| 1991 | All Saints College Bathurst | Bathurst | Mathematics | 4 |
| 1992 | All Saints College St Marys Campus | Maitland | Ancient History | 4 |
| 1993 | Alstonville High School | Alstonville | English Extension 1 | 4 |
| 1994 | Alstonville High School | Alstonville | Physics | 4 |
| 1995 | Aquinas College | Menai | Mathematics | 4 |
| 1996 | Aquinas College | Menai | Studies of Religion II | 4 |
| 1997 | Arden Anglican School Epping Campus | Epping | Mathematics | 4 |
| 1998 | Armidale High School | Armidale | Mathematics | 4 |
| 1999 | Ascham School | Edgecliff | German Extension | 4 |
| 2000 | Ascham School | Edgecliff | Mathematics Extension 2 | 4 |
| 2001 | Asquith Girls High School | Asquith | General Mathematics | 4 |
| 2002 | Asquith Girls High School | Asquith | Hospitality Examination | 4 |
| 2003 | Auburn Girls High School | Auburn | Biology | 4 |
| 2004 | Australian Institute of Music Senior Secondary College | Surry Hills | Music Extension | 4 |
| 2005 | Australian International School Hong Kong | Kowloon Tong, Hong Kong | General Mathematics | 4 |
| 2006 | Australian International School Singapore | Singapore | Legal Studies | 4 |
| 2007 | Bankstown Girls High School | Bankstown | Design and Technology | 4 |
| 2008 | Barker College | Hornsby | Agriculture | 4 |
| 2009 | Barker College | Hornsby | Information Processes and Technology | 4 |
| 2010 | Baulkham Hills High School | Baulkham Hills | Ancient History | 4 |
| |
||||
| 2011 | Baulkham Hills High School | Baulkham Hills | Latin Extension | 4 |
| 2012 | Baulkham Hills High School | Baulkham Hills | Visual Arts | 4 |
| 2013 | Bede Polding College | South Windsor | Ancient History | 4 |
| 2014 | Bede Polding College | South Windsor | General Mathematics | 4 |
| 2015 | Bede Polding College | South Windsor | Hospitality Examination | 4 |
| 2016 | Bede Polding College | South Windsor | Music 1 | 4 |
| 2017 | Bega High School | Bega | Ancient History | 4 |
| 2018 | Beverly Hills Girls High School | Beverly Hills | English (Advanced) | 4 |
| 2019 | Beverly Hills Girls High School | Beverly Hills | Mathematics Extension 1 | 4 |
| 2020 | Birrong Girls High School | Birrong | Ancient History | 4 |
| 2021 | Birrong Girls High School | Birrong | Biology | 4 |
| 2022 | Birrong Girls High School | Birrong | Mathematics Extension 1 | 4 |
| 2023 | Bishop Druitt College | Coffs Harbour | General Mathematics | 4 |
| 2024 | Blakehurst High School | Blakehurst | Business Studies | 4 |
| 2025 | Blakehurst High School | Blakehurst | Chemistry | 4 |
| 2026 | Blakehurst High School | Blakehurst | Community and Family Studies | 4 |
| 2027 | Blakehurst High School | Blakehurst | Japanese Beginners | 4 |
| 2028 | Blakehurst High School | Blakehurst | Modern Greek Continuers | 4 |
| 2029 | Blaxland High School | Blaxland | English (Advanced) | 4 |
| 2030 | Blaxland High School | Blaxland | Personal Development, Health and Physical Education | 4 |
| 2031 | Blue Mountains Grammar School | Wentworth Falls | Ancient History | 4 |
| 2032 | Bossley Park High School | Bossley Park | Industrial Technology | 4 |
| 2033 | Brigidine College Randwick | Randwick | Chemistry | 4 |
| 2034 | Brigidine College Randwick | Randwick | English (Standard) | 4 |
| 2035 | Brigidine College Randwick | Randwick | Hospitality Examination | 4 |
| 2036 | Brigidine College Randwick | Randwick | Legal Studies | 4 |
| 2037 | Brigidine College Randwick | Randwick | Studies of Religion II | 4 |
| 2038 | Brigidine College Randwick | Randwick | Visual Arts | 4 |
| 2039 | Brigidine College St Ives | St Ives | Mathematics | 4 |
| 2040 | Brigidine College St Ives | St Ives | Modern History | 4 |
| 2041 | Brigidine College St Ives | St Ives | Textiles and Design | 4 |
| 2042 | Brisbane Water Secondary College Woy Woy Campus | Woy Woy | Legal Studies | 4 |
| 2043 | Broughton Anglican College | Menangle Park | Hospitality Examination | 4 |
| 2044 | Bulli High School | Bulli | Mathematics | 4 |
| 2045 | Bulli High School | Bulli | Music 1 | 4 |
| 2046 | Burwood Girls High School | Croydon | French Continuers | 4 |
| 2047 | Burwood Girls High School | Croydon | History Extension | 4 |
| 2048 | Burwood Girls High School | Croydon | Modern History | 4 |
| 2049 | Cabramatta High School | Cabramatta | English as a Second Language | 4 |
| 2050 | Calrossy Anglican School | Tamworth | Personal Development, Health and Physical Education | 4 |
| 2051 | Canberra Grammar School | Red Hill, ACT | Biology | 4 |
| 2052 | Canberra Grammar School | Red Hill, ACT | Chinese Continuers | 4 |
| 2053 | Canberra Grammar School | Red Hill, ACT | Economics | 4 |
| 2054 | Canberra Grammar School | Red Hill, ACT | Latin Continuers | 4 |
| 2055 | Canberra Grammar School | Red Hill, ACT | Latin Extension | 4 |
| 2056 | Canberra Grammar School | Red Hill, ACT | Music Extension | 4 |
| 2057 | Canberra Grammar School | Red Hill, ACT | Software Design and Development | 4 |
| 2058 | Canley Vale High School | Canley Vale | Music 1 | 4 |
| 2059 | Canowindra High School | Canowindra | Design and Technology | 4 |
| 2060 | Canterbury Girls High School | Canterbury | Chinese Background Speakers | 4 |
| 2061 | Canterbury Girls High School | Canterbury | English (Advanced) | 4 |
| 2062 | Canterbury Girls High School | Canterbury | Korean Background Speakers | 4 |
| 2063 | Canterbury Girls High School | Canterbury | Mathematics | 4 |
| 2064 | Canterbury Girls High School | Canterbury | Mathematics Extension 1 | 4 |
| 2065 | Cardiff High School | Cardiff | Music 1 | 4 |
| 2066 | Caringbah High School | Caringbah | Engineering Studies | 4 |
| 2067 | Caringbah High School | Caringbah | Japanese Continuers | 4 |
| 2068 | Caringbah High School | Caringbah | Society and Culture | 4 |
| 2069 | Carlingford High School | Carlingford | Accounting | 4 |
| 2070 | Carlingford High School | Carlingford | Ancient History | 4 |
| 2071 | Carlingford High School | Carlingford | Chemistry | 4 |
| 2072 | Carlingford High School | Carlingford | Japanese Continuers | 4 |
| 2073 | Carlingford High School | Carlingford | Legal Studies | 4 |
| 2074 | Carlingford High School | Carlingford | Personal Development, Health and Physical Education | 4 |
| 2075 | Carlingford High School | Carlingford | Physics | 4 |
| 2076 | Carlingford High School | Carlingford | Senior Science | 4 |
| 2077 | Caroline Chisholm College | Glenmore Park | Personal Development, Health and Physical Education | 4 |
| 2078 | Castle Hill High School | Castle Hill | English as a Second Language | 4 |
| 2079 | Castle Hill High School | Castle Hill | Information Processes and Technology | 4 |
| 2080 | Castle Hill High School | Castle Hill | Music Extension | 4 |
| 2081 | Catherine McAuley Westmead | Westmead | Ancient History | 4 |
| 2082 | Catherine McAuley Westmead | Westmead | Biology | 4 |
| 2083 | Catherine McAuley Westmead | Westmead | Modern History | 4 |
| 2084 | Cecil Hills High School | Cecil Hills | English (Advanced) | 4 |
| 2085 | Cecil Hills High School | Cecil Hills | Information Processes and Technology | 4 |
| 2086 | Central Coast Adventist School | Erina | General Mathematics | 4 |
| 2087 | Central Coast Grammar School | Erina Heights | Society and Culture | 4 |
| 2088 | Cerdon College | Merrylands | Biology | 4 |
| 2089 | Cerdon College | Merrylands | Business Studies | 4 |
| 2090 | Cerdon College | Merrylands | Modern History | 4 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 14 Feb 2023