| 1966 | Mount Carmel Catholic High School | Varroville | Personal Development, Health and Physical Education | 4 |
| 1967 | Mount St Benedict College | Pennant Hills | Drama | 4 |
| 1968 | Mount St Benedict College | Pennant Hills | Food Technology | 4 |
| 1969 | Mount St Benedict College | Pennant Hills | General Mathematics | 4 |
| 1970 | Mount St Joseph Milperra | Milperra | History Extension | 4 |
| 1971 | Mount St Joseph Milperra | Milperra | Mathematics Extension 1 | 4 |
| 1972 | Mount St Joseph Milperra | Milperra | Modern History | 4 |
| 1973 | Mount St Joseph Milperra | Milperra | Music 1 | 4 |
| 1974 | Mount St Patrick College | Murwillumbah | Community and Family Studies | 4 |
| 1975 | Mount St Patrick College | Murwillumbah | English Extension 1 | 4 |
| 1976 | Mullumbimby High School | Mullumbimby | Mathematics | 4 |
| 1977 | Narrabri High School | Narrabri | Mathematics | 4 |
| 1978 | Newcastle Grammar School | Newcastle | General Mathematics | 4 |
| 1979 | Newcastle Grammar School | Newcastle | Mathematics | 4 |
| 1980 | Newington College | Stanmore | General Mathematics | 4 |
| 1981 | Newington College | Stanmore | Information Processes and Technology | 4 |
| 1982 | Newtown High School of Performing Arts | Newtown | Music Extension | 4 |
| 1983 | Normanhurst Boys High School | Normanhurst | Business Studies | 4 |
| 1984 | Normanhurst Boys High School | Normanhurst | English Extension 2 | 4 |
| 1985 | Normanhurst Boys High School | Normanhurst | Music 2 | 4 |
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| 1986 | Normanhurst Boys High School | Normanhurst | Visual Arts | 4 |
| 1987 | North Sydney Boys High School | Crows Nest | Ancient History | 4 |
| 1988 | North Sydney Girls High School | Crows Nest | Design and Technology | 4 |
| 1989 | North Sydney Girls High School | Crows Nest | Food Technology | 4 |
| 1990 | North Sydney Girls High School | Crows Nest | French Extension | 4 |
| 1991 | North Sydney Girls High School | Crows Nest | German Extension | 4 |
| 1992 | North Sydney Girls High School | Crows Nest | History Extension | 4 |
| 1993 | North Sydney Girls High School | Crows Nest | Latin Extension | 4 |
| 1994 | North Sydney Girls High School | Crows Nest | Music 2 | 4 |
| 1995 | Northern Beaches Secondary College Freshwater Campus | Freshwater | Ancient History | 4 |
| 1996 | Northern Beaches Secondary College Freshwater Campus | Freshwater | Business Studies | 4 |
| 1997 | Northern Beaches Secondary College Freshwater Campus | Freshwater | Visual Arts | 4 |
| 1998 | Northern Beaches Secondary College Mackellar Girls Campus | Manly Vale | English (Advanced) | 4 |
| 1999 | Northern Beaches Secondary College Mackellar Girls Campus | Manly Vale | Visual Arts | 4 |
| 2000 | Northern Beaches Secondary College Manly Campus | North Curl Curl | English Extension 2 | 4 |
| 2001 | Northern Beaches Secondary College Manly Campus | North Curl Curl | Legal Studies | 4 |
| 2002 | Nowra High School | Nowra | General Mathematics | 4 |
| 2003 | Nowra High School | Nowra | Personal Development, Health and Physical Education | 4 |
| 2004 | Nowra High School | Nowra | Textiles and Design | 4 |
| 2005 | Oakhill College | Castle Hill | Design and Technology | 4 |
| 2006 | Oakhill College | Castle Hill | English Extension 1 | 4 |
| 2007 | Our Lady of Mercy College Parramatta | Parramatta | English Extension 2 | 4 |
| 2008 | Our Lady of Mercy College Parramatta | Parramatta | Geography | 4 |
| 2009 | Our Lady of the Sacred Heart College | Kensington | Business Studies | 4 |
| 2010 | Our Lady of the Sacred Heart College | Kensington | Food Technology | 4 |
| 2011 | Oxford Falls Grammar School | Oxford Falls | Music 1 | 4 |
| 2012 | Oxley College | Burradoo | Geography | 4 |
| 2013 | Oxley High School | North Tamworth | Community and Family Studies | 4 |
| 2014 | Oxley High School | North Tamworth | Personal Development, Health and Physical Education | 4 |
| 2015 | Pacific Hills Christian School | Dural | History Extension | 4 |
| 2016 | Pacific Hills Christian School | Dural | Modern History | 4 |
| 2017 | Parkes High School | Parkes | Personal Development, Health and Physical Education | 4 |
| 2018 | Parramatta High School | Parramatta | Mathematics Extension 1 | 4 |
| 2019 | Parramatta Marist High School | Westmead | General Mathematics | 4 |
| 2020 | Parramatta Marist High School | Westmead | Modern History | 4 |
| 2021 | Patrician Brothers College Blacktown | Blacktown | Mathematics Extension 1 | 4 |
| 2022 | Patrician Brothers College Fairfield | Fairfield | Economics | 4 |
| 2023 | Patrician Brothers College Fairfield | Fairfield | Information Processes and Technology | 4 |
| 2024 | Patrician Brothers College Fairfield | Fairfield | Mathematics Extension 2 | 4 |
| 2025 | Patrician Brothers College Fairfield | Fairfield | Personal Development, Health and Physical Education | 4 |
| 2026 | Patrician Brothers College Fairfield | Fairfield | Visual Arts | 4 |
| 2027 | Pennant Hills High School | Pennant Hills | Ancient History | 4 |
| 2028 | Pennant Hills High School | Pennant Hills | Business Studies | 4 |
| 2029 | Pennant Hills High School | Pennant Hills | Chemistry | 4 |
| 2030 | Pennant Hills High School | Pennant Hills | Music 1 | 4 |
| 2031 | Pennant Hills High School | Pennant Hills | Personal Development, Health and Physical Education | 4 |
| 2032 | Pennant Hills High School | Pennant Hills | Physics | 4 |
| 2033 | Penrith High School | Penrith | Business Studies | 4 |
| 2034 | Penrith High School | Penrith | English Extension 2 | 4 |
| 2035 | Penrith High School | Penrith | Legal Studies | 4 |
| 2036 | Picnic Point High School | Picnic Point | General Mathematics | 4 |
| 2037 | Pittwater High School | Mona Vale | General Mathematics | 4 |
| 2038 | Pittwater High School | Mona Vale | Textiles and Design | 4 |
| 2039 | Pittwater House Schools | Collaroy | English (Advanced) | 4 |
| 2040 | Pittwater House Schools | Collaroy | Mathematics | 4 |
| 2041 | Pittwater House Schools | Collaroy | Mathematics Extension 1 | 4 |
| 2042 | Port Hacking High School | Miranda | Mathematics Extension 1 | 4 |
| 2043 | Port Macquarie High School | Port Macquarie | Ancient History | 4 |
| 2044 | Prairiewood High School | Prairiewood | Senior Science | 4 |
| 2045 | Presbyterian Ladies College Sydney | Croydon | Biology | 4 |
| 2046 | Presbyterian Ladies College Sydney | Croydon | Chemistry | 4 |
| 2047 | Presbyterian Ladies College Sydney | Croydon | Latin Extension | 4 |
| 2048 | Queenwood School for Girls | Mosman | English Extension 2 | 4 |
| 2049 | Queenwood School for Girls | Mosman | Geography | 4 |
| 2050 | Randwick Boys High School | Randwick | Chemistry | 4 |
| 2051 | Randwick Boys High School | Randwick | Mathematics Extension 2 | 4 |
| 2052 | Randwick Girls High School | Randwick | Japanese Continuers | 4 |
| 2053 | Randwick Girls High School | Randwick | Japanese Extension | 4 |
| 2054 | Ravenswood School for Girls | Gordon | German Continuers | 4 |
| 2055 | Ravenswood School for Girls | Gordon | Japanese Continuers | 4 |
| 2056 | Ravenswood School for Girls | Gordon | Music 2 | 4 |
| 2057 | Reddam House Bondi Campus | North Bondi | English Extension 1 | 4 |
| 2058 | Reddam House Bondi Campus | North Bondi | History Extension | 4 |
| 2059 | Redfield College | Dural | General Mathematics | 4 |
| 2060 | Redfield College | Dural | Personal Development, Health and Physical Education | 4 |
| 2061 | Riverside Girls High School | Gladesville | Ancient History | 4 |
| 2062 | Riverside Girls High School | Gladesville | Economics | 4 |
| 2063 | Riverside Girls High School | Gladesville | English as a Second Language | 4 |
| 2064 | Rose Bay Secondary College | Dover Heights | Mathematics | 4 |
| 2065 | Rosebank College | Five Dock | English (Advanced) | 4 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 22 Feb 2021