| 1991 | All Saints College Bathurst | Bathurst | Mathematics | 4 |
| 1992 | All Saints College St Marys Campus | Maitland | Ancient History | 4 |
| 1993 | Alstonville High School | Alstonville | English Extension 1 | 4 |
| 1994 | Alstonville High School | Alstonville | Physics | 4 |
| 1995 | Aquinas College | Menai | Mathematics | 4 |
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| 1996 | Aquinas College | Menai | Studies of Religion II | 4 |
| 1997 | Arden Anglican School Epping Campus | Epping | Mathematics | 4 |
| 1998 | Armidale High School | Armidale | Mathematics | 4 |
| 1999 | Ascham School | Edgecliff | German Extension | 4 |
| 2000 | Ascham School | Edgecliff | Mathematics Extension 2 | 4 |
| 2001 | Asquith Girls High School | Asquith | General Mathematics | 4 |
| 2002 | Asquith Girls High School | Asquith | Hospitality Examination | 4 |
| 2003 | Auburn Girls High School | Auburn | Biology | 4 |
| 2004 | Australian Institute of Music Senior Secondary College | Surry Hills | Music Extension | 4 |
| 2005 | Australian International School Hong Kong | Kowloon Tong, Hong Kong | General Mathematics | 4 |
| 2006 | Australian International School Singapore | Singapore | Legal Studies | 4 |
| 2007 | Bankstown Girls High School | Bankstown | Design and Technology | 4 |
| 2008 | Barker College | Hornsby | Agriculture | 4 |
| 2009 | Barker College | Hornsby | Information Processes and Technology | 4 |
| 2010 | Baulkham Hills High School | Baulkham Hills | Ancient History | 4 |
| 2011 | Baulkham Hills High School | Baulkham Hills | Latin Extension | 4 |
| 2012 | Baulkham Hills High School | Baulkham Hills | Visual Arts | 4 |
| 2013 | Bede Polding College | South Windsor | Ancient History | 4 |
| 2014 | Bede Polding College | South Windsor | General Mathematics | 4 |
| 2015 | Bede Polding College | South Windsor | Hospitality Examination | 4 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 14 Feb 2023