| 1901 | Sydney Grammar School | Darlinghurst | French Extension | 5 |
| 1902 | Sydney Grammar School | Darlinghurst | Music Extension | 5 |
| 1903 | Sydney Secondary College Blackwattle Bay Campus | Glebe | General Mathematics | 5 |
| 1904 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Legal Studies | 5 |
| 1905 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Society and Culture | 5 |
| 1906 | Tangara School for Girls | Cherrybrook | English Extension 2 | 5 |
| 1907 | Tangara School for Girls | Cherrybrook | Geography | 5 |
| 1908 | Tara Anglican School for Girls | North Parramatta | Drama | 5 |
| 1909 | Tara Anglican School for Girls | North Parramatta | Mathematics Extension 1 | 5 |
| 1910 | Tara Anglican School for Girls | North Parramatta | Personal Development, Health and Physical Education | 5 |
| 1911 | Terrigal High School | Terrigal | Community and Family Studies | 5 |
| 1912 | The Armidale School | Armidale | Mathematics Extension 1 | 5 |
| 1913 | The Forest High School | Frenchs Forest | General Mathematics | 5 |
| 1914 | The Hills Grammar School | Kenthurst | Mathematics Extension 2 | 5 |
| 1915 | The Illawarra Grammar School | Wollongong | Drama | 5 |
| 1916 | The Illawarra Grammar School | Wollongong | English Extension 2 | 5 |
| 1917 | The Illawarra Grammar School | Wollongong | Geography | 5 |
| 1918 | The Kings School | North Parramatta | Personal Development, Health and Physical Education | 5 |
| 1919 | The McDonald College | North Strathfield | Business Studies | 5 |
| 1920 | The Scots College | Bellevue Hill | Drama | 5 |
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| 1921 | The Scots College | Bellevue Hill | Legal Studies | 5 |
| 1922 | The Scots College | Bellevue Hill | Mathematics Extension 2 | 5 |
| 1923 | The Scots School Albury | Albury | Ancient History | 5 |
| 1924 | The Scots School Albury | Albury | Physics | 5 |
| 1925 | Trinity Anglican College Albury | Thurgoona | General Mathematics | 5 |
| 1926 | Trinity Catholic College Auburn Campus | Auburn | English Extension 1 | 5 |
| 1927 | Trinity Catholic College Auburn Campus | Auburn | General Mathematics | 5 |
| 1928 | Trinity Catholic College Goulburn | Goulburn | General Mathematics | 5 |
| 1929 | Trinity Catholic College Lismore | Lismore | Ancient History | 5 |
| 1930 | Trinity Catholic College Lismore | Lismore | English Extension 1 | 5 |
| 1931 | Trinity Catholic College Lismore | Lismore | General Mathematics | 5 |
| 1932 | Trinity Catholic College Lismore | Lismore | Studies of Religion I | 5 |
| 1933 | Trinity Grammar School | Summer Hill | History Extension | 5 |
| 1934 | Turramurra High School | South Turramurra | Ancient History | 5 |
| 1935 | Warners Bay High School | Warners Bay | Visual Arts | 5 |
| 1936 | Waverley College | Waverley | Ancient History | 5 |
| 1937 | Waverley College | Waverley | Legal Studies | 5 |
| 1938 | Wenona School | North Sydney | Ancient History | 5 |
| 1939 | Wenona School | North Sydney | Design and Technology | 5 |
| 1940 | Wenona School | North Sydney | Mathematics | 5 |
| 1941 | Wenona School | North Sydney | Music 1 | 5 |
| 1942 | Wenona School | North Sydney | Personal Development, Health and Physical Education | 5 |
| 1943 | Wenona School | North Sydney | Senior Science | 5 |
| 1944 | Wenona School | North Sydney | Visual Arts | 5 |
| 1945 | Westfields Sports High School | Fairfield West | Hospitality Examination | 5 |
| 1946 | Westfields Sports High School | Fairfield West | Mathematics Extension 1 | 5 |
| 1947 | Willoughby Girls High School | Willoughby | Visual Arts | 5 |
| 1948 | Winmalee High School | Winmalee | Drama | 5 |
| 1949 | Woolgoolga High School | Woolgoolga | Mathematics | 5 |
| 1950 | Wycliffe Christian School | Warrimoo | Industrial Technology | 5 |
| 1951 | Wyndham College | Quakers Hill | Business Studies | 5 |
| 1952 | Albury High School | Albury | Biology | 4 |
| 1953 | All Saints Catholic Senior College | Casula | Economics | 4 |
| 1954 | All Saints Catholic Senior College | Casula | English Extension 2 | 4 |
| 1955 | All Saints Catholic Senior College | Casula | Industrial Technology | 4 |
| 1956 | All Saints Catholic Senior College | Casula | Personal Development, Health and Physical Education | 4 |
| 1957 | All Saints College St Marys Campus | Maitland | Business Studies | 4 |
| 1958 | All Saints College St Marys Campus | Maitland | Hospitality Examination | 4 |
| 1959 | Alstonville High School | Alstonville | Ancient History | 4 |
| 1960 | Alstonville High School | Alstonville | Legal Studies | 4 |
| 1961 | Aquinas College | Menai | Ancient History | 4 |
| 1962 | Aquinas College | Menai | Biology | 4 |
| 1963 | Aquinas College | Menai | Community and Family Studies | 4 |
| 1964 | Aquinas College | Menai | Hospitality Examination | 4 |
| 1965 | Aquinas College | Menai | Information Processes and Technology | 4 |
| 1966 | Arden Anglican School Epping Campus | Epping | English (Advanced) | 4 |
| 1967 | Arthur Phillip High School | Parramatta | Ancient History | 4 |
| 1968 | Ascham School | Edgecliff | Biology | 4 |
| 1969 | Ascham School | Edgecliff | Economics | 4 |
| 1970 | Ascham School | Edgecliff | German Continuers | 4 |
| 1971 | Ascham School | Edgecliff | German Extension | 4 |
| 1972 | Ascham School | Edgecliff | History Extension | 4 |
| 1973 | Ascham School | Edgecliff | Latin Continuers | 4 |
| 1974 | Ashfield Boys High School | Ashfield | Chemistry | 4 |
| 1975 | Ashfield Boys High School | Ashfield | Mathematics Extension 2 | 4 |
| 1976 | Asquith Girls High School | Asquith | Biology | 4 |
| 1977 | Asquith Girls High School | Asquith | Mathematics | 4 |
| 1978 | Australian Institute of Music Senior Secondary College | Surry Hills | Music 1 | 4 |
| 1979 | Australian International School Hong Kong | Kowloon Tong, Hong Kong | Business Studies | 4 |
| 1980 | Barker College | Hornsby | Information Processes and Technology | 4 |
| 1981 | Barker College | Hornsby | Studies of Religion I | 4 |
| 1982 | Barrenjoey High School | Avalon | English Extension 1 | 4 |
| 1983 | Baulkham Hills High School | Baulkham Hills | Personal Development, Health and Physical Education | 4 |
| 1984 | Bede Polding College | South Windsor | General Mathematics | 4 |
| 1985 | Bede Polding College | South Windsor | Mathematics | 4 |
| 1986 | Bethany College | Hurstville | Mathematics Extension 1 | 4 |
| 1987 | Bethany College | Hurstville | Studies of Religion II | 4 |
| 1988 | Birrong Girls High School | Birrong | Japanese Continuers | 4 |
| 1989 | Birrong Girls High School | Birrong | Mathematics Extension 1 | 4 |
| 1990 | Bishop Druitt College | Coffs Harbour | English (Advanced) | 4 |
| 1991 | Bishop Druitt College | Coffs Harbour | General Mathematics | 4 |
| 1992 | Bishop Druitt College | Coffs Harbour | Mathematics Extension 1 | 4 |
| 1993 | Bishop Druitt College | Coffs Harbour | Personal Development, Health and Physical Education | 4 |
| 1994 | Bishop Tyrrell Anglican College | Fletcher | Drama | 4 |
| 1995 | Blakehurst High School | Blakehurst | Biology | 4 |
| 1996 | Blue Mountains Grammar School | Wentworth Falls | Chemistry | 4 |
| 1997 | Bossley Park High School | Bossley Park | Visual Arts | 4 |
| 1998 | Brigidine College Randwick | Randwick | Chemistry | 4 |
| 1999 | Brigidine College Randwick | Randwick | Community and Family Studies | 4 |
| 2000 | Brigidine College Randwick | Randwick | General Mathematics | 4 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 27 Jan 2021