| 1846 | Redfield College | Dural | Mathematics | 5 |
| 1847 | Riverside Girls High School | Gladesville | Mathematics | 5 |
| 1848 | Rose Bay Secondary College | Dover Heights | Mathematics | 5 |
| 1849 | Roseville College | Roseville | History Extension | 5 |
| 1850 | Roseville College | Roseville | Mathematics Extension 1 | 5 |
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| 1851 | SCECGS Redlands | Cremorne | Mathematics Extension 1 | 5 |
| 1852 | SCEGGS Darlinghurst | Darlinghurst | French Extension | 5 |
| 1853 | Sefton High School | Sefton | English Extension 1 | 5 |
| 1854 | Sefton High School | Sefton | Legal Studies | 5 |
| 1855 | SHORE Sydney Church of England Grammar School | North Sydney | Drama | 5 |
| 1856 | SHORE Sydney Church of England Grammar School | North Sydney | Physics | 5 |
| 1857 | SHORE Sydney Church of England Grammar School | North Sydney | Studies of Religion I | 5 |
| 1858 | Smiths Hill High School | Wollongong | Economics | 5 |
| 1859 | Smiths Hill High School | Wollongong | General Mathematics | 5 |
| 1860 | South Grafton High School | South Grafton | Modern History | 5 |
| 1861 | South Sydney High School | Maroubra | Mathematics Extension 1 | 5 |
| 1862 | St Aloysius College | Milsons Point | Mathematics Extension 2 | 5 |
| 1863 | St Andrews Cathedral School | Sydney | Music 1 | 5 |
| 1864 | St Andrews Cathedral School | Sydney | Music Extension | 5 |
| 1865 | St Catherines School | Waverley | Mathematics Extension 2 | 5 |
| 1866 | St Catherines School | Waverley | Modern History | 5 |
| 1867 | St Charbels College | Punchbowl | English (Advanced) | 5 |
| 1868 | St Charbels College | Punchbowl | Legal Studies | 5 |
| 1869 | St Charbels College | Punchbowl | Studies of Religion I | 5 |
| 1870 | St Clares College | Waverley | English (Advanced) | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 14 Feb 2023