| 1991 | All Saints College Bathurst | Bathurst | Mathematics | 4 |
| 1992 | All Saints College St Marys Campus | Maitland | Ancient History | 4 |
| 1993 | Alstonville High School | Alstonville | English Extension 1 | 4 |
| 1994 | Alstonville High School | Alstonville | Physics | 4 |
| 1995 | Aquinas College | Menai | Mathematics | 4 |
| 1996 | Aquinas College | Menai | Studies of Religion II | 4 |
| 1997 | Arden Anglican School Epping Campus | Epping | Mathematics | 4 |
| 1998 | Armidale High School | Armidale | Mathematics | 4 |
| 1999 | Ascham School | Edgecliff | German Extension | 4 |
| 2000 | Ascham School | Edgecliff | Mathematics Extension 2 | 4 |
| |
||||
| 2001 | Asquith Girls High School | Asquith | General Mathematics | 4 |
| 2002 | Asquith Girls High School | Asquith | Hospitality Examination | 4 |
| 2003 | Auburn Girls High School | Auburn | Biology | 4 |
| 2004 | Australian Institute of Music Senior Secondary College | Surry Hills | Music Extension | 4 |
| 2005 | Australian International School Hong Kong | Kowloon Tong, Hong Kong | General Mathematics | 4 |
| 2006 | Australian International School Singapore | Singapore | Legal Studies | 4 |
| 2007 | Bankstown Girls High School | Bankstown | Design and Technology | 4 |
| 2008 | Barker College | Hornsby | Agriculture | 4 |
| 2009 | Barker College | Hornsby | Information Processes and Technology | 4 |
| 2010 | Baulkham Hills High School | Baulkham Hills | Ancient History | 4 |
| 2011 | Baulkham Hills High School | Baulkham Hills | Latin Extension | 4 |
| 2012 | Baulkham Hills High School | Baulkham Hills | Visual Arts | 4 |
| 2013 | Bede Polding College | South Windsor | Ancient History | 4 |
| 2014 | Bede Polding College | South Windsor | General Mathematics | 4 |
| 2015 | Bede Polding College | South Windsor | Hospitality Examination | 4 |
| 2016 | Bede Polding College | South Windsor | Music 1 | 4 |
| 2017 | Bega High School | Bega | Ancient History | 4 |
| 2018 | Beverly Hills Girls High School | Beverly Hills | English (Advanced) | 4 |
| 2019 | Beverly Hills Girls High School | Beverly Hills | Mathematics Extension 1 | 4 |
| 2020 | Birrong Girls High School | Birrong | Ancient History | 4 |
| 2021 | Birrong Girls High School | Birrong | Biology | 4 |
| 2022 | Birrong Girls High School | Birrong | Mathematics Extension 1 | 4 |
| 2023 | Bishop Druitt College | Coffs Harbour | General Mathematics | 4 |
| 2024 | Blakehurst High School | Blakehurst | Business Studies | 4 |
| 2025 | Blakehurst High School | Blakehurst | Chemistry | 4 |
| 2026 | Blakehurst High School | Blakehurst | Community and Family Studies | 4 |
| 2027 | Blakehurst High School | Blakehurst | Japanese Beginners | 4 |
| 2028 | Blakehurst High School | Blakehurst | Modern Greek Continuers | 4 |
| 2029 | Blaxland High School | Blaxland | English (Advanced) | 4 |
| 2030 | Blaxland High School | Blaxland | Personal Development, Health and Physical Education | 4 |
| 2031 | Blue Mountains Grammar School | Wentworth Falls | Ancient History | 4 |
| 2032 | Bossley Park High School | Bossley Park | Industrial Technology | 4 |
| 2033 | Brigidine College Randwick | Randwick | Chemistry | 4 |
| 2034 | Brigidine College Randwick | Randwick | English (Standard) | 4 |
| 2035 | Brigidine College Randwick | Randwick | Hospitality Examination | 4 |
| 2036 | Brigidine College Randwick | Randwick | Legal Studies | 4 |
| 2037 | Brigidine College Randwick | Randwick | Studies of Religion II | 4 |
| 2038 | Brigidine College Randwick | Randwick | Visual Arts | 4 |
| 2039 | Brigidine College St Ives | St Ives | Mathematics | 4 |
| 2040 | Brigidine College St Ives | St Ives | Modern History | 4 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 14 Feb 2023