| 1966 | Arden Anglican School Epping Campus | Epping | English (Advanced) | 4 |
| 1967 | Arthur Phillip High School | Parramatta | Ancient History | 4 |
| 1968 | Ascham School | Edgecliff | Biology | 4 |
| 1969 | Ascham School | Edgecliff | Economics | 4 |
| 1970 | Ascham School | Edgecliff | German Continuers | 4 |
| 1971 | Ascham School | Edgecliff | German Extension | 4 |
| 1972 | Ascham School | Edgecliff | History Extension | 4 |
| 1973 | Ascham School | Edgecliff | Latin Continuers | 4 |
| 1974 | Ashfield Boys High School | Ashfield | Chemistry | 4 |
| 1975 | Ashfield Boys High School | Ashfield | Mathematics Extension 2 | 4 |
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| 1976 | Asquith Girls High School | Asquith | Biology | 4 |
| 1977 | Asquith Girls High School | Asquith | Mathematics | 4 |
| 1978 | Australian Institute of Music Senior Secondary College | Surry Hills | Music 1 | 4 |
| 1979 | Australian International School Hong Kong | Kowloon Tong, Hong Kong | Business Studies | 4 |
| 1980 | Barker College | Hornsby | Information Processes and Technology | 4 |
| 1981 | Barker College | Hornsby | Studies of Religion I | 4 |
| 1982 | Barrenjoey High School | Avalon | English Extension 1 | 4 |
| 1983 | Baulkham Hills High School | Baulkham Hills | Personal Development, Health and Physical Education | 4 |
| 1984 | Bede Polding College | South Windsor | General Mathematics | 4 |
| 1985 | Bede Polding College | South Windsor | Mathematics | 4 |
| 1986 | Bethany College | Hurstville | Mathematics Extension 1 | 4 |
| 1987 | Bethany College | Hurstville | Studies of Religion II | 4 |
| 1988 | Birrong Girls High School | Birrong | Japanese Continuers | 4 |
| 1989 | Birrong Girls High School | Birrong | Mathematics Extension 1 | 4 |
| 1990 | Bishop Druitt College | Coffs Harbour | English (Advanced) | 4 |
| 1991 | Bishop Druitt College | Coffs Harbour | General Mathematics | 4 |
| 1992 | Bishop Druitt College | Coffs Harbour | Mathematics Extension 1 | 4 |
| 1993 | Bishop Druitt College | Coffs Harbour | Personal Development, Health and Physical Education | 4 |
| 1994 | Bishop Tyrrell Anglican College | Fletcher | Drama | 4 |
| 1995 | Blakehurst High School | Blakehurst | Biology | 4 |
| 1996 | Blue Mountains Grammar School | Wentworth Falls | Chemistry | 4 |
| 1997 | Bossley Park High School | Bossley Park | Visual Arts | 4 |
| 1998 | Brigidine College Randwick | Randwick | Chemistry | 4 |
| 1999 | Brigidine College Randwick | Randwick | Community and Family Studies | 4 |
| 2000 | Brigidine College Randwick | Randwick | General Mathematics | 4 |
| 2001 | Brigidine College Randwick | Randwick | History Extension | 4 |
| 2002 | Burwood Girls High School | Croydon | Chinese Background Speakers | 4 |
| 2003 | Burwood Girls High School | Croydon | English Extension 1 | 4 |
| 2004 | Burwood Girls High School | Croydon | Italian Continuers | 4 |
| 2005 | Burwood Girls High School | Croydon | Japanese Beginners | 4 |
| 2006 | Byron Bay High School | Byron Bay | English (Advanced) | 4 |
| 2007 | Cabramatta High School | Cabramatta | Mathematics Extension 1 | 4 |
| 2008 | Calrossy Anglican School | Tamworth | Ancient History | 4 |
| 2009 | Camden Haven High School | Laurieton | Music 1 | 4 |
| 2010 | Campbelltown Performing Arts High School | Campbelltown | Music 1 | 4 |
| 2011 | Canberra Grammar School | Red Hill, ACT | English (Advanced) | 4 |
| 2012 | Canberra Grammar School | Red Hill, ACT | Latin Continuers | 4 |
| 2013 | Canberra Grammar School | Red Hill, ACT | Latin Extension | 4 |
| 2014 | Canberra Grammar School | Red Hill, ACT | Software Design and Development | 4 |
| 2015 | Canley Vale High School | Canley Vale | Chemistry | 4 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 27 Jan 2021