| 1866 | Trinity Catholic College Lismore | Lismore | English Extension 1 | 5 |
| 1867 | Trinity Catholic College Lismore | Lismore | Studies of Religion I | 5 |
| 1868 | Wagga Wagga High School | Wagga Wagga | English (Advanced) | 5 |
| 1869 | Waverley College | Waverley | Mathematics Extension 1 | 5 |
| 1870 | Wenona School | North Sydney | Ancient History | 5 |
| 1871 | Wenona School | North Sydney | Modern History | 5 |
| 1872 | William Clarke College | Kellyville | Music Extension | 5 |
| 1873 | William Clarke College | Kellyville | Physics | 5 |
| 1874 | Willoughby Girls High School | Willoughby | General Mathematics | 5 |
| 1875 | Willoughby Girls High School | Willoughby | History Extension | 5 |
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| 1876 | Willoughby Girls High School | Willoughby | Personal Development, Health and Physical Education | 5 |
| 1877 | Wollongong High School of the Performing Arts | Fairy Meadow | Ancient History | 5 |
| 1878 | Wollongong High School of the Performing Arts | Fairy Meadow | Dance | 5 |
| 1879 | Woolgoolga High School | Woolgoolga | Ancient History | 5 |
| 1880 | Woolooware High School | Woolooware | Personal Development, Health and Physical Education | 5 |
| 1881 | Xavier Catholic College | Skennars Head | Biology | 5 |
| 1882 | Xavier Catholic College | Skennars Head | Chemistry | 5 |
| 1883 | Xavier Catholic College | Skennars Head | General Mathematics | 5 |
| 1884 | Xavier Catholic College | Skennars Head | Visual Arts | 5 |
| 1885 | Abbotsleigh | Wahroonga | Chemistry | 4 |
| 1886 | Abbotsleigh | Wahroonga | German Continuers | 4 |
| 1887 | Abbotsleigh | Wahroonga | Latin Continuers | 4 |
| 1888 | Abbotsleigh | Wahroonga | Latin Extension | 4 |
| 1889 | Abbotsleigh | Wahroonga | Physics | 4 |
| 1890 | Albury High School | Albury | Mathematics | 4 |
| 1891 | Albury High School | Albury | Senior Science | 4 |
| 1892 | All Saints Catholic Senior College | Casula | Biology | 4 |
| 1893 | All Saints Catholic Senior College | Casula | Drama | 4 |
| 1894 | All Saints Catholic Senior College | Casula | English (Standard) | 4 |
| 1895 | All Saints Catholic Senior College | Casula | Food Technology | 4 |
| 1896 | All Saints Catholic Senior College | Casula | Studies of Religion I | 4 |
| 1897 | All Saints Catholic Senior College | Casula | Studies of Religion II | 4 |
| 1898 | All Saints College St Marys Campus | Maitland | Biology | 4 |
| 1899 | All Saints College St Marys Campus | Maitland | Business Studies | 4 |
| 1900 | All Saints College St Marys Campus | Maitland | Drama | 4 |
| 1901 | All Saints College St Marys Campus | Maitland | English Extension 1 | 4 |
| 1902 | All Saints College St Marys Campus | Maitland | Mathematics | 4 |
| 1903 | All Saints College St Marys Campus | Maitland | Studies of Religion II | 4 |
| 1904 | Alstonville High School | Alstonville | Biology | 4 |
| 1905 | Alstonville High School | Alstonville | English Extension 1 | 4 |
| 1906 | Alstonville High School | Alstonville | English Extension 2 | 4 |
| 1907 | Alstonville High School | Alstonville | Music 1 | 4 |
| 1908 | Aquinas College | Menai | Economics | 4 |
| 1909 | Aquinas College | Menai | Legal Studies | 4 |
| 1910 | Aquinas College | Menai | Mathematics | 4 |
| 1911 | Armidale High School | Armidale | Ancient History | 4 |
| 1912 | Armidale High School | Armidale | Visual Arts | 4 |
| 1913 | Arthur Phillip High School | Parramatta | Mathematics Extension 2 | 4 |
| 1914 | Ascham School | Edgecliff | General Mathematics | 4 |
| 1915 | Asquith Girls High School | Asquith | Geography | 4 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 5 Dec 2016