| 1876 | St Marys Senior High School | St Marys | Music 1 | 5 |
| 1877 | St Patricks College Campbelltown | Campbelltown | Personal Development, Health and Physical Education | 5 |
| 1878 | St Patricks College Strathfield | Strathfield | Ancient History | 5 |
| 1879 | St Patricks College Strathfield | Strathfield | Legal Studies | 5 |
| 1880 | St Patricks College Sutherland | Sutherland | Ancient History | 5 |
| 1881 | St Patricks College Sutherland | Sutherland | Visual Arts | 5 |
| 1882 | St Patricks Marist College | Dundas | Mathematics Extension 1 | 5 |
| 1883 | St Pauls High School | Booragul | Biology | 5 |
| 1884 | St Pauls High School | Booragul | Mathematics | 5 |
| 1885 | St Pauls High School | Booragul | Studies of Religion I | 5 |
| 1886 | St Philips Christian College Newcastle | Waratah | Entertainment Industry Examination | 5 |
| 1887 | St Philips Christian College Newcastle | Waratah | Mathematics | 5 |
| 1888 | St Pius X College | Chatswood | Music 1 | 5 |
| 1889 | St Scholasticas College Glebe Point | Glebe Point | English (Advanced) | 5 |
| 1890 | St Stanislaus College | Bathurst | Personal Development, Health and Physical Education | 5 |
| 1891 | St Ursulas College | Kingsgrove | Business Studies | 5 |
| 1892 | St Ursulas College | Kingsgrove | Personal Development, Health and Physical Education | 5 |
| 1893 | St Vincents College | Potts Point | English Extension 1 | 5 |
| 1894 | Stella Maris College | Manly | Chinese Background Speakers | 5 |
| 1895 | Stella Maris College | Manly | English Extension 1 | 5 |
| 1896 | Stella Maris College | Manly | Modern History | 5 |
| 1897 | Sule College Prestons | Prestons | Mathematics Extension 1 | 5 |
| 1898 | Sydney Boys High School | Moore Park | English Extension 2 | 5 |
| 1899 | Sydney Boys High School | Moore Park | Music Extension | 5 |
| 1900 | Sydney Girls High School | Surry Hills | English Extension 2 | 5 |
| 1901 | Sydney Grammar School | Darlinghurst | French Extension | 5 |
| 1902 | Sydney Grammar School | Darlinghurst | Music Extension | 5 |
| 1903 | Sydney Secondary College Blackwattle Bay Campus | Glebe | General Mathematics | 5 |
| 1904 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Legal Studies | 5 |
| 1905 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Society and Culture | 5 |
| |
||||
| 1906 | Tangara School for Girls | Cherrybrook | English Extension 2 | 5 |
| 1907 | Tangara School for Girls | Cherrybrook | Geography | 5 |
| 1908 | Tara Anglican School for Girls | North Parramatta | Drama | 5 |
| 1909 | Tara Anglican School for Girls | North Parramatta | Mathematics Extension 1 | 5 |
| 1910 | Tara Anglican School for Girls | North Parramatta | Personal Development, Health and Physical Education | 5 |
| 1911 | Terrigal High School | Terrigal | Community and Family Studies | 5 |
| 1912 | The Armidale School | Armidale | Mathematics Extension 1 | 5 |
| 1913 | The Forest High School | Frenchs Forest | General Mathematics | 5 |
| 1914 | The Hills Grammar School | Kenthurst | Mathematics Extension 2 | 5 |
| 1915 | The Illawarra Grammar School | Wollongong | Drama | 5 |
| 1916 | The Illawarra Grammar School | Wollongong | English Extension 2 | 5 |
| 1917 | The Illawarra Grammar School | Wollongong | Geography | 5 |
| 1918 | The Kings School | North Parramatta | Personal Development, Health and Physical Education | 5 |
| 1919 | The McDonald College | North Strathfield | Business Studies | 5 |
| 1920 | The Scots College | Bellevue Hill | Drama | 5 |
| 1921 | The Scots College | Bellevue Hill | Legal Studies | 5 |
| 1922 | The Scots College | Bellevue Hill | Mathematics Extension 2 | 5 |
| 1923 | The Scots School Albury | Albury | Ancient History | 5 |
| 1924 | The Scots School Albury | Albury | Physics | 5 |
| 1925 | Trinity Anglican College Albury | Thurgoona | General Mathematics | 5 |
| 1926 | Trinity Catholic College Auburn Campus | Auburn | English Extension 1 | 5 |
| 1927 | Trinity Catholic College Auburn Campus | Auburn | General Mathematics | 5 |
| 1928 | Trinity Catholic College Goulburn | Goulburn | General Mathematics | 5 |
| 1929 | Trinity Catholic College Lismore | Lismore | Ancient History | 5 |
| 1930 | Trinity Catholic College Lismore | Lismore | English Extension 1 | 5 |
| 1931 | Trinity Catholic College Lismore | Lismore | General Mathematics | 5 |
| 1932 | Trinity Catholic College Lismore | Lismore | Studies of Religion I | 5 |
| 1933 | Trinity Grammar School | Summer Hill | History Extension | 5 |
| 1934 | Turramurra High School | South Turramurra | Ancient History | 5 |
| 1935 | Warners Bay High School | Warners Bay | Visual Arts | 5 |
| 1936 | Waverley College | Waverley | Ancient History | 5 |
| 1937 | Waverley College | Waverley | Legal Studies | 5 |
| 1938 | Wenona School | North Sydney | Ancient History | 5 |
| 1939 | Wenona School | North Sydney | Design and Technology | 5 |
| 1940 | Wenona School | North Sydney | Mathematics | 5 |
| 1941 | Wenona School | North Sydney | Music 1 | 5 |
| 1942 | Wenona School | North Sydney | Personal Development, Health and Physical Education | 5 |
| 1943 | Wenona School | North Sydney | Senior Science | 5 |
| 1944 | Wenona School | North Sydney | Visual Arts | 5 |
| 1945 | Westfields Sports High School | Fairfield West | Hospitality Examination | 5 |
| 1946 | Westfields Sports High School | Fairfield West | Mathematics Extension 1 | 5 |
| 1947 | Willoughby Girls High School | Willoughby | Visual Arts | 5 |
| 1948 | Winmalee High School | Winmalee | Drama | 5 |
| 1949 | Woolgoolga High School | Woolgoolga | Mathematics | 5 |
| 1950 | Wycliffe Christian School | Warrimoo | Industrial Technology | 5 |
| 1951 | Wyndham College | Quakers Hill | Business Studies | 5 |
| 1952 | Albury High School | Albury | Biology | 4 |
| 1953 | All Saints Catholic Senior College | Casula | Economics | 4 |
| 1954 | All Saints Catholic Senior College | Casula | English Extension 2 | 4 |
| 1955 | All Saints Catholic Senior College | Casula | Industrial Technology | 4 |
| 1956 | All Saints Catholic Senior College | Casula | Personal Development, Health and Physical Education | 4 |
| 1957 | All Saints College St Marys Campus | Maitland | Business Studies | 4 |
| 1958 | All Saints College St Marys Campus | Maitland | Hospitality Examination | 4 |
| 1959 | Alstonville High School | Alstonville | Ancient History | 4 |
| 1960 | Alstonville High School | Alstonville | Legal Studies | 4 |
| 1961 | Aquinas College | Menai | Ancient History | 4 |
| 1962 | Aquinas College | Menai | Biology | 4 |
| 1963 | Aquinas College | Menai | Community and Family Studies | 4 |
| 1964 | Aquinas College | Menai | Hospitality Examination | 4 |
| 1965 | Aquinas College | Menai | Information Processes and Technology | 4 |
| 1966 | Arden Anglican School Epping Campus | Epping | English (Advanced) | 4 |
| 1967 | Arthur Phillip High School | Parramatta | Ancient History | 4 |
| 1968 | Ascham School | Edgecliff | Biology | 4 |
| 1969 | Ascham School | Edgecliff | Economics | 4 |
| 1970 | Ascham School | Edgecliff | German Continuers | 4 |
| 1971 | Ascham School | Edgecliff | German Extension | 4 |
| 1972 | Ascham School | Edgecliff | History Extension | 4 |
| 1973 | Ascham School | Edgecliff | Latin Continuers | 4 |
| 1974 | Ashfield Boys High School | Ashfield | Chemistry | 4 |
| 1975 | Ashfield Boys High School | Ashfield | Mathematics Extension 2 | 4 |
| 1976 | Asquith Girls High School | Asquith | Biology | 4 |
| 1977 | Asquith Girls High School | Asquith | Mathematics | 4 |
| 1978 | Australian Institute of Music Senior Secondary College | Surry Hills | Music 1 | 4 |
| 1979 | Australian International School Hong Kong | Kowloon Tong, Hong Kong | Business Studies | 4 |
| 1980 | Barker College | Hornsby | Information Processes and Technology | 4 |
| 1981 | Barker College | Hornsby | Studies of Religion I | 4 |
| 1982 | Barrenjoey High School | Avalon | English Extension 1 | 4 |
| 1983 | Baulkham Hills High School | Baulkham Hills | Personal Development, Health and Physical Education | 4 |
| 1984 | Bede Polding College | South Windsor | General Mathematics | 4 |
| 1985 | Bede Polding College | South Windsor | Mathematics | 4 |
| 1986 | Bethany College | Hurstville | Mathematics Extension 1 | 4 |
| 1987 | Bethany College | Hurstville | Studies of Religion II | 4 |
| 1988 | Birrong Girls High School | Birrong | Japanese Continuers | 4 |
| 1989 | Birrong Girls High School | Birrong | Mathematics Extension 1 | 4 |
| 1990 | Bishop Druitt College | Coffs Harbour | English (Advanced) | 4 |
| 1991 | Bishop Druitt College | Coffs Harbour | General Mathematics | 4 |
| 1992 | Bishop Druitt College | Coffs Harbour | Mathematics Extension 1 | 4 |
| 1993 | Bishop Druitt College | Coffs Harbour | Personal Development, Health and Physical Education | 4 |
| 1994 | Bishop Tyrrell Anglican College | Fletcher | Drama | 4 |
| 1995 | Blakehurst High School | Blakehurst | Biology | 4 |
| 1996 | Blue Mountains Grammar School | Wentworth Falls | Chemistry | 4 |
| 1997 | Bossley Park High School | Bossley Park | Visual Arts | 4 |
| 1998 | Brigidine College Randwick | Randwick | Chemistry | 4 |
| 1999 | Brigidine College Randwick | Randwick | Community and Family Studies | 4 |
| 2000 | Brigidine College Randwick | Randwick | General Mathematics | 4 |
| 2001 | Brigidine College Randwick | Randwick | History Extension | 4 |
| 2002 | Burwood Girls High School | Croydon | Chinese Background Speakers | 4 |
| 2003 | Burwood Girls High School | Croydon | English Extension 1 | 4 |
| 2004 | Burwood Girls High School | Croydon | Italian Continuers | 4 |
| 2005 | Burwood Girls High School | Croydon | Japanese Beginners | 4 |
| 2006 | Byron Bay High School | Byron Bay | English (Advanced) | 4 |
| 2007 | Cabramatta High School | Cabramatta | Mathematics Extension 1 | 4 |
| 2008 | Calrossy Anglican School | Tamworth | Ancient History | 4 |
| 2009 | Camden Haven High School | Laurieton | Music 1 | 4 |
| 2010 | Campbelltown Performing Arts High School | Campbelltown | Music 1 | 4 |
| 2011 | Canberra Grammar School | Red Hill, ACT | English (Advanced) | 4 |
| 2012 | Canberra Grammar School | Red Hill, ACT | Latin Continuers | 4 |
| 2013 | Canberra Grammar School | Red Hill, ACT | Latin Extension | 4 |
| 2014 | Canberra Grammar School | Red Hill, ACT | Software Design and Development | 4 |
| 2015 | Canley Vale High School | Canley Vale | Chemistry | 4 |
| 2016 | Caringbah High School | Caringbah | Drama | 4 |
| 2017 | Caringbah High School | Caringbah | Software Design and Development | 4 |
| 2018 | Caringbah High School | Caringbah | Studies of Religion I | 4 |
| 2019 | Carlingford High School | Carlingford | General Mathematics | 4 |
| 2020 | Caroline Chisholm College | Glenmore Park | Biology | 4 |
| 2021 | Casimir Catholic College | Marrickville | Personal Development, Health and Physical Education | 4 |
| 2022 | Casimir Catholic College | Marrickville | Studies of Religion I | 4 |
| 2023 | Catherine McAuley Westmead | Westmead | Mathematics Extension 1 | 4 |
| 2024 | Cecil Hills High School | Cecil Hills | Legal Studies | 4 |
| 2025 | Cecil Hills High School | Cecil Hills | Senior Science | 4 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 27 Jan 2021