| 1866 | St Johns College | ? | Modern History | 5 |
| 1867 | St Johns College | ? | Visual Arts | 5 |
| 1868 | St Josephs Catholic College | East Gosford | Mathematics Extension 1 | 5 |
| 1869 | St Lukes Grammar School | Dee Why | Mathematics Extension 2 | 5 |
| 1870 | St Marks Coptic Orthodox College | Wattle Grove | Chemistry | 5 |
| 1871 | St Mary Star of the Sea College | Wollongong | Drama | 5 |
| 1872 | St Mary Star of the Sea College | Wollongong | Economics | 5 |
| 1873 | St Marys Cathedral College | Sydney | Industrial Technology | 5 |
| 1874 | St Marys Cathedral College | Sydney | Music 1 | 5 |
| 1875 | St Marys Senior High School | St Marys | French Beginners | 5 |
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| 1876 | St Marys Senior High School | St Marys | Music 1 | 5 |
| 1877 | St Patricks College Campbelltown | Campbelltown | Personal Development, Health and Physical Education | 5 |
| 1878 | St Patricks College Strathfield | Strathfield | Ancient History | 5 |
| 1879 | St Patricks College Strathfield | Strathfield | Legal Studies | 5 |
| 1880 | St Patricks College Sutherland | Sutherland | Ancient History | 5 |
| 1881 | St Patricks College Sutherland | Sutherland | Visual Arts | 5 |
| 1882 | St Patricks Marist College | Dundas | Mathematics Extension 1 | 5 |
| 1883 | St Pauls High School | Booragul | Biology | 5 |
| 1884 | St Pauls High School | Booragul | Mathematics | 5 |
| 1885 | St Pauls High School | Booragul | Studies of Religion I | 5 |
| 1886 | St Philips Christian College Newcastle | Waratah | Entertainment Industry Examination | 5 |
| 1887 | St Philips Christian College Newcastle | Waratah | Mathematics | 5 |
| 1888 | St Pius X College | Chatswood | Music 1 | 5 |
| 1889 | St Scholasticas College Glebe Point | Glebe Point | English (Advanced) | 5 |
| 1890 | St Stanislaus College | Bathurst | Personal Development, Health and Physical Education | 5 |
| 1891 | St Ursulas College | Kingsgrove | Business Studies | 5 |
| 1892 | St Ursulas College | Kingsgrove | Personal Development, Health and Physical Education | 5 |
| 1893 | St Vincents College | Potts Point | English Extension 1 | 5 |
| 1894 | Stella Maris College | Manly | Chinese Background Speakers | 5 |
| 1895 | Stella Maris College | Manly | English Extension 1 | 5 |
| 1896 | Stella Maris College | Manly | Modern History | 5 |
| 1897 | Sule College Prestons | Prestons | Mathematics Extension 1 | 5 |
| 1898 | Sydney Boys High School | Moore Park | English Extension 2 | 5 |
| 1899 | Sydney Boys High School | Moore Park | Music Extension | 5 |
| 1900 | Sydney Girls High School | Surry Hills | English Extension 2 | 5 |
| 1901 | Sydney Grammar School | Darlinghurst | French Extension | 5 |
| 1902 | Sydney Grammar School | Darlinghurst | Music Extension | 5 |
| 1903 | Sydney Secondary College Blackwattle Bay Campus | Glebe | General Mathematics | 5 |
| 1904 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Legal Studies | 5 |
| 1905 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Society and Culture | 5 |
| 1906 | Tangara School for Girls | Cherrybrook | English Extension 2 | 5 |
| 1907 | Tangara School for Girls | Cherrybrook | Geography | 5 |
| 1908 | Tara Anglican School for Girls | North Parramatta | Drama | 5 |
| 1909 | Tara Anglican School for Girls | North Parramatta | Mathematics Extension 1 | 5 |
| 1910 | Tara Anglican School for Girls | North Parramatta | Personal Development, Health and Physical Education | 5 |
| 1911 | Terrigal High School | Terrigal | Community and Family Studies | 5 |
| 1912 | The Armidale School | Armidale | Mathematics Extension 1 | 5 |
| 1913 | The Forest High School | Frenchs Forest | General Mathematics | 5 |
| 1914 | The Hills Grammar School | Kenthurst | Mathematics Extension 2 | 5 |
| 1915 | The Illawarra Grammar School | Wollongong | Drama | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 27 Jan 2021