| 1876 | Rosebank College | Five Dock | Ancient History | 5 |
| 1877 | Roseville College | Roseville | Ancient History | 5 |
| 1878 | Roseville College | Roseville | Drama | 5 |
| 1879 | Roseville College | Roseville | Mathematics | 5 |
| 1880 | Santa Sabina College | Strathfield | Modern History | 5 |
| 1881 | Santa Sabina College | Strathfield | Visual Arts | 5 |
| 1882 | SCECGS Redlands | Cremorne | General Mathematics | 5 |
| 1883 | SCEGGS Darlinghurst | Darlinghurst | Music 1 | 5 |
| 1884 | Sefton High School | Sefton | English (Standard) | 5 |
| 1885 | Sefton High School | Sefton | Information Processes and Technology | 5 |
| 1886 | Sefton High School | Sefton | Studies of Religion I | 5 |
| 1887 | SHORE Sydney Church of England Grammar School | North Sydney | Economics | 5 |
| 1888 | SHORE Sydney Church of England Grammar School | North Sydney | History Extension | 5 |
| 1889 | Smiths Hill High School | Wollongong | English Extension 2 | 5 |
| 1890 | Springwood High School | Springwood | Music 1 | 5 |
| 1891 | St Aloysius College | Milsons Point | Biology | 5 |
| 1892 | St Aloysius College | Milsons Point | Drama | 5 |
| 1893 | St Andrews Cathedral School | Sydney | Drama | 5 |
| 1894 | St Andrews Cathedral School | Sydney | Legal Studies | 5 |
| 1895 | St Andrews Cathedral School | Sydney | Music Extension | 5 |
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| 1896 | St Augustines College | Brookvale | English (Advanced) | 5 |
| 1897 | St Augustines College | Brookvale | General Mathematics | 5 |
| 1898 | St Catherines School | Waverley | Mathematics Extension 2 | 5 |
| 1899 | St Charbels College | Punchbowl | Legal Studies | 5 |
| 1900 | St Charbels College | Punchbowl | Mathematics Extension 1 | 5 |
| 1901 | St Clares College | Waverley | Studies of Religion II | 5 |
| 1902 | St Clares High School | Taree | English (Advanced) | 5 |
| 1903 | St Columbas Catholic College | Springwood | English Extension 1 | 5 |
| 1904 | St Euphemia College | Bankstown | Modern Greek Continuers | 5 |
| 1905 | St Euphemia College | Bankstown | Modern Greek Extension | 5 |
| 1906 | St Francis Xaviers College | Hamilton | Ancient History | 5 |
| 1907 | St George Girls High School | Kogarah | Legal Studies | 5 |
| 1908 | St George Girls High School | Kogarah | Music Extension | 5 |
| 1909 | St Gregorys College Campbelltown | Gregory Hills | English (Advanced) | 5 |
| 1910 | St Gregorys College Campbelltown | Gregory Hills | Senior Science | 5 |
| 1911 | St Ignatius College | Lane Cove | Chemistry | 5 |
| 1912 | St Ives High School | St Ives | Legal Studies | 5 |
| 1913 | St Ives High School | St Ives | Mathematics | 5 |
| 1914 | St Ives High School | St Ives | Mathematics Extension 2 | 5 |
| 1915 | St John Bosco College | Engadine | Mathematics | 5 |
| 1916 | St John Paul College | Coffs Harbour | Legal Studies | 5 |
| 1917 | St John Paul II Catholic College Nirimba | Quakers Hill | Music 1 | 5 |
| 1918 | St John The Evangelist Catholic High School | Nowra | Drama | 5 |
| 1919 | St Johns College | ? | Mathematics Extension 1 | 5 |
| 1920 | St Josephs Catholic College | East Gosford | Geography | 5 |
| 1921 | St Josephs College | ? | English Extension 1 | 5 |
| 1922 | St Marks Coptic Orthodox College | Wattle Grove | Physics | 5 |
| 1923 | St Mary and St Minas Coptic Orthodox College | Rockdale | Mathematics Extension 2 | 5 |
| 1924 | St Mary Star of the Sea College | Wollongong | Biology | 5 |
| 1925 | St Mary Star of the Sea College | Wollongong | Mathematics | 5 |
| 1926 | St Mary Star of the Sea College | Wollongong | Music 1 | 5 |
| 1927 | St Marys Cathedral College | Sydney | Industrial Technology | 5 |
| 1928 | St Marys Senior High School | St Marys | Economics | 5 |
| 1929 | St Marys Senior High School | St Marys | English Extension 1 | 5 |
| 1930 | St Marys Senior High School | St Marys | Information Processes and Technology | 5 |
| 1931 | St Patricks College Campbelltown | Campbelltown | Ancient History | 5 |
| 1932 | St Patricks College Campbelltown | Campbelltown | Legal Studies | 5 |
| 1933 | St Patricks College Campbelltown | Campbelltown | Studies of Religion I | 5 |
| 1934 | St Patricks College Campbelltown | Campbelltown | Studies of Religion II | 5 |
| 1935 | St Patricks College Strathfield | Strathfield | Chemistry | 5 |
| 1936 | St Patricks College Sutherland | Sutherland | Mathematics Extension 2 | 5 |
| 1937 | St Patricks College Sutherland | Sutherland | Personal Development, Health and Physical Education | 5 |
| 1938 | St Patricks College Sutherland | Sutherland | Physics | 5 |
| 1939 | St Patricks Marist College | Dundas | Food Technology | 5 |
| 1940 | St Pauls Catholic College | ? | General Mathematics | 5 |
| 1941 | St Pauls Catholic College | ? | Visual Arts | 5 |
| 1942 | St Pauls Grammar School | Cranebrook | General Mathematics | 5 |
| 1943 | St Philips Christian College Newcastle | Waratah | Mathematics | 5 |
| 1944 | St Philips Christian College Newcastle | Waratah | Mathematics Extension 1 | 5 |
| 1945 | St Ursulas College | Kingsgrove | Visual Arts | 5 |
| 1946 | St Vincents College | Potts Point | Biology | 5 |
| 1947 | St Vincents College | Potts Point | Personal Development, Health and Physical Education | 5 |
| 1948 | Stella Maris College | Manly | Chinese Background Speakers | 5 |
| 1949 | Strathfield Girls High School | Strathfield | Ancient History | 5 |
| 1950 | Strathfield Girls High School | Strathfield | Information Processes and Technology | 5 |
| 1951 | Strathfield Girls High School | Strathfield | Mathematics Extension 2 | 5 |
| 1952 | Strathfield Girls High School | Strathfield | Visual Arts | 5 |
| 1953 | Strathfield South High School | Enfield | Mathematics Extension 1 | 5 |
| 1954 | Sutherland Shire Christian School | Barden Ridge | English (Advanced) | 5 |
| 1955 | Sydney Boys High School | Moore Park | Engineering Studies | 5 |
| 1956 | Sydney Distance Education High School | Woolloomooloo | English (Advanced) | 5 |
| 1957 | Sydney Grammar School | Darlinghurst | Classical Greek Continuers | 5 |
| 1958 | Sydney Grammar School | Darlinghurst | Classical Greek Extension | 5 |
| 1959 | Sydney Grammar School | Darlinghurst | Italian Extension | 5 |
| 1960 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Biology | 5 |
| 1961 | Sydney Technical High School | Bexley | Modern History | 5 |
| 1962 | Sylvania High School | Sylvania | Food Technology | 5 |
| 1963 | Tangara School for Girls | Cherrybrook | Music 1 | 5 |
| 1964 | Tara Anglican School for Girls | North Parramatta | English Extension 1 | 5 |
| 1965 | Tara Anglican School for Girls | North Parramatta | Food Technology | 5 |
| 1966 | Tara Anglican School for Girls | North Parramatta | Mathematics | 5 |
| 1967 | Tempe High School | Tempe | Mathematics | 5 |
| 1968 | Tempe High School | Tempe | Mathematics Extension 2 | 5 |
| 1969 | The Armidale School | Armidale | Mathematics | 5 |
| 1970 | The Hills Grammar School | Kenthurst | Mathematics Extension 2 | 5 |
| 1971 | The Hills Grammar School | Kenthurst | Visual Arts | 5 |
| 1972 | The Illawarra Grammar School | Wollongong | Visual Arts | 5 |
| 1973 | The Kings School | North Parramatta | Senior Science | 5 |
| 1974 | The McDonald College | North Strathfield | Music Extension | 5 |
| 1975 | The Scots College | Bellevue Hill | Ancient History | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 17 Feb 2023