| 1991 | Westfields Sports High School | Fairfield West | Business Studies | 5 |
| 1992 | Westfields Sports High School | Fairfield West | English (Advanced) | 5 |
| 1993 | Westfields Sports High School | Fairfield West | Mathematics Extension 1 | 5 |
| 1994 | William Clarke College | Kellyville | Drama | 5 |
| 1995 | William Clarke College | Kellyville | Music 1 | 5 |
| 1996 | Willoughby Girls High School | Willoughby | Modern History | 5 |
| 1997 | Willoughby Girls High School | Willoughby | Textiles and Design | 5 |
| 1998 | Wingham High School | Wingham | Food Technology | 5 |
| 1999 | Wollongong High School of the Performing Arts | Fairy Meadow | Modern History | 5 |
| 2000 | Woolooware High School | Woolooware | Industrial Technology | 5 |
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| 2001 | Woolooware High School | Woolooware | Mathematics | 5 |
| 2002 | Wycliffe Christian School | Warrimoo | Music 1 | 5 |
| 2003 | Xavier High School | North Albury | Hospitality Examination | 5 |
| 2004 | Xavier High School | North Albury | Personal Development, Health and Physical Education | 5 |
| 2005 | Abbotsleigh | Wahroonga | Latin Continuers | 4 |
| 2006 | Al-Faisal College | Auburn | Mathematics | 4 |
| 2007 | Albion Park High School | Albion Park | Personal Development, Health and Physical Education | 4 |
| 2008 | All Saints Catholic Senior College | Casula | Biology | 4 |
| 2009 | All Saints Catholic Senior College | Casula | Economics | 4 |
| 2010 | All Saints Catholic Senior College | Casula | Society and Culture | 4 |
| 2011 | All Saints Catholic Senior College | Casula | Studies of Religion II | 4 |
| 2012 | All Saints College Bathurst | Bathurst | Chemistry | 4 |
| 2013 | All Saints College St Marys Campus | Maitland | Biology | 4 |
| 2014 | All Saints College St Marys Campus | Maitland | Industrial Technology | 4 |
| 2015 | All Saints College St Marys Campus | Maitland | Society and Culture | 4 |
| 2016 | All Saints College St Marys Campus | Maitland | Textiles and Design | 4 |
| 2017 | Aquinas College | Menai | Design and Technology | 4 |
| 2018 | Aquinas College | Menai | Economics | 4 |
| 2019 | Aquinas College | Menai | Mathematics | 4 |
| 2020 | Arden Anglican School Epping Campus | Epping | General Mathematics | 4 |
| 2021 | Arden Anglican School Epping Campus | Epping | Mathematics Extension 1 | 4 |
| 2022 | Arthur Phillip High School | Parramatta | General Mathematics | 4 |
| 2023 | Arthur Phillip High School | Parramatta | Legal Studies | 4 |
| 2024 | Ascham School | Edgecliff | Ancient History | 4 |
| 2025 | Ascham School | Edgecliff | Economics | 4 |
| 2026 | Ascham School | Edgecliff | English Extension 2 | 4 |
| 2027 | Ascham School | Edgecliff | Music 1 | 4 |
| 2028 | Ascham School | Edgecliff | Music 2 | 4 |
| 2029 | Ashfield Boys High School | Ashfield | General Mathematics | 4 |
| 2030 | Ashfield Boys High School | Ashfield | Legal Studies | 4 |
| 2031 | Asquith Girls High School | Asquith | English (Advanced) | 4 |
| 2032 | Asquith Girls High School | Asquith | Hospitality Examination | 4 |
| 2033 | Asquith Girls High School | Asquith | Music 1 | 4 |
| 2034 | Asquith Girls High School | Asquith | Visual Arts | 4 |
| 2035 | Auburn Girls High School | Auburn | Biology | 4 |
| 2036 | Australian International School Singapore | Singapore | Chemistry | 4 |
| 2037 | Batemans Bay High School | Batehaven | Design and Technology | 4 |
| 2038 | Baulkham Hills High School | Baulkham Hills | Japanese Continuers | 4 |
| 2039 | Bega High School | Bega | Ancient History | 4 |
| 2040 | Bega High School | Bega | Biology | 4 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 17 Feb 2023