| 1876 | St George Christian School | Hurstville | Music 1 | 5 |
| 1877 | St Gregorys College Campbelltown | Gregory Hills | Geography | 5 |
| 1878 | St Gregorys College Campbelltown | Gregory Hills | Mathematics Extension 1 | 5 |
| 1879 | St Gregorys College Campbelltown | Gregory Hills | Studies of Religion I | 5 |
| 1880 | St Gregorys College Campbelltown | Gregory Hills | Studies of Religion II | 5 |
| 1881 | St Ignatius College | Lane Cove | Chemistry | 5 |
| 1882 | St Ignatius College | Lane Cove | English Extension 2 | 5 |
| 1883 | St Ives High School | St Ives | Chinese Background Speakers | 5 |
| 1884 | St John Bosco College | Engadine | Design and Technology | 5 |
| 1885 | St John Paul College | Coffs Harbour | Legal Studies | 5 |
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| 1886 | St John Paul College | Coffs Harbour | Mathematics General 2 | 5 |
| 1887 | St John Paul College | Coffs Harbour | Senior Science | 5 |
| 1888 | St Johns College Dubbo | Dubbo East | Industrial Technology | 5 |
| 1889 | St Johns College Dubbo | Dubbo East | Visual Arts | 5 |
| 1890 | St Johns College Woodlawn | Lismore | Mathematics General 2 | 5 |
| 1891 | St Josephs Catholic College | East Gosford | Legal Studies | 5 |
| 1892 | St Josephs Catholic College | East Gosford | Personal Development, Health and Physical Education | 5 |
| 1893 | St Josephs Regional College | Port Macquarie | Mathematics General 2 | 5 |
| 1894 | St Lukes Grammar School | Dee Why | Biology | 5 |
| 1895 | St Lukes Grammar School | Dee Why | Studies of Religion I | 5 |
| 1896 | St Marks Coptic Orthodox College | Wattle Grove | Chemistry | 5 |
| 1897 | St Patricks College Strathfield | Strathfield | Industrial Technology | 5 |
| 1898 | St Patricks College Sutherland | Sutherland | Business Studies | 5 |
| 1899 | St Patricks College Sutherland | Sutherland | Design and Technology | 5 |
| 1900 | St Patricks College Sutherland | Sutherland | Legal Studies | 5 |
| 1901 | St Patricks College Sutherland | Sutherland | Mathematics Extension 1 | 5 |
| 1902 | St Pauls Catholic College Greystanes | Greystanes | Mathematics Extension 1 | 5 |
| 1903 | St Pauls Catholic College Greystanes | Greystanes | Studies of Religion I | 5 |
| 1904 | St Pauls Catholic College Manly | Manly | English (Advanced) | 5 |
| 1905 | St Pauls College Walla Walla | Walla Walla | English (Advanced) | 5 |
| 1906 | St Pauls College Walla Walla | Walla Walla | English Extension 1 | 5 |
| 1907 | St Pauls College Walla Walla | Walla Walla | Senior Science | 5 |
| 1908 | St Pauls College Walla Walla | Walla Walla | Studies of Religion I | 5 |
| 1909 | St Pauls College West Kempsey | West Kempsey | Industrial Technology | 5 |
| 1910 | St Pauls High School | Booragul | Studies of Religion I | 5 |
| 1911 | St Peters Catholic College | Tuggerah | English (Advanced) | 5 |
| 1912 | St Peters Catholic College | Tuggerah | Mathematics General 2 | 5 |
| 1913 | St Philips Christian College Newcastle | Waratah | Community and Family Studies | 5 |
| 1914 | St Scholasticas College Glebe Point | Glebe Point | Mathematics | 5 |
| 1915 | St Spyridon College Senior School | Maroubra | Modern Greek Continuers | 5 |
| 1916 | St Spyridon College Senior School | Maroubra | Modern Greek Extension | 5 |
| 1917 | St Spyridon College Senior School | Maroubra | Personal Development, Health and Physical Education | 5 |
| 1918 | St Ursulas College | Kingsgrove | Music 1 | 5 |
| 1919 | St Vincents College | Potts Point | Modern History | 5 |
| 1920 | Stella Maris College | Manly | Modern History | 5 |
| 1921 | Stella Maris College | Manly | Visual Arts | 5 |
| 1922 | Strathfield Girls High School | Strathfield | Tamil Continuers | 5 |
| 1923 | Strathfield Girls High School | Strathfield | Visual Arts | 5 |
| 1924 | Sutherland Shire Christian School | Barden Ridge | Studies of Religion I | 5 |
| 1925 | Sydney Boys High School | Moore Park | Biology | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 14 Feb 2023