| 1891 | St Josephs College | ? | Geography | 5 |
| 1892 | St Josephs College | ? | Senior Science | 5 |
| 1893 | St Leos Catholic College | Wahroonga | Chemistry | 5 |
| 1894 | St Lukes Grammar School | Dee Why | Ancient History | 5 |
| 1895 | St Lukes Grammar School | Dee Why | Biology | 5 |
| 1896 | St Marys Cathedral College | Sydney | Mathematics Extension 1 | 5 |
| 1897 | St Marys Cathedral College | Sydney | Mathematics General 2 | 5 |
| 1898 | St Marys Cathedral College | Sydney | Physics | 5 |
| 1899 | St Marys Senior High School | St Marys | Hospitality Examination | 5 |
| 1900 | St Marys Senior High School | St Marys | Information Processes and Technology | 5 |
| 1901 | St Narsai Assyrian Christian College | Horsley Park | Mathematics | 5 |
| 1902 | St Patricks College Campbelltown | Campbelltown | English (Advanced) | 5 |
| 1903 | St Patricks College Campbelltown | Campbelltown | Music 1 | 5 |
| 1904 | St Patricks College Campbelltown | Campbelltown | Personal Development, Health and Physical Education | 5 |
| 1905 | St Patricks College Campbelltown | Campbelltown | Senior Science | 5 |
| 1906 | St Patricks College Strathfield | Strathfield | Biology | 5 |
| 1907 | St Patricks College Strathfield | Strathfield | Mathematics Extension 2 | 5 |
| 1908 | St Patricks College Strathfield | Strathfield | Music 1 | 5 |
| 1909 | St Patricks College Strathfield | Strathfield | Personal Development, Health and Physical Education | 5 |
| 1910 | St Pauls Catholic College | ? | Business Studies | 5 |
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| 1911 | St Pauls High School | Booragul | Studies of Religion I | 5 |
| 1912 | St Peters Catholic College | Tuggerah | Studies of Religion I | 5 |
| 1913 | St Philips Christian College Newcastle | Waratah | Mathematics | 5 |
| 1914 | St Philips Christian College Newcastle | Waratah | Studies of Religion II | 5 |
| 1915 | St Philips Christian College Newcastle | Waratah | Visual Arts | 5 |
| 1916 | St Pius X College | Chatswood | Chemistry | 5 |
| 1917 | St Pius X College | Chatswood | Physics | 5 |
| 1918 | St Scholasticas College Glebe Point | Glebe Point | Personal Development, Health and Physical Education | 5 |
| 1919 | St Spyridon College Senior School | Maroubra | Modern Greek Continuers | 5 |
| 1920 | St Ursulas College | Kingsgrove | Biology | 5 |
| 1921 | St Ursulas College | Kingsgrove | Community and Family Studies | 5 |
| 1922 | St Ursulas College | Kingsgrove | Personal Development, Health and Physical Education | 5 |
| 1923 | St Vincents College | Potts Point | Mathematics | 5 |
| 1924 | Stella Maris College | Manly | Mathematics | 5 |
| 1925 | Stella Maris College | Manly | Studies of Religion I | 5 |
| 1926 | Strathfield Girls High School | Strathfield | Business Studies | 5 |
| 1927 | Strathfield Girls High School | Strathfield | English as a Second Language | 5 |
| 1928 | Strathfield Girls High School | Strathfield | English Extension 1 | 5 |
| 1929 | Strathfield Girls High School | Strathfield | Heritage Korean | 5 |
| 1930 | Strathfield Girls High School | Strathfield | Japanese Continuers | 5 |
| 1931 | Strathfield Girls High School | Strathfield | Textiles and Design | 5 |
| 1932 | Sydney Boys High School | Moore Park | Ancient History | 5 |
| 1933 | Sydney Girls High School | Surry Hills | Latin Continuers | 5 |
| 1934 | Sydney Girls High School | Surry Hills | Latin Extension | 5 |
| 1935 | Sydney Grammar School | Darlinghurst | Chinese Continuers | 5 |
| 1936 | Sydney Technical High School | Bexley | Design and Technology | 5 |
| 1937 | Sydney Technical High School | Bexley | Modern History | 5 |
| 1938 | Tangara School for Girls | Cherrybrook | Biology | 5 |
| 1939 | Tangara School for Girls | Cherrybrook | English (Advanced) | 5 |
| 1940 | Tangara School for Girls | Cherrybrook | Modern History | 5 |
| 1941 | Tara Anglican School for Girls | North Parramatta | Biology | 5 |
| 1942 | Tara Anglican School for Girls | North Parramatta | English (Advanced) | 5 |
| 1943 | Tara Anglican School for Girls | North Parramatta | Food Technology | 5 |
| 1944 | Tara Anglican School for Girls | North Parramatta | Visual Arts | 5 |
| 1945 | Tempe High School | Tempe | Chemistry | 5 |
| 1946 | Tempe High School | Tempe | Legal Studies | 5 |
| 1947 | Tempe High School | Tempe | Personal Development, Health and Physical Education | 5 |
| 1948 | The Hills Grammar School | Kenthurst | English Extension 2 | 5 |
| 1949 | The Jannali High School | Jannali | Personal Development, Health and Physical Education | 5 |
| 1950 | The Kings School | North Parramatta | Economics | 5 |
| 1951 | The Kings School | North Parramatta | Geography | 5 |
| 1952 | The Kings School | North Parramatta | Personal Development, Health and Physical Education | 5 |
| 1953 | Trinity Anglican College Albury | Thurgoona | Personal Development, Health and Physical Education | 5 |
| 1954 | Trinity Catholic College Auburn Campus | Auburn | Chemistry | 5 |
| 1955 | Trinity Catholic College Lismore | Lismore | Ancient History | 5 |
| 1956 | Trinity Catholic College Lismore | Lismore | Italian Continuers | 5 |
| 1957 | Trinity Catholic College Lismore | Lismore | Mathematics | 5 |
| 1958 | Trinity Catholic College Lismore | Lismore | Personal Development, Health and Physical Education | 5 |
| 1959 | Trinity Grammar School | Summer Hill | Chemistry | 5 |
| 1960 | Trinity Grammar School | Summer Hill | English Extension 1 | 5 |
| 1961 | Turramurra High School | South Turramurra | Chinese Background Speakers | 5 |
| 1962 | Turramurra High School | South Turramurra | Legal Studies | 5 |
| 1963 | Turramurra High School | South Turramurra | Mathematics Extension 2 | 5 |
| 1964 | Warners Bay High School | Warners Bay | Music 1 | 5 |
| 1965 | Waverley College | Waverley | Mathematics | 5 |
| 1966 | Wenona School | North Sydney | French Continuers | 5 |
| 1967 | Westfields Sports High School | Fairfield West | Biology | 5 |
| 1968 | Willoughby Girls High School | Willoughby | Personal Development, Health and Physical Education | 5 |
| 1969 | Willoughby Girls High School | Willoughby | Senior Science | 5 |
| 1970 | Winmalee High School | Winmalee | Community and Family Studies | 5 |
| 1971 | Winmalee High School | Winmalee | English (Advanced) | 5 |
| 1972 | Woolooware High School | Woolooware | Mathematics General 2 | 5 |
| 1973 | Woolooware High School | Woolooware | Personal Development, Health and Physical Education | 5 |
| 1974 | Wycliffe Christian School | Warrimoo | Mathematics General 2 | 5 |
| 1975 | Wyndham College | Quakers Hill | Senior Science | 5 |
| 1976 | Wyndham College | Quakers Hill | Society and Culture | 5 |
| 1977 | Wyndham College | Quakers Hill | Visual Arts | 5 |
| 1978 | Xavier Catholic College | Skennars Head | Mathematics | 5 |
| 1979 | Xavier Catholic College | Skennars Head | Mathematics Extension 1 | 5 |
| 1980 | Abbotsleigh | Wahroonga | Physics | 4 |
| 1981 | Al-Faisal College | Auburn | Business Studies | 4 |
| 1982 | Al-Faisal College | Auburn | Community and Family Studies | 4 |
| 1983 | Alexandria Park Community School | Alexandria | Mathematics Extension 1 | 4 |
| 1984 | All Saints College Bathurst | Bathurst | Mathematics General 2 | 4 |
| 1985 | All Saints College St Marys Campus | Maitland | Biology | 4 |
| 1986 | All Saints College St Marys Campus | Maitland | Mathematics | 4 |
| 1987 | Alpha Omega Senior College | Auburn | Business Studies | 4 |
| 1988 | Alstonville High School | Alstonville | Biology | 4 |
| 1989 | Amity College Prestons | Prestons | Economics | 4 |
| 1990 | Aquinas College | Menai | English (Advanced) | 4 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 14 Feb 2023