| 1861 | St Andrews Cathedral School | Sydney | Mathematics Extension 1 | 5 |
| 1862 | St Andrews Cathedral School | Sydney | Music Extension | 5 |
| 1863 | St Augustines College | Brookvale | Business Studies | 5 |
| 1864 | St Catherines Catholic College | Singleton | Drama | 5 |
| 1865 | St Columba Anglican School | Port Macquarie | Geography | 5 |
| 1866 | St Dominics College | Kingswood | Ancient History | 5 |
| 1867 | St Dominics College | Kingswood | Business Studies | 5 |
| 1868 | St Euphemia College | Bankstown | Design and Technology | 5 |
| 1869 | St Euphemia College | Bankstown | English Extension 1 | 5 |
| 1870 | St Euphemia College | Bankstown | Modern Greek Extension | 5 |
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| 1871 | St Francis Xaviers College | Hamilton | Community and Family Studies | 5 |
| 1872 | St Francis Xaviers College | Hamilton | English Extension 2 | 5 |
| 1873 | St Francis Xaviers College | Hamilton | Mathematics | 5 |
| 1874 | St George Christian School | Hurstville | Music 1 | 5 |
| 1875 | St George Girls High School | Kogarah | Geography | 5 |
| 1876 | St George Girls High School | Kogarah | Physics | 5 |
| 1877 | St George Girls High School | Kogarah | Textiles and Design | 5 |
| 1878 | St Gregorys College Campbelltown | Gregory Hills | English (Advanced) | 5 |
| 1879 | St Gregorys College Campbelltown | Gregory Hills | Legal Studies | 5 |
| 1880 | St Gregorys College Campbelltown | Gregory Hills | Personal Development, Health and Physical Education | 5 |
| 1881 | St Ignatius College | Lane Cove | Chinese Extension | 5 |
| 1882 | St Ignatius College | Lane Cove | English Extension 2 | 5 |
| 1883 | St Ignatius College | Lane Cove | Visual Arts | 5 |
| 1884 | St Ives High School | St Ives | English as a Second Language | 5 |
| 1885 | St John Bosco College | Engadine | Design and Technology | 5 |
| 1886 | St John Paul College | Coffs Harbour | Studies of Religion I | 5 |
| 1887 | St Johns College | ? | English Extension 1 | 5 |
| 1888 | St Johns Park High School | St Johns Park | Ancient History | 5 |
| 1889 | St Johns Park High School | St Johns Park | Mathematics Extension 2 | 5 |
| 1890 | St Josephs Catholic High School | Albion Park | Studies of Religion I | 5 |
| 1891 | St Josephs College | ? | Geography | 5 |
| 1892 | St Josephs College | ? | Senior Science | 5 |
| 1893 | St Leos Catholic College | Wahroonga | Chemistry | 5 |
| 1894 | St Lukes Grammar School | Dee Why | Ancient History | 5 |
| 1895 | St Lukes Grammar School | Dee Why | Biology | 5 |
| 1896 | St Marys Cathedral College | Sydney | Mathematics Extension 1 | 5 |
| 1897 | St Marys Cathedral College | Sydney | Mathematics General 2 | 5 |
| 1898 | St Marys Cathedral College | Sydney | Physics | 5 |
| 1899 | St Marys Senior High School | St Marys | Hospitality Examination | 5 |
| 1900 | St Marys Senior High School | St Marys | Information Processes and Technology | 5 |
| 1901 | St Narsai Assyrian Christian College | Horsley Park | Mathematics | 5 |
| 1902 | St Patricks College Campbelltown | Campbelltown | English (Advanced) | 5 |
| 1903 | St Patricks College Campbelltown | Campbelltown | Music 1 | 5 |
| 1904 | St Patricks College Campbelltown | Campbelltown | Personal Development, Health and Physical Education | 5 |
| 1905 | St Patricks College Campbelltown | Campbelltown | Senior Science | 5 |
| 1906 | St Patricks College Strathfield | Strathfield | Biology | 5 |
| 1907 | St Patricks College Strathfield | Strathfield | Mathematics Extension 2 | 5 |
| 1908 | St Patricks College Strathfield | Strathfield | Music 1 | 5 |
| 1909 | St Patricks College Strathfield | Strathfield | Personal Development, Health and Physical Education | 5 |
| 1910 | St Pauls Catholic College | ? | Business Studies | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 14 Feb 2023