| 1866 | St Catherines School | Waverley | Modern History | 5 |
| 1867 | St Charbels College | Punchbowl | English (Advanced) | 5 |
| 1868 | St Charbels College | Punchbowl | Legal Studies | 5 |
| 1869 | St Charbels College | Punchbowl | Studies of Religion I | 5 |
| 1870 | St Clares College | Waverley | English (Advanced) | 5 |
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| 1871 | St Columba Anglican School | Port Macquarie | Music 1 | 5 |
| 1872 | St Columbas Catholic College | Springwood | Biology | 5 |
| 1873 | St Columbas Catholic College | Springwood | English Extension 2 | 5 |
| 1874 | St Columbas Catholic College | Springwood | General Mathematics | 5 |
| 1875 | St Columbas Catholic College | Springwood | Personal Development, Health and Physical Education | 5 |
| 1876 | St Edwards Christian Brothers College | East Gosford | Industrial Technology | 5 |
| 1877 | St Francis De Sales Regional College | Leeton | General Mathematics | 5 |
| 1878 | St Francis De Sales Regional College | Leeton | Studies of Religion I | 5 |
| 1879 | St Francis Xaviers College | Hamilton | Legal Studies | 5 |
| 1880 | St Francis Xaviers College | Hamilton | Mathematics Extension 1 | 5 |
| 1881 | St Francis Xaviers College | Hamilton | Personal Development, Health and Physical Education | 5 |
| 1882 | St George Girls High School | Kogarah | English Extension 2 | 5 |
| 1883 | St George Girls High School | Kogarah | French Continuers | 5 |
| 1884 | St Gregorys College Campbelltown | Gregory Hills | Mathematics Extension 1 | 5 |
| 1885 | St Gregorys College Campbelltown | Gregory Hills | Senior Science | 5 |
| 1886 | St Ignatius College | Lane Cove | Biology | 5 |
| 1887 | St Ignatius College | Lane Cove | Latin Extension | 5 |
| 1888 | St Ignatius College | Lane Cove | Visual Arts | 5 |
| 1889 | St Ives High School | St Ives | Mathematics Extension 2 | 5 |
| 1890 | St John Bosco College | Engadine | Mathematics | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 14 Feb 2023