5 |
| 2047 | Patrician Brothers College Fairfield | Fairfield | Legal Studies | 5 |
| 2048 | Patrician Brothers College Fairfield | Fairfield | Mathematics Extension 1 | 5 |
| 2049 | Pennant Hills High School | Pennant Hills | Mathematics | 5 |
| 2050 | Penrith Anglican College | Orchard Hills | Personal Development, Health and Physical Education | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 14 Feb 2023