| 2006 | Baulkham Hills High School | Baulkham Hills | History Extension | 4 |
| 2007 | Bede Polding College | South Windsor | Hospitality Examination | 4 |
| 2008 | Bede Polding College | South Windsor | Legal Studies | 4 |
| 2009 | Bede Polding College | South Windsor | Mathematics General 2 | 4 |
| 2010 | Bellingen High School | Bellingen | Society and Culture | 4 |
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| 2011 | Belmont Christian College | Belmont North | Music 1 | 4 |
| 2012 | Bethany College | Hurstville | Ancient History | 4 |
| 2013 | Bethany College | Hurstville | Business Studies | 4 |
| 2014 | Bethany College | Hurstville | Mathematics | 4 |
| 2015 | Bethany College | Hurstville | Mathematics General 2 | 4 |
| 2016 | Bethany College | Hurstville | Visual Arts | 4 |
| 2017 | Bethlehem College | Ashfield | English (Advanced) | 4 |
| 2018 | Beverly Hills Girls High School | Beverly Hills | Mathematics | 4 |
| 2019 | Birrong Girls High School | Birrong | Business Studies | 4 |
| 2020 | Blakehurst High School | Blakehurst | Chinese Background Speakers | 4 |
| 2021 | Blakehurst High School | Blakehurst | Community and Family Studies | 4 |
| 2022 | Blakehurst High School | Blakehurst | Mathematics General 2 | 4 |
| 2023 | Blue Mountains Grammar School | Wentworth Falls | Mathematics General 2 | 4 |
| 2024 | Blue Mountains Grammar School | Wentworth Falls | Visual Arts | 4 |
| 2025 | Bonnyrigg High School | Bonnyrigg | Business Studies | 4 |
| 2026 | Bossley Park High School | Bossley Park | Mathematics | 4 |
| 2027 | Brigidine College Randwick | Randwick | Community and Family Studies | 4 |
| 2028 | Brigidine College Randwick | Randwick | Hospitality Examination | 4 |
| 2029 | Brigidine College St Ives | St Ives | Textiles and Design | 4 |
| 2030 | Broughton Anglican College | Menangle Park | Legal Studies | 4 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 14 Feb 2023