| 1906 | Homebush Boys High School | Homebush | Business Studies | 5 |
| 1907 | Homebush Boys High School | Homebush | Mathematics Extension 2 | 5 |
| 1908 | Hunter School of Performing Arts | Broadmeadow | Mathematics | 5 |
| 1909 | Hunter Valley Grammar School | Ashtonfield | Biology | 5 |
| 1910 | Hunter Valley Grammar School | Ashtonfield | Business Studies | 5 |
| 1911 | Hunter Valley Grammar School | Ashtonfield | Personal Development, Health and Physical Education | 5 |
| 1912 | Hurlstone Agricultural High School | Glenfield | Economics | 5 |
| 1913 | International Grammar School | Ultimo | Economics | 5 |
| 1914 | International Grammar School | Ultimo | Japanese Continuers | 5 |
| 1915 | International Grammar School | Ultimo | Mathematics | 5 |
| 1916 | IPEKA Integrated Christian School | Jakarta, Indonesia | Software Design and Development | 5 |
| 1917 | James Ruse Agricultural High School | Carlingford | English Extension 2 | 5 |
| 1918 | James Ruse Agricultural High School | Carlingford | Japanese Continuers | 5 |
| 1919 | James Sheahan Catholic High School | Orange | Mathematics General 2 | 5 |
| 1920 | Kambala | Rose Bay | Modern History | 5 |
| 1921 | Kellyville High School | Kellyville | Music 1 | 5 |
| 1922 | Kildare Catholic College | Wagga Wagga | English (Advanced) | 5 |
| 1923 | Kildare Catholic College | Wagga Wagga | English (Standard) | 5 |
| 1924 | Kildare Catholic College | Wagga Wagga | Modern History | 5 |
| 1925 | Killara High School | Killara | Ancient History | 5 |
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| 1926 | Killara High School | Killara | Legal Studies | 5 |
| 1927 | Killara High School | Killara | Music 1 | 5 |
| 1928 | Killara High School | Killara | Society and Culture | 5 |
| 1929 | Killara High School | Killara | Visual Arts | 5 |
| 1930 | Killarney Heights High School | Killarney Heights | Ancient History | 5 |
| 1931 | Kincoppal Rose Bay School of the Sacred Heart | Vaucluse | English Extension 2 | 5 |
| 1932 | Kincoppal Rose Bay School of the Sacred Heart | Vaucluse | Italian Beginners | 5 |
| 1933 | Kincumber High School | Kincumber | Legal Studies | 5 |
| 1934 | Kingsgrove High School | Kingsgrove | Mathematics Extension 1 | 5 |
| 1935 | Kinross Wolaroi School | Orange | Ancient History | 5 |
| 1936 | Kinross Wolaroi School | Orange | Industrial Technology | 5 |
| 1937 | Kinross Wolaroi School | Orange | Music 1 | 5 |
| 1938 | Kinross Wolaroi School | Orange | Studies of Religion I | 5 |
| 1939 | Kirrawee High School | Kirrawee | Legal Studies | 5 |
| 1940 | Knox Grammar School | Wahroonga | Geography | 5 |
| 1941 | Knox Grammar School | Wahroonga | Information Processes and Technology | 5 |
| 1942 | Korowal School | Hazelbrook | Visual Arts | 5 |
| 1943 | Lambton High School | Lambton | Mathematics Extension 1 | 5 |
| 1944 | Lisarow High School | Lisarow | Biology | 5 |
| 1945 | Loreto Kirribilli | Kirribilli | Biology | 5 |
| 1946 | Loreto Kirribilli | Kirribilli | Design and Technology | 5 |
| 1947 | Loreto Kirribilli | Kirribilli | English (Standard) | 5 |
| 1948 | Loreto Kirribilli | Kirribilli | French Continuers | 5 |
| 1949 | Loreto Normanhurst | Normanhurst | English Extension 1 | 5 |
| 1950 | Loreto Normanhurst | Normanhurst | History Extension | 5 |
| 1951 | Loreto Normanhurst | Normanhurst | Senior Science | 5 |
| 1952 | Loreto Normanhurst | Normanhurst | Visual Arts | 5 |
| 1953 | Lucas Heights Community School | Barden Ridge | Community and Family Studies | 5 |
| 1954 | Macarthur Anglican School | Cobbitty | Society and Culture | 5 |
| 1955 | Macarthur Girls High School | Parramatta | Personal Development, Health and Physical Education | 5 |
| 1956 | Macarthur Girls High School | Parramatta | Studies of Religion I | 5 |
| 1957 | MacKillop College Port Macquarie | Port Macquarie | Community and Family Studies | 5 |
| 1958 | MacKillop College Port Macquarie | Port Macquarie | Legal Studies | 5 |
| 1959 | Macquarie College | Wallsend | Mathematics | 5 |
| 1960 | Macquarie College | Wallsend | Studies of Religion II | 5 |
| 1961 | Macquarie Fields High School | Macquarie Fields | Mathematics Extension 2 | 5 |
| 1962 | Macquarie Fields High School | Macquarie Fields | Mathematics General 2 | 5 |
| 1963 | Malek Fahd Islamic School | Greenacre | Mathematics General 2 | 5 |
| 1964 | Marcellin College | Randwick | Geography | 5 |
| 1965 | Marcellin College | Randwick | Mathematics General 2 | 5 |
| 1966 | Marian Catholic College Kenthurst | Kenthurst | Personal Development, Health and Physical Education | 5 |
| 1967 | Marist College Eastwood | Eastwood | Biology | 5 |
| 1968 | Marist College Eastwood | Eastwood | English (Advanced) | 5 |
| 1969 | Marist College Kogarah | Bexley | English (Standard) | 5 |
| 1970 | Marist College Kogarah | Bexley | Studies of Religion II | 5 |
| 1971 | Marist College North Shore | North Sydney | English (Advanced) | 5 |
| 1972 | Marist College North Shore | North Sydney | Mathematics Extension 1 | 5 |
| 1973 | Marist College North Shore | North Sydney | Modern History | 5 |
| 1974 | Marist Sisters College Woolwich | Woolwich | Modern History | 5 |
| 1975 | Marist Sisters College Woolwich | Woolwich | Music 1 | 5 |
| 1976 | Mater Dei Catholic College | Wagga Wagga | Legal Studies | 5 |
| 1977 | Mater Dei Catholic College | Wagga Wagga | Mathematics General 2 | 5 |
| 1978 | Mater Dei Catholic College | Wagga Wagga | Music 1 | 5 |
| 1979 | Mater Maria Catholic College | Warriewood | Mathematics General 2 | 5 |
| 1980 | Mater Maria Catholic College | Warriewood | Music 1 | 5 |
| 1981 | Meadowbank Education Trust School | Sydney Olympic Park | English (Advanced) | 5 |
| 1982 | Menai High School | Menai | Personal Development, Health and Physical Education | 5 |
| 1983 | Mercy Catholic College | Chatswood | English (Advanced) | 5 |
| 1984 | Mercy Catholic College | Chatswood | Legal Studies | 5 |
| 1985 | Mercy Catholic College | Chatswood | Music 1 | 5 |
| 1986 | Mercy Catholic College | Chatswood | Visual Arts | 5 |
| 1987 | Merewether High School | Broadmeadow | Ancient History | 5 |
| 1988 | Merewether High School | Broadmeadow | Geography | 5 |
| 1989 | Meriden School | Strathfield | Business Studies | 5 |
| 1990 | Meriden School | Strathfield | Legal Studies | 5 |
| 1991 | Meriden School | Strathfield | Modern History | 5 |
| 1992 | Meriden School | Strathfield | Music 1 | 5 |
| 1993 | MLC School | Burwood | Mathematics Extension 1 | 5 |
| 1994 | MLC School | Burwood | Mathematics General 2 | 5 |
| 1995 | MLC School | Burwood | Music 2 | 5 |
| 1996 | MLC School | Burwood | Textiles and Design | 5 |
| 1997 | Model Farms High School | Baulkham Hills | Biology | 5 |
| 1998 | Model Farms High School | Baulkham Hills | Drama | 5 |
| 1999 | Model Farms High School | Baulkham Hills | Industrial Technology | 5 |
| 2000 | Monte Sant Angelo Mercy College | North Sydney | Society and Culture | 5 |
| 2001 | Moorebank High School | Moorebank | English Extension 1 | 5 |
| 2002 | Moorebank High School | Moorebank | Legal Studies | 5 |
| 2003 | Moriah College | Queens Park | Biology | 5 |
| 2004 | Moriah College | Queens Park | Modern History | 5 |
| 2005 | Moriah College | Queens Park | Music 1 | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 14 Feb 2023