| 1866 | St Catherines School | Waverley | Modern History | 5 |
| 1867 | St Charbels College | Punchbowl | English (Advanced) | 5 |
| 1868 | St Charbels College | Punchbowl | Legal Studies | 5 |
| 1869 | St Charbels College | Punchbowl | Studies of Religion I | 5 |
| 1870 | St Clares College | Waverley | English (Advanced) | 5 |
| 1871 | St Columba Anglican School | Port Macquarie | Music 1 | 5 |
| 1872 | St Columbas Catholic College | Springwood | Biology | 5 |
| 1873 | St Columbas Catholic College | Springwood | English Extension 2 | 5 |
| 1874 | St Columbas Catholic College | Springwood | General Mathematics | 5 |
| 1875 | St Columbas Catholic College | Springwood | Personal Development, Health and Physical Education | 5 |
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| 1876 | St Edwards Christian Brothers College | East Gosford | Industrial Technology | 5 |
| 1877 | St Francis De Sales Regional College | Leeton | General Mathematics | 5 |
| 1878 | St Francis De Sales Regional College | Leeton | Studies of Religion I | 5 |
| 1879 | St Francis Xaviers College | Hamilton | Legal Studies | 5 |
| 1880 | St Francis Xaviers College | Hamilton | Mathematics Extension 1 | 5 |
| 1881 | St Francis Xaviers College | Hamilton | Personal Development, Health and Physical Education | 5 |
| 1882 | St George Girls High School | Kogarah | English Extension 2 | 5 |
| 1883 | St George Girls High School | Kogarah | French Continuers | 5 |
| 1884 | St Gregorys College Campbelltown | Gregory Hills | Mathematics Extension 1 | 5 |
| 1885 | St Gregorys College Campbelltown | Gregory Hills | Senior Science | 5 |
| 1886 | St Ignatius College | Lane Cove | Biology | 5 |
| 1887 | St Ignatius College | Lane Cove | Latin Extension | 5 |
| 1888 | St Ignatius College | Lane Cove | Visual Arts | 5 |
| 1889 | St Ives High School | St Ives | Mathematics Extension 2 | 5 |
| 1890 | St John Bosco College | Engadine | Mathematics | 5 |
| 1891 | St John Paul College | Coffs Harbour | General Mathematics | 5 |
| 1892 | St John Paul College | Coffs Harbour | Mathematics | 5 |
| 1893 | St John The Evangelist Catholic High School | Nowra | General Mathematics | 5 |
| 1894 | St Johns College | ? | Legal Studies | 5 |
| 1895 | St Josephs Catholic College | East Gosford | Modern History | 5 |
| 1896 | St Josephs Catholic College | East Gosford | Studies of Religion II | 5 |
| 1897 | St Josephs College | ? | Ancient History | 5 |
| 1898 | St Josephs College | ? | Physics | 5 |
| 1899 | St Josephs College | ? | Visual Arts | 5 |
| 1900 | St Josephs Regional College | Port Macquarie | Personal Development, Health and Physical Education | 5 |
| 1901 | St Leos Catholic College | Wahroonga | Studies of Religion II | 5 |
| 1902 | St Mary and St Minas Coptic Orthodox College | Rockdale | Chemistry | 5 |
| 1903 | St Mary and St Minas Coptic Orthodox College | Rockdale | Mathematics Extension 2 | 5 |
| 1904 | St Marys Cathedral College | Sydney | Legal Studies | 5 |
| 1905 | St Marys Senior High School | St Marys | English (Standard) | 5 |
| 1906 | St Marys Senior High School | St Marys | Filipino Continuers | 5 |
| 1907 | St Marys Senior High School | St Marys | Music 1 | 5 |
| 1908 | St Patricks College Sutherland | Sutherland | English (Advanced) | 5 |
| 1909 | St Patricks College Sutherland | Sutherland | Senior Science | 5 |
| 1910 | St Patricks College Sutherland | Sutherland | Visual Arts | 5 |
| 1911 | St Patricks Marist College | Dundas | Business Studies | 5 |
| 1912 | St Patricks Marist College | Dundas | Studies of Religion II | 5 |
| 1913 | St Pauls Catholic College | ? | Personal Development, Health and Physical Education | 5 |
| 1914 | St Pauls High School | Booragul | English (Advanced) | 5 |
| 1915 | St Philips Christian College Newcastle | Waratah | Biology | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 14 Feb 2023