| 2001 | Asquith Girls High School | Asquith | General Mathematics | 4 |
| 2002 | Asquith Girls High School | Asquith | Hospitality Examination | 4 |
| 2003 | Auburn Girls High School | Auburn | Biology | 4 |
| 2004 | Australian Institute of Music Senior Secondary College | Surry Hills | Music Extension | 4 |
| 2005 | Australian International School Hong Kong | Kowloon Tong, Hong Kong | General Mathematics | 4 |
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| 2006 | Australian International School Singapore | Singapore | Legal Studies | 4 |
| 2007 | Bankstown Girls High School | Bankstown | Design and Technology | 4 |
| 2008 | Barker College | Hornsby | Agriculture | 4 |
| 2009 | Barker College | Hornsby | Information Processes and Technology | 4 |
| 2010 | Baulkham Hills High School | Baulkham Hills | Ancient History | 4 |
| 2011 | Baulkham Hills High School | Baulkham Hills | Latin Extension | 4 |
| 2012 | Baulkham Hills High School | Baulkham Hills | Visual Arts | 4 |
| 2013 | Bede Polding College | South Windsor | Ancient History | 4 |
| 2014 | Bede Polding College | South Windsor | General Mathematics | 4 |
| 2015 | Bede Polding College | South Windsor | Hospitality Examination | 4 |
| 2016 | Bede Polding College | South Windsor | Music 1 | 4 |
| 2017 | Bega High School | Bega | Ancient History | 4 |
| 2018 | Beverly Hills Girls High School | Beverly Hills | English (Advanced) | 4 |
| 2019 | Beverly Hills Girls High School | Beverly Hills | Mathematics Extension 1 | 4 |
| 2020 | Birrong Girls High School | Birrong | Ancient History | 4 |
| 2021 | Birrong Girls High School | Birrong | Biology | 4 |
| 2022 | Birrong Girls High School | Birrong | Mathematics Extension 1 | 4 |
| 2023 | Bishop Druitt College | Coffs Harbour | General Mathematics | 4 |
| 2024 | Blakehurst High School | Blakehurst | Business Studies | 4 |
| 2025 | Blakehurst High School | Blakehurst | Chemistry | 4 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 14 Feb 2023