| 2001 | Northern Beaches Secondary College Manly Campus | North Curl Curl | Legal Studies | 4 |
| 2002 | Nowra High School | Nowra | General Mathematics | 4 |
| 2003 | Nowra High School | Nowra | Personal Development, Health and Physical Education | 4 |
| 2004 | Nowra High School | Nowra | Textiles and Design | 4 |
| 2005 | Oakhill College | Castle Hill | Design and Technology | 4 |
| 2006 | Oakhill College | Castle Hill | English Extension 1 | 4 |
| 2007 | Our Lady of Mercy College Parramatta | Parramatta | English Extension 2 | 4 |
| 2008 | Our Lady of Mercy College Parramatta | Parramatta | Geography | 4 |
| 2009 | Our Lady of the Sacred Heart College | Kensington | Business Studies | 4 |
| 2010 | Our Lady of the Sacred Heart College | Kensington | Food Technology | 4 |
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| 2011 | Oxford Falls Grammar School | Oxford Falls | Music 1 | 4 |
| 2012 | Oxley College | Burradoo | Geography | 4 |
| 2013 | Oxley High School | North Tamworth | Community and Family Studies | 4 |
| 2014 | Oxley High School | North Tamworth | Personal Development, Health and Physical Education | 4 |
| 2015 | Pacific Hills Christian School | Dural | History Extension | 4 |
| 2016 | Pacific Hills Christian School | Dural | Modern History | 4 |
| 2017 | Parkes High School | Parkes | Personal Development, Health and Physical Education | 4 |
| 2018 | Parramatta High School | Parramatta | Mathematics Extension 1 | 4 |
| 2019 | Parramatta Marist High School | Westmead | General Mathematics | 4 |
| 2020 | Parramatta Marist High School | Westmead | Modern History | 4 |
| 2021 | Patrician Brothers College Blacktown | Blacktown | Mathematics Extension 1 | 4 |
| 2022 | Patrician Brothers College Fairfield | Fairfield | Economics | 4 |
| 2023 | Patrician Brothers College Fairfield | Fairfield | Information Processes and Technology | 4 |
| 2024 | Patrician Brothers College Fairfield | Fairfield | Mathematics Extension 2 | 4 |
| 2025 | Patrician Brothers College Fairfield | Fairfield | Personal Development, Health and Physical Education | 4 |
| 2026 | Patrician Brothers College Fairfield | Fairfield | Visual Arts | 4 |
| 2027 | Pennant Hills High School | Pennant Hills | Ancient History | 4 |
| 2028 | Pennant Hills High School | Pennant Hills | Business Studies | 4 |
| 2029 | Pennant Hills High School | Pennant Hills | Chemistry | 4 |
| 2030 | Pennant Hills High School | Pennant Hills | Music 1 | 4 |
| 2031 | Pennant Hills High School | Pennant Hills | Personal Development, Health and Physical Education | 4 |
| 2032 | Pennant Hills High School | Pennant Hills | Physics | 4 |
| 2033 | Penrith High School | Penrith | Business Studies | 4 |
| 2034 | Penrith High School | Penrith | English Extension 2 | 4 |
| 2035 | Penrith High School | Penrith | Legal Studies | 4 |
| 2036 | Picnic Point High School | Picnic Point | General Mathematics | 4 |
| 2037 | Pittwater High School | Mona Vale | General Mathematics | 4 |
| 2038 | Pittwater High School | Mona Vale | Textiles and Design | 4 |
| 2039 | Pittwater House Schools | Collaroy | English (Advanced) | 4 |
| 2040 | Pittwater House Schools | Collaroy | Mathematics | 4 |
| 2041 | Pittwater House Schools | Collaroy | Mathematics Extension 1 | 4 |
| 2042 | Port Hacking High School | Miranda | Mathematics Extension 1 | 4 |
| 2043 | Port Macquarie High School | Port Macquarie | Ancient History | 4 |
| 2044 | Prairiewood High School | Prairiewood | Senior Science | 4 |
| 2045 | Presbyterian Ladies College Sydney | Croydon | Biology | 4 |
| 2046 | Presbyterian Ladies College Sydney | Croydon | Chemistry | 4 |
| 2047 | Presbyterian Ladies College Sydney | Croydon | Latin Extension | 4 |
| 2048 | Queenwood School for Girls | Mosman | English Extension 2 | 4 |
| 2049 | Queenwood School for Girls | Mosman | Geography | 4 |
| 2050 | Randwick Boys High School | Randwick | Chemistry | 4 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 22 Feb 2021