| 1921 | St Josephs College | ? | English Extension 1 | 5 |
| 1922 | St Marks Coptic Orthodox College | Wattle Grove | Physics | 5 |
| 1923 | St Mary and St Minas Coptic Orthodox College | Rockdale | Mathematics Extension 2 | 5 |
| 1924 | St Mary Star of the Sea College | Wollongong | Biology | 5 |
| 1925 | St Mary Star of the Sea College | Wollongong | Mathematics | 5 |
| 1926 | St Mary Star of the Sea College | Wollongong | Music 1 | 5 |
| 1927 | St Marys Cathedral College | Sydney | Industrial Technology | 5 |
| 1928 | St Marys Senior High School | St Marys | Economics | 5 |
| 1929 | St Marys Senior High School | St Marys | English Extension 1 | 5 |
| 1930 | St Marys Senior High School | St Marys | Information Processes and Technology | 5 |
| 1931 | St Patricks College Campbelltown | Campbelltown | Ancient History | 5 |
| 1932 | St Patricks College Campbelltown | Campbelltown | Legal Studies | 5 |
| 1933 | St Patricks College Campbelltown | Campbelltown | Studies of Religion I | 5 |
| 1934 | St Patricks College Campbelltown | Campbelltown | Studies of Religion II | 5 |
| 1935 | St Patricks College Strathfield | Strathfield | Chemistry | 5 |
| 1936 | St Patricks College Sutherland | Sutherland | Mathematics Extension 2 | 5 |
| 1937 | St Patricks College Sutherland | Sutherland | Personal Development, Health and Physical Education | 5 |
| 1938 | St Patricks College Sutherland | Sutherland | Physics | 5 |
| 1939 | St Patricks Marist College | Dundas | Food Technology | 5 |
| 1940 | St Pauls Catholic College | ? | General Mathematics | 5 |
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| 1941 | St Pauls Catholic College | ? | Visual Arts | 5 |
| 1942 | St Pauls Grammar School | Cranebrook | General Mathematics | 5 |
| 1943 | St Philips Christian College Newcastle | Waratah | Mathematics | 5 |
| 1944 | St Philips Christian College Newcastle | Waratah | Mathematics Extension 1 | 5 |
| 1945 | St Ursulas College | Kingsgrove | Visual Arts | 5 |
| 1946 | St Vincents College | Potts Point | Biology | 5 |
| 1947 | St Vincents College | Potts Point | Personal Development, Health and Physical Education | 5 |
| 1948 | Stella Maris College | Manly | Chinese Background Speakers | 5 |
| 1949 | Strathfield Girls High School | Strathfield | Ancient History | 5 |
| 1950 | Strathfield Girls High School | Strathfield | Information Processes and Technology | 5 |
| 1951 | Strathfield Girls High School | Strathfield | Mathematics Extension 2 | 5 |
| 1952 | Strathfield Girls High School | Strathfield | Visual Arts | 5 |
| 1953 | Strathfield South High School | Enfield | Mathematics Extension 1 | 5 |
| 1954 | Sutherland Shire Christian School | Barden Ridge | English (Advanced) | 5 |
| 1955 | Sydney Boys High School | Moore Park | Engineering Studies | 5 |
| 1956 | Sydney Distance Education High School | Woolloomooloo | English (Advanced) | 5 |
| 1957 | Sydney Grammar School | Darlinghurst | Classical Greek Continuers | 5 |
| 1958 | Sydney Grammar School | Darlinghurst | Classical Greek Extension | 5 |
| 1959 | Sydney Grammar School | Darlinghurst | Italian Extension | 5 |
| 1960 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Biology | 5 |
| 1961 | Sydney Technical High School | Bexley | Modern History | 5 |
| 1962 | Sylvania High School | Sylvania | Food Technology | 5 |
| 1963 | Tangara School for Girls | Cherrybrook | Music 1 | 5 |
| 1964 | Tara Anglican School for Girls | North Parramatta | English Extension 1 | 5 |
| 1965 | Tara Anglican School for Girls | North Parramatta | Food Technology | 5 |
| 1966 | Tara Anglican School for Girls | North Parramatta | Mathematics | 5 |
| 1967 | Tempe High School | Tempe | Mathematics | 5 |
| 1968 | Tempe High School | Tempe | Mathematics Extension 2 | 5 |
| 1969 | The Armidale School | Armidale | Mathematics | 5 |
| 1970 | The Hills Grammar School | Kenthurst | Mathematics Extension 2 | 5 |
| 1971 | The Hills Grammar School | Kenthurst | Visual Arts | 5 |
| 1972 | The Illawarra Grammar School | Wollongong | Visual Arts | 5 |
| 1973 | The Kings School | North Parramatta | Senior Science | 5 |
| 1974 | The McDonald College | North Strathfield | Music Extension | 5 |
| 1975 | The Scots College | Bellevue Hill | Ancient History | 5 |
| 1976 | The Scots College | Bellevue Hill | Drama | 5 |
| 1977 | The Scots College | Bellevue Hill | Physics | 5 |
| 1978 | The Scots School Albury | Albury | Ancient History | 5 |
| 1979 | The Scots School Albury | Albury | Music 1 | 5 |
| 1980 | Trinity Catholic College Auburn Campus | Auburn | Industrial Technology | 5 |
| 1981 | Trinity Catholic College Auburn Campus | Auburn | Legal Studies | 5 |
| 1982 | Trinity Catholic College Goulburn | Goulburn | Senior Science | 5 |
| 1983 | Trinity Grammar School | Summer Hill | Chinese Continuers | 5 |
| 1984 | Trinity Grammar School | Summer Hill | Physics | 5 |
| 1985 | Tuggerah Lakes Secondary College The Entrance Campus | Shelly Beach | Visual Arts | 5 |
| 1986 | Turramurra High School | South Turramurra | English Extension 1 | 5 |
| 1987 | Turramurra High School | South Turramurra | Physics | 5 |
| 1988 | Ulladulla High School | Ulladulla | General Mathematics | 5 |
| 1989 | Warners Bay High School | Warners Bay | General Mathematics | 5 |
| 1990 | Wenona School | North Sydney | Modern History | 5 |
| 1991 | Westfields Sports High School | Fairfield West | Business Studies | 5 |
| 1992 | Westfields Sports High School | Fairfield West | English (Advanced) | 5 |
| 1993 | Westfields Sports High School | Fairfield West | Mathematics Extension 1 | 5 |
| 1994 | William Clarke College | Kellyville | Drama | 5 |
| 1995 | William Clarke College | Kellyville | Music 1 | 5 |
| 1996 | Willoughby Girls High School | Willoughby | Modern History | 5 |
| 1997 | Willoughby Girls High School | Willoughby | Textiles and Design | 5 |
| 1998 | Wingham High School | Wingham | Food Technology | 5 |
| 1999 | Wollongong High School of the Performing Arts | Fairy Meadow | Modern History | 5 |
| 2000 | Woolooware High School | Woolooware | Industrial Technology | 5 |
| 2001 | Woolooware High School | Woolooware | Mathematics | 5 |
| 2002 | Wycliffe Christian School | Warrimoo | Music 1 | 5 |
| 2003 | Xavier High School | North Albury | Hospitality Examination | 5 |
| 2004 | Xavier High School | North Albury | Personal Development, Health and Physical Education | 5 |
| 2005 | Abbotsleigh | Wahroonga | Latin Continuers | 4 |
| 2006 | Al-Faisal College | Auburn | Mathematics | 4 |
| 2007 | Albion Park High School | Albion Park | Personal Development, Health and Physical Education | 4 |
| 2008 | All Saints Catholic Senior College | Casula | Biology | 4 |
| 2009 | All Saints Catholic Senior College | Casula | Economics | 4 |
| 2010 | All Saints Catholic Senior College | Casula | Society and Culture | 4 |
| 2011 | All Saints Catholic Senior College | Casula | Studies of Religion II | 4 |
| 2012 | All Saints College Bathurst | Bathurst | Chemistry | 4 |
| 2013 | All Saints College St Marys Campus | Maitland | Biology | 4 |
| 2014 | All Saints College St Marys Campus | Maitland | Industrial Technology | 4 |
| 2015 | All Saints College St Marys Campus | Maitland | Society and Culture | 4 |
| 2016 | All Saints College St Marys Campus | Maitland | Textiles and Design | 4 |
| 2017 | Aquinas College | Menai | Design and Technology | 4 |
| 2018 | Aquinas College | Menai | Economics | 4 |
| 2019 | Aquinas College | Menai | Mathematics | 4 |
| 2020 | Arden Anglican School Epping Campus | Epping | General Mathematics | 4 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 17 Feb 2023